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77951457281
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note
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3), 49.7 (d, C-3), 35.7 (t), 31.7 (t), 29.3 (t), 29.1 (2t), 24.7 (t), 22.6 (t), 14.0 (q).
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50
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52
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77951448609
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note
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2 was added and the solution was analysed on chiral HRGC (γ-CDX).
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53
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20644469267
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54
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77951475689
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note
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258 +0.26, Δε225 -10.58.
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-
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-
55
-
-
77951438845
-
-
note
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223 +9.3.
-
-
-
-
56
-
-
77951496392
-
-
note
-
25 = -9.5 (c 0.49, MeOH), >99% e.e.
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-
-
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57
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-
77951460073
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note
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4, the solvent was removed and (-)-3 was recovered (>99% e.e., 0.056 g, 71% yield).
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58
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0001769386
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