Preparation of the binary technetium bromides: TcBr 3 and TcBr 4

Journal of the American Chemical Society

Volumn 131, Issue 3, 2009, Pages 910-911

  Poineau, Frederic ^a   Rodriguez, Efrain E ^b   Forster, Paul M ^a   Sattelberger, Alfred P ^c   Cheetham, Anthony K ^d   Czerwinski, Kenneth R ^a  

^a UNIVERSITY OF NEVADA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c ARGONNE NATIONAL LABORATORY   (United States)

^d UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EDGE SHARING; ELEMENTAL BROMINE; INFINITE CHAINS; METAL-METAL BONDS; ORTHORHOMBIC SPACE GROUPS; SINGLE CRYSTAL XRD;

BROMINE; BROMINE COMPOUNDS; CHEMICAL BONDS; SINGLE CRYSTALS;

TECHNETIUM;

BROMINE DERIVATIVE; TECHNETIUM DERIVATIVE; TECHNETIUM TETRABROMIDE; TECHNETIUM TRIBROMIDE; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; DRUG STRUCTURE; DRUG SYNTHESIS; X RAY DIFFRACTION;

EID: 67749096004     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja808597r     Document Type: Article

References (24)

1. (a) Alberto, R. Comp. Coord. Chem II 2004, 5, 127-270.
2. (b) Sattelberger, A. P.; Poineau, F.; Scott, B. L. Comp. Coord. Chem III 2007, 5, 833-854.
3. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Sattelberger, A. P.; Bhattacharjee, J.; Waghmare, U. V.; Hartmann, T.; Cheetham, A. K. J. Am. Chem. Soc. 2007, 129, 10244-10248.
4. (a) Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6 th ed.; John Wiley and Sons: New York, 1999, Chapter 18-D.
5. (b) Schwochau, K. Technetium: Chemistry and Radiopharmaceutical. Applications; Wiley-VCH: Weinheim, Germany, 2000.
6. Rinke, K.; Klein, M.; Schaefer, H. J. Less-Common Met. 1967, 12, 497-503.
7. 1 = 4.70%, GOF 1.06, 3458 reflections, 29 refined parameters. Full refinement details are included in Supporting Information.
8. (a) Lin, J.; Miller, G. J. Inorg. Chem. 1993, 32, 1476-1487.
9. (b) Merlino, S.; Labella, L.; Marchetti, F.; Toscani, S. Chem. Mater. 2004, 16, 3895-903.
10. (c) Hillebrecht, H.; Ludwig, Th.; Thiele, G. Z. Anorg. Allg. Chem. 2004, 630, 2199-2204.
11. (d) Lachgar, A.; Dudis, D. S.; Corbett, J. D. Inorg. Chem. 1990, 29, 2242-2246.
12. (a) Aslanov, L. A.; Volkov, S. V.; Kolesnichenko, V. L.; Rybakov, V. B.; Timoshchenko, N. I. Ukr. Khim. Zh. 1992, 58, 279-281.
13. (b) Kolbin, N. I.; Ovchinnikov, K. V. Zh. Neorg. Khim. 1968, 13, 2306-2307.
14. (a) Thompson, R. J.; Foster, R. E.; Booker, J. L. Inorg. Synth. 1967, 10, 58-61.
15. (b) Glicksman, H. D.; Hamer, A. D.; Smith, T. J.; Walton, R. A. Inorg. Chem. 1976, 15, 2205-2209.
16. (c) Cotton, F. A.; Lippard, S. J.; Mague, J. Y. Inorg. Chem. 1965, 4, 508-514.
17. (d) Colton, R. J. Chem. Soc. 1962, 2078-2080.
18. 4: Pbca (a = 6.3237(5) Å12.1777(9) Å, c= 14.7397(11) Å), R1 = 2.16%, GOF 1.071, 1969 peaks > 2δ, 46 refined parameters. Full refinement details are included in Supporting Information.
19. Batsanov, S. S. Inorg. Mater. 2001, 37, 871-885.
20. Elder, M.; Penfold, B. R. Inorg. Chem. 1966, 5, 1197-1200.
21. (a) Thiele, G.; Wochner, H.; Wagner, H. Z. Anorg. Allg. Chem. 1985, 530, 178-186.
22. (b) Pilbrow, M. F. J. Chem. Soc., Chem. Comm. 1972, 5, 270-271.
23. Degner, M.; Holle, Bernd; Kamm, J.; Pilbrow, M. F.; Thiele, G.; Wagner, D.; Weigl, W.; Woditsch, P. Transition Met. Chem. 1976, 1, 41-47.
24. Fergusson, J. E.; Hickford, J. H. Aust. J. Chem. 1970, 23, 453-61.