Synthesis, spectroscopic and electrochemical properties, and electronic structures of octahedral hexatechnetium(III) clusters [Tc6Q 8(CN)6]4? (Q = S, Se)

Inorganic Chemistry

Volumn 49, Issue 13, 2010, Pages 5876-5882

  Yoshimura, Takashi ^a   Ikai, Takuya ^a   Takayama, Tsutomu ^b   Sekine, Tsutomu ^c   Kino, Yasushi ^c   Shinohara, Atsushi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b DAIDO UNIVERSITY   (Japan)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77954136078     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic1000717     Document Type: Article

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133. 4? (Q = S, Se) following the same method as that used for the hexatechnetium complexes. The bond distances and angles in the optimized geometries of the rhenium complexes and the frequencies were in good agreement with the values calculated theoretically using the same basis set.
134. 4?, with a maximum emission wavelength at 858 nm at 80 K in the solid state, could not be confirmed by the naked eye.