The wheel-shaped Cu20 tungstophosphate [Cu20Cl(OH) 24(H2O)12(P8W48O 184)]25- ion

Angewandte Chemie - International Edition

Volumn 44, Issue 24, 2005, Pages 3777-3780

  Mal, Sib Sankar ^a   Kortz, Ulrich ^a  

^a JACOBS UNIVERSITY BREMEN   (Germany)

Author keywords

Chemistry; Copper; Polyoxometalates; Supramolecular; Template synthesis; Tungsten

Indexed keywords

CRYSTAL SYMMETRY; DERIVATIVES; MOLECULAR STRUCTURE; NEGATIVE IONS; PARAMAGNETISM; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

HIGH SYMMETRY; METAL IONS; TEMPLATES;

COPPER COMPOUNDS;

EID: 20644448598     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500682     Document Type: Article

References (38)

1. J. Berzelius, Poggendorff's Ann. Phys. 1826, 6, 369.
2. a) J. F. Keggin, Nature 1933, 131, 908-909;
3. b) J. F. Keggin, Proc. R. Soc. London Ser. A 1934, 144, 75-77.
4. M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer, Berlin, 1983.
5. M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56-70;
6. Angew. Chem. Int. Ed. Engl. 1991, 30, 34-48.
7. Polyoxometalates: from Platonic Solids to Anti Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994.
8. Chem. Rev. 1998, 98, 1-389 (Special Thematic Issue on Polyoxometalates).
9. Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 2001.
10. Polyoxometalate Chemistry for Nano-Composite Design (Eds.: T. Yamase, M. T. Pope), Kluwer, Dordrecht, 2002.
11. C. L. Hill, C. M. Prosser-McCartha, Coord. Chem. Rev. 1995, 143, 407-455.
12. a) A. Müller, B. Botar, S. K. Das, H. Bögge, M. Schmidtmann, A. Merca, Polyhedron 2004, 23, 2381-2385;
13. b) A. Müller, S. Q. N. Shah, H. Bögge, M. Schmidtmann, Nature 1999, 397, 48-50.
14. K. Wassermann, M. H. Dickman, M. T. Pope, Angew. Chem. 1997, 109, 1513-1516;
15. Angew. Chem. Int. Ed. Engl. 1997, 36, 1445-1448.
16. Examples of recent work include: a) B. S. Bassil, S. Nellutla, U. Kortz, A. C. Stowe, J. van Tol, N. S. Dalal, B. Keita, L. Nadjo, Inorg. Chem. 2005, 44, 2659-2665;
17. b) L.-H. Bi, U. Kortz, S. Nellutla, A. C. Stowe, N. S. Dalal, B. Keita, L. Nadjo, Inorg. Chem. 2005, 44, 896-903;
18. c) A. C. Stowe, S. Nellutla, N. S. Dalal, U. Kortz, Eur. J. Inorg. Chem. 2004, 3792-3797;
19. d) D. Jabbour, B. Keita, I. M. Mbomekalle, L. Nadjo, U. Kortz, Eur. J. Inorg. Chem. 2004, 2036-2044;
20. e) U. Kortz, S. Nellutla, A. C. Stowe, N. S. Dalal, U. Rauwald, W. Danquah, D. Ravot, Inorg. Chem. 2004, 43, 2308-2317;
21. f) U. Kortz, S. Nellutla, A. C. Stowe, N S. Dalal, J. van Tol, B. S. Bassil, Inorg. Chem. 2004, 43, 144-154.
22. A. J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K. A. Abboud, G. Christou, Angew. Chem. 2004, 116, 2169-2173;
23. Angew. Chem. Int. Ed. 2004, 43, 2117-2121.
24. a) R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141-143;
25. b) T. Lis, Acta Crystallogr. Sect. B 1980, 36, 2042-2046.
26. J. M. Clemente-Juan, E. Coronado, Coord. Chem. Rev. 1999, 193-195, 361-394.
27. a) L.-H. Bi, U. Kortz, Inorg. Chem. 2004, 43, 7961-7962;
28. b) T. M. Anderson, W. A. Neiwert, K. I. Hardcastle, C. L. Hill, Inorg. Chem. 2004, 43, 7353-7358;
29. c) P. Mialane, A. Dolbecq, J. Marrot, E. Rivière, F. Sécheresse, Angew. Chem. 2003, 115, 3647-3650;
30. Angew. Chem. Int. Ed. 2003, 42, 3523-3526;
31. d) J. M. Clemente-Juan, E. Coronado, J. R. Galán-Mascarós, C. J. Gómez-García, Inorg. Chem. 1999, 38, 55-63;
32. e) K. Wassermann, R. Palm, H.-J. Lunk, J. Fuchs, N. Steinfeldt, R. Stösser, Inorg. Chem. 1995, 34, 5029-5036;
33. f) T. J. R. Weakley, J. Chem. Soc. Chem. Commun. 1984, 1406-1407.
34. a) R. Contant, A. Tézé, Inorg. Chem. 1985, 24, 4610-4614;
35. b) R. Contant. Inorg. Synth. 1990, 27, 110.
36. 21- was recently presented at a conference. M. T. Pope, International Symposium on Nano-structures and Physicochemical Properties of Polyoxometalate Superclusters and Related Colloid Particles, Shonan Village Center. Kanagawa, Japan, 21.-25. November 2004.
37. -3. Routine Lorentz and polarization corrections were applied and an absorption correction was performed using the SADABS program (G. M. Sheldrick, Siemens Analytical X-ray Instrument Division, Madison, WI, 1995). Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49) 7247-808-666; e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-415126.
38. I. D. Brown, D. Altermatt, Acta Crystallogr. Sect. B 1985, 41, 244-247.