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Volumn 30, Issue 25, 1997, Pages 8036-8044

Nonaffine deformation and elasticity of polymer networks

Author keywords

[No Author keywords available]

Indexed keywords

ELASTICITY; MOLECULAR STRUCTURE; PLASTIC DEFORMATION; STRAIN; STRESS ANALYSIS;

EID: 0031384689     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma970364k     Document Type: Article
Times cited : (241)

References (41)
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    • Wall, F. T.; Flory, P. J. J. Chem. Phys. 1951, 19, 1435. Flory, P. J. Proc. R. Soc. London 1976, A. 351, 351.
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  • 19
    • 0003544037 scopus 로고
    • Cornell University: Ithaca, NY
    • For simplicity, we do not consider semidilute solutions with large density fluctuations on scales smaller than the correlation length. The results of this paper can be extended to semidilute solutions using scaling concepts, see: de Gennes, P. G. Scaling Concepts in Polymer Physics; Cornell University: Ithaca, NY, 1979.
    • (1979) Scaling Concepts in Polymer Physics
    • De Gennes, P.G.1
  • 20
    • 85033180815 scopus 로고    scopus 로고
    • note
    • The correlations in positions of potential cross-links, which appear because of the coherence through the paths connecting these points, can be neglected in our mean field consideration since such correlations give only small fluctuation corrections to the mean field free energy of the dense network.
  • 21
    • 85033164843 scopus 로고    scopus 로고
    • note
    • 2N. This leads to a tube with oscillating walls. Since we expect topological entanglements to confine the whole strand rather than individual monomers, this case, N > n, is not a good representation of confining potential.
  • 22
    • 85033188136 scopus 로고    scopus 로고
    • note
    • Note that it has to be modified for deformations affecting the volume in swollen networks. The elasticity of virtual springs depends on the polymer concentration in such nonGaussian phantom networks.
  • 23
    • 85033166771 scopus 로고    scopus 로고
    • note
    • c = kTc(1 - 2/f)/N, where f is the functionality of cross-links, see section 2.
  • 26
    • 3743105722 scopus 로고
    • Priss, L. S. Dokl. Akad. Nauk SSSR 1957, 116, 225; Sou. Phys. Tech. Phys. 1958, 3, 597; Zh. Tekh. Phys. 1958, 28, 636.
    • (1957) Dokl. Akad. Nauk SSSR , vol.116 , pp. 225
    • Priss, L.S.1
  • 27
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    • Priss, L. S. Dokl. Akad. Nauk SSSR 1957, 116, 225; Sou. Phys. Tech. Phys. 1958, 3, 597; Zh. Tekh. Phys. 1958, 28, 636.
    • (1958) Sou. Phys. Tech. Phys. , vol.3 , pp. 597
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    • Priss, L. S. Dokl. Akad. Nauk SSSR 1957, 116, 225; Sou. Phys. Tech. Phys. 1958, 3, 597; Zh. Tekh. Phys. 1958, 28, 636.
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    • Mooney, M. J. Appl. Phys. 1948, 19, 434. Rivlin, R. S. Philos. Trans. R. Soc. London, Ser. A 1948, 241, 379.
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    • Mooney, M.1
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    • Doctoral Dissertation, Northwestern University
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.