A novel framework type for inorganic clusters with cyanide ligands: Crystal structures of Cs2Mn3[Re6Se8(CN)6]2·15H2O and (H3O)2Co3[Re6Se8(CN)6]2·14.5H2O

Angewandte Chemie - International Edition

Volumn 37, Issue 13-14, 1998, Pages 1943-1945

  Naumov, Nikolaj G ^a   Virovets, Alexander V ^a   Sokolov, Maxim N ^a   Artemkina, Sofia B ^b   Fedorov, Vladimir E ^a  

^a ENERGY SYSTEMS INSTITUTE   (Russian Federation)

^b NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

Author keywords

Clusters; Cyanide complexes; Rhenium; Solid state structures

Indexed keywords

EID: 0032479725     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980803)37:13/14<1943::AID-ANIE1943<3.0.CO;2-Q     Document Type: Article

References (21)

1. A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon Press, Oxford, 1986, pp. 941-943.
2. K. R. Dunbar, R. A. Heintz, Prog. Inorg. Chem. 1997, 45, 283-391.
3. J. F. Keggin, F. D. Miles, Nature 1936, 137, 577-578.
4. H. J. Buser, D. Schwarzenbach, W. Petter, A. Ludi, Inorg. Chem. 1977, 16, 2704-2710.
5. D. F. Mullica, E. L. Sappenfield, D. B. Tippin, D. H. Leschnitzer, Inorg. Chim. Acta 1989, 164, 99-103.
6. K. A. Hofmann, F. Höchtlen, Chem. Ber. 1903, 36, 1149-1151.
7. K. A. Hofmann, H. Arnoldi, Chem. Ber. 1906, 39, 339-344.
8. J. H. Rayner, H. M. Powell, J. Chem. Soc. 1958, 3412-3418.
9. T. Iwamoto, T. Miyoshi, Y. Sasaki, Acta Crystallogr. Sect. B 1974, 30, 292-295.
10. Yu. V. Mironov, A. V. Virovets, V. E. Fedorov, N. V. Podberezskaya, O. V. Shishkin, Yu. T. Struchkov, Polyhedron 1995, 14, 3171-3173.
11. N. G. Naumov, A. V. Virovets, N. V. Podberezskaya, V.E. Fedorov, Zh. Strukt. Khim. 1997, 38, 1020-1026.
12. H. Imoto, N. G. Naumov, A. V. Virovets, T. Saito, V. E. Fedorov, Zh. Strukt. Khim. 1998, in press.
13. M. Laing, P. M. Kiernan, W. P. Griffith, J. Chem. Soc. Chem. Commun. 1977, 221-222.
14. Y. V. Mironov, T. E. Albrecht-Schmitt, J. A. Ibers, Z. Krist. New Crystal Structures 1997, 212, 308.
15. V. P. Fedin, M. R. G. Elsegood, W. Clegg, A. G. Sykes, Polyhedron 1996, 15, 485-488.
16. 2+ ions bonded to N atoms (2.19-2.21 Å for M = Mn and 2.03-2.15 Å for M = Co). The metal-carbon distances are shorter (1.85-1.90 Å). The IR spectra demonstrated single, sharp peaks due to the CN stretching vibration, in the case of linkage isomerism at least two peaks would be observed.
17. H. Henkel, D. Babel, Z. Naturforsch. Teil B 1984, 39, 880-885.
18. G. W. Beall, W. O. Milligan, J. Korp, I. Bernal, Inorg. Chem. 1977, 16, 2715-2718.
19. S. C. Abrahams, J. L. Bernstein, R. Liminga, E. T. Eisenmann, J. Chem. Phys. 1980, 73, 4585-4590.
20. 2O, (space group Im3̄m, Z = 8, a = 19.857 Å).
21. G. M. Sheldrick, SHELX-97, Universität Göttingen, 1997.