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Volumn 352, Issue 9, 2010, Pages 1441-1445

Dual amine- and brønsted acid-catalyzed α-allylic alkylation of aldehydes

Author keywords

Aldehydes; Allylic alkylation; Br nsted acids; Enamine catalysis; Organocatalysis

Indexed keywords


EID: 77954308586     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000071     Document Type: Article
Times cited : (27)

References (66)
  • 1
    • 84942767100 scopus 로고
    • (Eds.: W Bartmann, K.B. Sharpless), Pergamon Press, Oxford, Charpter 57
    • a) B. M. Trost, T. R. Verhoeven, in: Comprehensive Organometallic Chemistry, (Eds.: W Bartmann, K.B. Sharpless), Pergamon Press, Oxford, 1982, Vol. 8, Charpter 57;
    • (1982) Comprehensive Organometallic Chemistry , vol.8
    • Trost, B.M.1    Verhoeven, T.R.2
  • 2
    • 0002782655 scopus 로고
    • Eds. : B. M. Trost, I. Fleming, Pergamon, Oxford
    • b) D. Caine, in: Comprehensive Organic Synthesis (Eds. : B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, Vol. 3, pp 1-63.
    • (1991) Comprehensive Organic Synthesis , vol.3 , pp. 1-63
    • Caine, D.1
  • 30
    • 53549086402 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed.
    • Angew. Chem. Int. Ed. 2008, 47, 1741;
    • (2008) , vol.47 , pp. 1741
  • 66
    • 77954281092 scopus 로고    scopus 로고
    • (R,R)-1,2-diphenylethylenediamine (DPEN), Ts-DPEN, L-proline, L-serine, and L-tryptophan, Lthreonine, quinine-derived primary amines, and other simple and commercial available secondary amino organocatalysts have been used in the asymmetric α-allylic alkylation of cyclohexanone, in which most of the amino catalysts gave no enantioselectivity and 7% ee was the best result for the L-tryptophan-catalyzed α-allylic alkylation of cyclohexanone in the presence of TsOH
    • (R,R)-1,2-diphenylethylenediamine (DPEN), Ts-DPEN, L-proline, L-serine, and L-tryptophan, Lthreonine, quinine-derived primary amines, and other simple and commercial available secondary amino organocatalysts have been used in the asymmetric α-allylic alkylation of cyclohexanone, in which most of the amino catalysts gave no enantioselectivity and 7% ee was the best result for the L-tryptophan-catalyzed α-allylic alkylation of cyclohexanone in the presence of TsOH.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.