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Volumn 12, Issue 6, 2010, Pages 1264-1267

Novel aryl and heteroaryl acyl sulfamide synthesis via microwave-assisted palladium-catalyzed carbonylation

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOMETALLIC COMPOUND; PALLADIUM; SULFONAMIDE;

EID: 77949860758     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol100083w     Document Type: Article
Times cited : (17)

References (41)
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    • For a general review on carbonylation reactions see: Barnard, C. F. J. Organometallics 2008, 5402-5422.
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  • 24
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    • Kappe, C.O.1
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    • Experimental setup: All reactions were performed with a CEM Discover single mode microwave reactor equipped with a 300 W source. A 10 mL fiber optic accessory was equipped with, a gas inlet to allow introduction of carbon monoxide gas to the reaction vessel and each of the reactions was performed in a CEM 10 mL microwave reaction vial. All temperature measurements were performed with, a fiber optic probe
    • Experimental setup: All reactions were performed with a CEM Discover single mode microwave reactor equipped with a 300 W source. A 10 mL fiber optic accessory was equipped with, a gas inlet to allow introduction of carbon monoxide gas to the reaction vessel and each of the reactions was performed in a CEM 10 mL microwave reaction vial. All temperature measurements were performed with, a fiber optic probe.
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    • 2 10 mol %, triethylamine (3 equiv), 0.3 M dioxane, 4 h, 100 °C, 65 psi CO.
    • 2 10 mol %, triethylamine (3 equiv), 0.3 M dioxane, 4 h, 100 °C, 65 psi CO.
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    • 2 10 mol %, triethylamine (3 equiv), DMAP (1 equiv), 0.3 M dioxane, 4 h, 100 °C, 65 psi CO
    • 2 10 mol %, triethylamine (3 equiv), DMAP (1 equiv), 0.3 M dioxane, 4 h, 100 °C, 65 psi CO.


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