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Inorganic Chemistry

Volumn 48, Issue 1, 2009, Pages 5-7

Base-mediated conversion of hydrazine to diazene and dinitrogen at an iron center

(3) Field, Leslie D a Li, Hsiu L a Magill, Alison M a

a UNIVERSITY OF NEW SOUTH WALES (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

DIAZENE; HYDRAZINE; HYDRAZINE DERIVATIVE; IMIDE; IRON; NITROGEN; ORGANOMETALLIC COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS;

HYDRAZINES; IMIDES; IRON; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NITROGEN; ORGANOMETALLIC COMPOUNDS;

EID: 59849091037 PISSN: 00201669 EISSN: None Source Type: Journal
DOI: 10.1021/ic801856q Document Type: Article

Times cited : (68)

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- The possibility that the reaction proceeds by loss of diazene followed by disproportionation to yield hydrazine and free dinitrogen, which can be trapped by iron(0, can be discounted. The reaction is done using 15N- labeled [Fe(N2H4)(dmpe)2]2+ 1 under a 14N atmosphere, and there is little incorporation of 14N into the product Fe(N2)(dmpe)2 5 by IR spectroscopy
- 2 5 by IR spectroscopy.

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