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77952107954
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Syntheses: the furan-2-ylmethylene salicyloyl hydrazone (H2fysh) was synthesized by a procedure, which is similar to that in reference [18, Synthesis of compound 1: Pb(NO3)2 (0.033 g, 0.10 mmol) was added to a solution of H2fysh ligand (0.027 g, 0.11 mmol) in a mixed solvent of methanol and DMF (5:1 v/v, 12 mL) with stirring. After stirring for 1 h, the suspension was filtered. The filtrate was left at room temperature about 4 months. Orange-red prism crystals suitable for X-ray diffraction were obtained by slow evaporation in 53% yield based on Pb(NO3)2. Anal. Calcd for C24H18N4O6Pb: C, 43.31; H, 2.73; N, 8.42, Found: C, 43.78; H, 2.59; N, 8.29
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6Pb: C, 43.31; H, 2.73; N, 8.42%. Found: C, 43.78; H, 2.59; N, 8.29%.
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24
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77952108030
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2=0.0524 for 2718 independent reflections. The diffraction data were collected on a Rigaku Weissenberg IP diffractometer with graphite-monochromated Mo Kα radiation (λ = 0.71073 Å). The structure was solved with direct methods and refined with full-matrix least-squares (SHELX-97).
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2=0.0524 for 2718 independent reflections. The diffraction data were collected on a Rigaku Weissenberg IP diffractometer with graphite-monochromated Mo Kα radiation (λ = 0.71073 Å). The structure was solved with direct methods and refined with full-matrix least-squares (SHELX-97).
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