Lone Pair Functionality in Divalent Lead Compounds

Inorganic Chemistry

Volumn 37, Issue 8, 1998, Pages 1853-1867

  Shimoni Livny, Liat ^a   Glusker, Jenny P ^a   Bock, Charles W ^a,b  

^a FOX CHASE CANCER CENTER   (United States)

^b THOMAS JEFFERSON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000518104     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970909r     Document Type: Article

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68. AQOHPB [CN5, hemidirected], CEJMIN [CN7, hemidirected], DEBGEW [CN7, hemidirected], FITMAW [CN7, hemidirected], FUFWEI[CN3, hemidirected], FUYDOS [CN8, holodirected], GEKTEV [CN7, holodirected], GEMJAJ [CN7, hemidirected], HABCES [CN7, hemidirected], HAKYOH [CN7, hemidirected], HEBDOX (CN8, holodirected], LAJDOP [CN 8, holodirected], PBACTH02 [CN8, holodirected] PBACTH10 [CN8, holodirected], PEFDAT [CN9, holodirected], PYCXPB [CN6, hemidirected], SEYFEH [CN 7, holodirected], VEYCUX [CN6, holodirected], WENVAM [CN8 hemidirected], WEWZON [CN7, holodirected], WIJYOD [CN7, holodirected], ZIKGAB [CN8, holodirected], ZUZSES [CN8, holodirected].
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72. -, less charge is transferred to the lead and the 6p/6s population ratio is much smaller, 0.24.
73. - are calculated to be linear and planar, respectively.
74. - were found (two monodentate, two bidentate, or one mono- and one bidentate interactions), Examples of both monoand bidentate interactions are found in the CSD, although not at coordination number 4.