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Volumn 47, Issue 36, 2008, Pages 6881-6884

Reversible redox reactions in an extended polyoxometalate framework solid

Author keywords

Cluster compounds; Framework materials; Polyoxometalates; Redox chemistry; Self assembly

Indexed keywords

METALLIC COMPOUNDS; SPECTROELECTROCHEMISTRY; WATER;

EID: 53249123412     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200802594     Document Type: Article
Times cited : (124)

References (27)
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    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 4635-4637
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    • Angew. Chem. Int. Ed. 2008, 47, 4699-4702;
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 4699-4702
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    • 46749142141 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 4388-4391.
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 4388-4391
  • 18
    • 34250741996 scopus 로고    scopus 로고
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    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 3900-3904
  • 20
    • 53249143585 scopus 로고    scopus 로고
    • A family of isostructural materials has been synthesized where M = manganese or cobalt, and X = silicon or germanium.
    • A family of isostructural materials has been synthesized where M = manganese or cobalt, and X = silicon or germanium.
  • 22
    • 53249139906 scopus 로고    scopus 로고
    • Crystal data and structure refinement for 1ox: [C 160H496N40Mn12O356Si 7W72, Mr, 22770 g mol-1; a tetrahedral brown crystal (0.18 × 0.15 × 0.15 mm3) was analyzed with a Rigaku Image Plate diffractometer using MoKα radiation (λ, 0.71073 Å) at 150(2) K. Cubic, space group I43d, a, 38.541(5) Å V, 57249(12) Å3, Z, 4, 1, 2.631 g cm-3, μ, Mo Kα, 14.757 mm-1, F(000, 41240, 30628 reflections measured, of which 6229 are independent, 364 refined parameters, R1, 0.0829, wR2, 0.2010. Many data sets were collected of the native material, and the material returned to the oxidized state during the redox cycles and the average unit cell parameter was 38.54(4) with a maximum variation of ±0.02
    • red) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 24
    • 0033519328 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1999, 38, 1292-1294.
    • (1999) Angew. Chem. Int. Ed , vol.38 , pp. 1292-1294


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.