Dithiodiolate Ligands: Group 4 complexes and application in lactide polymerization

Inorganic Chemistry

Volumn 49, Issue 9, 2010, Pages 3977-3979

  Sergeeva, Ekaterina ^a   Kopilov, Jacob ^a   Goldberg, Israel ^a   Kol, Moshe ^a  

^a TEL AVIV UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

DILACTIDE; DIOXANE DERIVATIVE; LIGAND; ORGANOMETALLIC COMPOUND; THIOL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; DIOXANES; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM; SULFHYDRYL COMPOUNDS;

EID: 77951566613     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic100390x     Document Type: Article

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32. Although polymerization demonstrates a relatively high activity toward l -lactide, it is significantly slower than that of rac -lactide because of a mild kinetic preference for consecutive polymerization of d-and l -lactide to give heterotactically enriched poly(lactide).