Inhomogeneities and chain dynamics in diene rubbers vulcanized with different cure systems

Macromolecules

Volumn 43, Issue 9, 2010, Pages 4210-4222

  Valentin J L ^a,b   Posadas, P ^a   Fernandez Torres A ^a   Malmierca, M A ^a   Gonzalez L ^a   Chasse W ^b   Saalwachter K ^b  

^a INSTITUTO DE CIENCIA Y TECNOLOGÍA DE POLÍMEROS   (Spain)

^b MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHAIN DYNAMICS; CHAIN RELAXATION; CHARACTERISTIC DIFFERENCE; CORRELATION TIME; CU-RE SYSTEM; DANGLING CHAIN; DIENE RUBBERS; HIGH-CONTENT; INHOMOGENEITIES; INHOMOGENEOUS DISTRIBUTION; LOCAL DYNAMICS; LOW FIELD; MACROSCOPIC PROPERTIES; MICROSTRUCTURAL FACTORS; NETWORK STRUCTURES; NMR SPECTROSCOPY; ORGANIC PEROXIDE; QUALITATIVE DIFFERENCES; QUANTITATIVE MEASUREMENT; RADICAL MECHANISM; RESIDUAL DIPOLAR COUPLINGS; SPATIAL HOMOGENEITY; SULFUR VULCANIZATION; VULCANIZATION PROCESS;

BUTADIENE; CURING; DYNAMICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; OXIDATION; PROTONS; SULFUR; VULCANIZATION;

RUBBER;

EID: 77951885171     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma1003437     Document Type: Article

References (85)

1. Alliger, G.; Sjothun, I. J. Vulcanization of Elastomers; Reinhold Publishing Corp.: New York, 1964.
2. Hofmann, W. Vulcanization and vulcanizing Agents; MacLaren: London, UK. 1967.
3. Chapman, A.V.; Porter, M. Natural Rubber Science and Technology; Oxford Science Publications: New York, 1988.
4. Coran, A. Y. Rubber Chem. Technol. 1995, 68, 351-375
5. Aprem, A. S.; Joseph, K.; Thomas, S. Rubber Chem. Technol. 2005, 78, 458-488
6. Coleman, M. M.; Shelton, J. R.; Koenig, J. L. Ind. Eng. Chem. Product Res. Dev. 1974, 13, 154-165
7. Krejsa, M. R.; Koenig, J. L. Rubber Chem. Technol. 1993, 66, 376-410
8. Akiba, M.; Hashim, A. S. Prog. Polym. Sci. 1997, 22, 475-521
9. Heideman, G.; Datta, R. N.; Noordermeer, J. W. M. Rubber Chem. Technol. 2004, 77, 512-541
10. Ghosh, P.; Katare, S.; Patkar, P.; Caruthers, J. M.; Venkatasubramanian, V. Rubber Chem. Technol. 2003, 76, 592-693
11. Manik, S. P.; Banerjee, S. Rubber Chem. Technol. 1970, 43, 1311-1326
12. Brydson, J. A. Rubber Chemistry; Applied Science Publishers, Ltd.: London, England. 1978.
13. Gonzalez, L.; Rodriguez, A.; del Campo, A.; Marcos-Fernandez, A. Rubber Chem. Technol. 2000, 73, 89-100
14. Posadas, P.; Fernandez, A.; Brasero, J.; Valentin, J. L.; Marcos, A.; Rodriguez, A.; Gonzalez, L. J. Appl. Polym. Sci. 2007, 106, 3481-3487
15. Dluzneski, P. R. Rubber Chem. Technol. 2001, 74, 451-492
16. Valentin, J. L.; Fernandez-Torres, A.; Posadas, P.; Marcos-Fernandez, A.; Rodriguez, A.; Gonzalez, L. J. Polym. Sci., Part B: Polym. Phys. 2007, 45, 544-556
17. Hernandez, L. G.; Diaz, A. R.; Fernandez, A. M.; Anton, C. C. Kautsch. Gummi Kunstst. 1994, 47 (10) 715-721
18. Gonzalez, L.; Rodriguez, A.; Marcos, A.; Chamorro, C. Rubber Chem. Technol. 1996, 69, 203-214
19. Treloar, L. R. G. The Physics of Rubber Elasticity, 3 rd ed.; Clarendon Press: Oxford, U.K., 1975.
20. Mark, J. E.; Erman, B.; Eirich, F. R. Science and Technology of Rubber, 2 nd ed.; Academic Press: San Diego, CA, 1994.
21. Rubinstein, M.; Colby, R. H. Polymer Physics; Oxford University Press: New York. 2003.
22. Kuhn, W.; Grün, F. Kolloid Z. Z. Polym. 1943, 101, 248-262
23. James, H. M.; Guth, E. J. Chem. Phys. 1943, 11, 455-481
24. James, H. M.; Guth, E. J. Chem. Phys. 1947, 15, 669-683
25. Flory, P. J.; Gordon, M.; McCrum, N. G. Proc. R. Soc. London A 1976, 351, 351-380
26. Flory, P. J.; Erman, B. Macromolecules 1982, 15, 800-806
27. Erman, B.; Flory, P. J. Macromolecules 1982, 15, 806-811
28. Edwards, S. F. Proc. Phys. Soc. 1967, 92, 9-16
29. Rubinstein, M.; Panyukov, S. Macromolecules 1997, 30, 8036-8044
30. Ball, R. C.; Doi, M.; Edwards, S. F.; Warner, M. Polymer. 1981, 22, 1010-1018
31. Edwards, S. F.; Vilgis, T. A. Rep. Prog. Phys. 1988, 51, 243-297
32. Rubinstein, M.; Panyukov, S. Macromolecules 2002, 35, 6670-6686
33. Vilgis, T. A. Macromolecules 1992, 25, 399-403
34. Vilgis, T. A.; Heinrich, G. Macromol. Theory Simul. 1994, 3, 271-293
35. Tan, Z.; Jaeger, R.; Vancso, G. J. Polymer 1994, 35, 3230-3236
36. Arndt, K. F.; Schreck, J. Acta Polym. 1985, 36, 56-57
37. Gillmor, J. R.; Colby, R. H.; Patel, S. K.; Malone, S.; Cohen, C. Macromolecules 1992, 25, 5241-5251
38. Valentin, J. L.; Carretero-Gonzalez, J.; Mora-Barrantes, I.; Chasse, W.; Saalwächter, K. Macromolecules 2008, 41, 4717-4729
39. Pyckout-Hintzen, W.; Springer, T.; Forster, F.; Gronski, W. Macromolecules 1991, 24, 1269-1274
40. Zaper, A. M.; Koenig, J. L. Rubber Chem. Technol. 1987, 60, 252-277
41. Orza, R. A.; Magusin, P. C. M. M.; Litvinov, V. M.; van Duin, M.; Michels, M. A. J. Macromolecules 2009, 42, 8914-8924
42. Imanishi, Y.; Adachi, K.; Kotaka, T. J. Chem. Phys. 1988, 89, 7585-7592
43. Ikeda, Y.; Higashitani, N.; Hijikata, K.; Kokubo, Y.; Morita, Y.; Shibayama, M.; Osaka, N.; Suzuki, T.; Endo, H.; Kohjiya, S. Macromolecules 2009, 42, 2741-2748
44. Ikeda, Y.; Yasuda, Y.; Hijikata, K.; Tosaka, M.; Kohjiya, S. Macromolecules 2008, 41, 5876-5884
45. Litvinov, V. M.; De, P. P. Spectroscopy of Rubbers and Rubbery Materials; Rapra Technology Ltd.: Shawbury, U.K., 2002.
46. Cohen-Addad, J. P.; Vogin, R. Phys. Rev. Lett. 1974, 33, 940-943
47. Brereton, M. G. Macromolecules 1990, 23, 1119-1131
48. Graf, R.; Heuer, A.; Spiess, H. W. Phys. Rev. Lett. 1998, 80, 5738-5741
49. Saalwächter, K. Prog. Nucl. Magn. Reson. Spectrosc. 2007, 51, 1-35
50. Litvinov, V. M. Macromolecules 2006, 39, 8727-8741
51. Callaghan, P. T.; Samulski, E. T. Macromolecules 1997, 30, 113-122
52. Demco, D. E.; Hafner, S.; Fülber, C.; Graf, R.; Spiess, H. W. J. Chem. Phys. 1996, 105, 11285-11296
53. Saalwächter, K. Macromolecules 2005, 38, 1508-1512
54. Saalwächter, K.; Sommer, J.-U. Macromol. Rapid Commun. 2007, 28, 1455-1465
55. Saalwächter, K.; Ziegler, P.; Spyckerelle, O.; Haidar, B.; Vidal, A.; Sommer, J.-U. J. Chem. Phys. 2003, 119, 3468-3482
56. Saalwächter, K.; Heuer, A. Macromolecules 2006, 39, 3291-3303
57. Weese, J. Comput. Phys. Commun. 1992, 69, 99-111
58. Weese, J. Comput. Phys. Commun. 1993, 77, 429-440
59. Saalwächter, K.; Herrero, B.; López-Manchado, M. A. Macromolecules 2005, 38, 9650-9660
60. Curro, J. G.; Pincus, P. Macromolecules 1983, 16, 559-562
61. Heinrich, G.; Vilgis, T. A. Macromolecules 1992, 25, 404-407
62. Roth, L. E.; Vega, D. A.; Valles, E. M.; Villar, M. A. Polymer. 2004, 45, 5923-5931
63. Batra, A.; Cohen, C.; Archer, L. Macromolecules 2005, 38, 7174-7180
64. Doi, M.; Edwards, S. F. The Theory of Polymer Dynamics; Clarendon Press: Oxford, U.K., 1986.
65. Pearson, D. S.; Helfand, E. Macromolecules 1984, 17, 888-895
66. Plazek, D. J. J. Polym. Sci. Polym. Phys. 1966, 4, 745-763
67. Dickie, R. A.; Ferry, J. D. J. Phys. Chem. 1966, 70, 2594-2600
68. Acosta, R. H.; Vega, D. A.; Villar, M. A.; Monti, G. A.; Valles, E. M. Macromolecules 2006, 39, 4788-4792
69. Acosta, R. H.; Monti, G. A.; Villar, M. A.; Valles, E. M.; Vega, D. A. Macromolecules 2009, 42, 4674-4680
70. Moore, C. G.; Scanlan, J. J. Polym. Sci. 1960, 43, 23-33
71. Heinen, W.; Rosenmöller, C. H.; Wenzel, C. B.; de Groot, H. J. M.; Lugtenburg, J.; van Duin, M. Macromolecules 1996, 29, 1151-1157
72. Coiai, S.; Passaglia, E.; Aglietto, M.; Ciardelli, F. Macromolecules 2004, 37, 8414-8423
73. Graessley, W. W. Adv. Polym. Sci. 1974, 16, 1-177
74. Abdel-Goad, M.; Pyckhout-Hintzen, W.; Kahle, S.; Allgaier, J.; Richter, D.; Fetters, L. J. Macromolecules 2004, 37, 8135-8144
75. Mark, J. E. Polymer Data Handbook; Oxford University Press, Inc.: New York, 1999.
76. Skinner, T. D. Rubber Chem. Technol. 1972, 45, 182-192
77. Mark, H. F. Rubber Chem. Technol. 1988, 61, G73
78. Gonzalez, L.; Valentin, J. L.; Fernandez-Torres, A.; Rodriguez, A.; Marcos-Fernandez, A. J. Appl. Polym. Sci. 2005, 98, 1219-1223
79. Suzuki, T.; Osaka, N.; Endo, H.; Shibayama, M.; Ikeda, Y.; Asai, H.; Higashitani, N.; Kokubo, Y.; Kohjiya, S. Macromolecules 2010, 43, 1556-1563
80. Dohi, H.; Horiuchi, S. Polymer 2007, 48, 2526-2530
81. Rana, M. A.; Koenig, J. L. Macromolecules 1994, 27, 3727-3734
82. Oh, S. J.; Koenig, J. L. Polymer. 1999, 4703-4708
83. Sommer, J.-U.; Saalwächter, K. Eur. Phys. J. E. 2005, 18, 167-182
84. Saalwächter, K.; Kleinschmidt, F.; Sommer, J.-U. Macromolecules 2004, 37, 8556-8568
85. Sommer, J.-U.; Chassé, W.; Valentin, J. L.; Saalwächter, K. Phys. Rev. E. 2008, 78, 051803