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77953002982
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Commercially available from Aldrich
-
Commercially available from Aldrich.
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43
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77952968419
-
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Enantiomeric excess (ee) was determined by Mosher ester analysis; see
-
Enantiomeric excess (ee) was determined by Mosher ester analysis; see
-
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45
-
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77952960411
-
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note
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The relative and absolute configuration of this product is based on Barrett's work (14) and further confirmed by comparison of the sign of optical rotation of its derived cis -dihydroarenediol with those in the literature (see the Supporting Information).
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77952985926
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note
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Prepared from commercially available 2-bromo-5-fluorobenzaldehyde by Stille reaction using tributylvinyltin reagent in 94% yield.
-
-
-
-
50
-
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77952984055
-
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note
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Prepared from the corresponding alcohol (24) by oxidation with Collins reagent.
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55
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77953016777
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note
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Compound 19 was prepared from the reported lactone 18 (29) in three steps as follows
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56
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77952977716
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The relative and absolute configuration of this diol is based on Barrett's work. (14)
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58
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