Characterization of structurally unusual diiron NxHy complexes

Journal of the American Chemical Society

Volumn 131, Issue 30, 2009, Pages 10358-10359

  Saouma, Caroline T ^a   Müller, Peter ^a   Peters, Jonas C ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIIRON COMPLEX; HYDRAZIDO LIGANDS; LIMITING STATE;

HYDRAZINE; PHOSPHORUS COMPOUNDS;

LIGANDS;

AMIDE; BENZOQUINONE DERIVATIVE; DIAMIDE; FERROUS ION; HYDRAZINE; HYDROGEN; IMIDE; IRON; IRON COMPLEX; LIGAND; NITROGEN; PROTON;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CRYSTAL; LOW TEMPERATURE; MOLECULAR MECHANICS; NITROGEN NUCLEAR MAGNETIC RESONANCE; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; SYNTHESIS;

HYDROGEN; IRON; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; NITROGEN; ORGANOMETALLIC COMPOUNDS;

EID: 68049104344     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja903967z     Document Type: Article

References (31)

1. (a) Hoffmann, B. M.; Dean, D. R.; Seefeldt, L. C. Acc. Chem. Res. 2009, 42, 609.
2. (b) Peters, J. C.; Mehn, M. P. In Activation of SmallMolecules; Tolman, W. B., Ed.; Wiley: NewYork, 2006; pp 81-120.
3. (c) Howard, J. B.; Rees, D. C. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 17088.
4. (d) Schrock, R. R. Angew. Chem., Int. Ed. 2008, 47, 5512.
5. Barney, B. M.; Yang, T.-C.; Igarashi, R. Y.; Santos, P. C.; Laryukhin, M.; Lee, H.-I.; Hoffman, B. M.; Deadn, D. D.; Seefeldt, L. C. J. Am. Chem. Soc. 2005, 127, 14960.
6. Kästner, J.; Blöchl, P. E. J. Am. Chem. Soc. 2007, 129, 2998.
7. For example, see: (a) Hendrich, M. P.; Gunderson, W.; Behan, R. K.; Green, M. T.; Mehn, M. P.; Betley, T. A.; Lu, C. C.; Peters, J. C. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 17107.
8. (b) Smith, J. M.; Lachicotte, R. J.; Pittard, K. A.; Cundari, T. R.; Lukat-Rodgers, G.; Rodgers, K. R.; Holland, P. L. J. Am. Chem. Soc. 2001, 123, 9222.
9. (c) Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 10782.
10. (d) Brown, S. D.; Mehn, M. P.; Peters, J. C. J. Am. Chem. Soc. 2005, 127, 13146.
11. (e) Smith, J. M.; Sadique, A. R.; Cundari, T. R.; Rodgers, K. R.; Lukat-Rodgers, G.; Lachicotte, R. J.; Flaschenriem, C. J.; Vela, J.; Holland, P. L. J. Am. Chem. Soc. 2006, 128, 756.
12. (a) Vogel, C.; Heinemann, F. W.; Sutter, J.; Anthon, C.; Meyer, K. Angew. Chem., Int. Ed. 2008, 47, 2681.
13. (b) Scepaniak, J. J.; Young, J. A.; Bontchev, R. P.; Smith, J. M. Angew. Chem., Int. Ed. 2009, 48, 3158.
14. Dean, D. R.; Hoffman, B. M.; Seefeldt, L. C. Biochemistry 2007, 46, 6784.
15. (a) Goedken, V. L.; Peng, S.-M.; Molin-Norris, J.; Park, Y.-a. J. Am. Chem. Soc. 1976, 98, 8391.
16. (b) Sellmann, D.; Shaban, S. Y.; Heinemann, F. W. Eur. J. Inorg. Chem. 2004, 4591.
17. (c) Crossland, J. L.; Zakharov, L. N.; Tyler, D. R. Inorg. Chem. 2007, 46, 10476.
18. (d) Field, L. D.; Li, H. L.; Dalgarno, S. J.; Turner, P. Chem. Commun. 2008, 1680.
19. 2) complex, see ref 7d.
20. 2 complex, see: Fox, D. J.; Bergman, R. G. J. Am. Chem. Soc. 2003, 125, 8985.
21. 2), see: Dahl, L. F.; Costello, W. R.; King, R. B. J. Am. Chem. Soc. 1968, 90, 5422.
22. eq value of the N atom connectedto that proton.
23. The magnitude of these couplings may be expected to be on the order of 0-10 Hz. See: (a) von Philipsborn, W.; Müller, R. Angew. Chem., Int. Ed. Engl. 1986, 25, 383.
24. (b) Smith, M. R., III; Cheng, T. Y.; Hillhouse, G. L. J. Am. Chem. Soc. 1993, 115, 8638.
25. 3.
26. Blum, L.; Williams, I. D.; Schrock, R. R. J. Am. Chem. Soc. 1984, 106, 8316.
27. Cheng, T. Y.; Ponce, A.; Rheingold, A. L.; Hillhouse, G. L. Angew. Chem., Int. Ed. Engl. 1994, 33, 657.
28. (a) Albertin, G.; Antoniutti, S.; Lanfranchi, M.; Pelizzi, G.; Bordignon, E. Inorg. Chem. 1986, 25, 950.
29. (b) Smith, M. R., III; Hillhouse, G. L. J. Am. Chem. Soc. 1988, 110, 4066.
30. (c) Chen, Y.; Zhou, Y.; Chen, P.; Tao, Y.; Li, Y.; Qu, J. J. Am. Chem. Soc. 2008, 130, 15250.
31. Smith, M. R., III; Cheng, T. Y.; Hillhouse, G. L. J. Am. Chem. Soc. 1993, 115, 8638