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Volumn 46, Issue 24, 2007, Pages 4477-4480

Metal-oxide-based nucleation process under confined conditions: Two mixed-valence V6-type aggregates closing the W48 wheel-type cluster cavities

Author keywords

Confined geometries; Directed assembly; Electronic structure; Mixed valent compounds; Polyoxometalates

Indexed keywords

CLUSTER ANALYSIS; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; MAGNETIC PROPERTIES; METAL OXIDE CERAMICS; VANADIUM COMPOUNDS;

EID: 34250788541     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200700441     Document Type: Article
Times cited : (101)

References (29)
  • 2
    • 34250740154 scopus 로고    scopus 로고
    • Prebiotic Chemistry: From Simple Amphiphiles to Protocell Models: D. W. Deamer, J. P. Dworkin, Top. Curr. Chem. 2005, 259 (Ed.: P. Walde).
    • b) "Prebiotic Chemistry: From Simple Amphiphiles to Protocell Models": D. W. Deamer, J. P. Dworkin, Top. Curr. Chem. 2005, 259 (Ed.: P. Walde).
  • 5
    • 0037888199 scopus 로고    scopus 로고
    • 37-type species is formed: A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, M. J. Koop, Chem. Eur. J. 1998, 4, 1000-1006.
    • 37-type species is formed: A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, M. J. Koop, Chem. Eur. J. 1998, 4, 1000-1006.
  • 7
    • 34250702422 scopus 로고    scopus 로고
    • 25- S. S. Mai, U. Kortz, Angew. Chem. 2005, 117, 3843-3846;
    • 25- (S. S. Mai, U. Kortz, Angew. Chem. 2005, 117, 3843-3846;
  • 8
    • 20644448598 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 3777-3780) and (Ln4(H2O)28-(H2O) 28[K⊂P8W48O184(H 4W4O12)2Ln2(H 2O)10]13-}x Ln, La, Ce, Pr, Nd
    • x (Ln = La, Ce, Pr, Nd)
  • 9
    • 34250704013 scopus 로고    scopus 로고
    • M. Zimmermann, N. Belai, R. J. Butcher, M. T. Pope, Symposium on Nano-structures and Physicochemical Properties of Polyoxometalate Superclusters and Related Colloid Particles, Kanagawa, Japan, November 21-25, 2004;
    • (M. Zimmermann, N. Belai, R. J. Butcher, M. T. Pope, Symposium on "Nano-structures and Physicochemical Properties of Polyoxometalate Superclusters and Related Colloid Particles", Kanagawa, Japan, November 21-25, 2004;
  • 10
    • 34250718399 scopus 로고    scopus 로고
    • M. Zimmermann, Diplofnarbeit (supervised by M.T.P.), Bielefeld University, 2005;
    • M. Zimmermann, Diplofnarbeit (supervised by M.T.P.), Bielefeld University, 2005;
  • 12
    • 34250760100 scopus 로고    scopus 로고
    • + cations (German Research Foundation meeting on Molecular Magnetism, Bad Durkheim, Germany, January 15-17, 2006).
    • + cations (German Research Foundation meeting on Molecular Magnetism, Bad Durkheim, Germany, January 15-17, 2006).
  • 13
    • 34250722431 scopus 로고    scopus 로고
    • Crystal data for 2, H172K16Na 12O292P8V12W48, M, 15 430.70 g mol-1, triclinic, space group P1, a, 19.7360(14, b, 20.7245(15, c, 21.1487(16) Å, α, 104.134(1, β, 117.561(1, γ, 104.410(1)°, V, 6745.6(9) Å3, Z, 1, ρ, 3.799 g cm-3, μ, 21.203 mm-1, F (000, 6892, Crystal size, 0.45 x 0.30 x 0.25 mm3. A total of 39 426 reflections (1.64 < θ < 27.02°) were collected of which 28 343 reflections were unique (R(int, 0.0382, An empirical absorption correction using equivalent reflections was performed with the program SADABS 2.03. The structure was solved with the program SHELXS-97 and refined using SHELXL-97 to R, 0.0589 for 25 047 reflections with I > 2σI, R, 0.0665 for all reflections; Ma
    • Kα radiation, graphite monochromator; hemisphere data collection in ω at 0.3° scan width in three runs with 606, 435, and 230 frames (φ = 0, 88, and 180°) at a detector distance of 5 cm). (SHELXS/L, SADABS from G. M. Sheldrick, University of Gottingen 1997/2001; structure graphics with DIAMOND 2.1 from K. Brandenburg, Crystal Impact GbR, 2001). Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-417620.
  • 15
  • 16
    • 34250766448 scopus 로고    scopus 로고
    • Although the nonrigidity of the {P8W48} assembly should not have been unexpected, the other reported derivatives[6] retain the essentially square conformation
    • [6] retain the essentially "square" conformation.
  • 17
    • 0001154167 scopus 로고    scopus 로고
    • 6- (Y. Jeannin, J. Martin-Frère, J. Am. Chem. Soc. 1981, 103, 1664-1667)
    • 6- (Y. Jeannin, J. Martin-Frère, J. Am. Chem. Soc. 1981, 103, 1664-1667)
  • 18
    • 37049089142 scopus 로고    scopus 로고
    • 6- (C. M. Tourné, G. F. Tourné, T. J. R. Weakley, J. Chem. Soc. Dalton Trans. 1986, 2237-2242).
    • 6- (C. M. Tourné, G. F. Tourné, T. J. R. Weakley, J. Chem. Soc. Dalton Trans. 1986, 2237-2242).
  • 19
    • 28144462780 scopus 로고    scopus 로고
    • 2O ligands on the outer periphery for compound types, see, for example: A. Müller, S. Roy, J. Mater. Chem. 2005, 15, 4673-4677
    • 2O ligands on the outer periphery (for compound types, see, for example: A. Müller, S. Roy, J. Mater. Chem. 2005, 15, 4673-4677
  • 22
    • 34250746169 scopus 로고    scopus 로고
    • Single crystal EPR studies on magnetic interactions in poly-oxometalates containing several paramagnetic ions: Y. H. Cho, PhD Thesis, Sogang University, Seoul, Korea, 1996.
    • "Single crystal EPR studies on magnetic interactions in poly-oxometalates containing several paramagnetic ions": Y. H. Cho, PhD Thesis, Sogang University, Seoul, Korea, 1996.
  • 28
    • 0020765376 scopus 로고    scopus 로고
    • VI.
    • VI.
  • 29


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.