Generation and intermolecular trapping of 1,2-diaza-4silacyclopentane-3,5- diyls in the denitrogenation of 2,3,5,6-tetraaza-7silabicyclo[2.2.1]hept-2-ene: An experimental and computational study

Journal of Organic Chemistry

Volumn 75, Issue 6, 2010, Pages 1956-1960

  Nakamura, Takeshi ^a   Takegami, Akinobu ^b   Abe, Manabu ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; COMPUTATIONAL STUDIES; DENITROGENATION; DIRADICALS; EXPERIMENTAL OBSERVATION; INTERMOLECULAR TRAPPING; LOW-ACTIVATION ENERGY; NITROGEN ATOM; POLYCYCLIC COMPOUNDS; PREPARATION CONDITIONS; SINGLET STATE; TRIPLET STATE;

CHEMICAL REACTIONS; NITROGEN COMPOUNDS; PARAFFINS;

ACTIVATION ENERGY;

1,2 DIAZA 4 SILACYCLOPENTANE 3,5 DIYL DERIVATIVE; 2,3,5,6 TETRAAZA 7 SILABICYCLO[2.2.1]HEPT 2 ENE; 4 METHYL 1,2,4 TRIAZOLE 3,5 DIONE; 4 PHENYL 1,2,4 TRIAZOLE 3,5 DIONE; 4,4 DI TERT BUTYL 3,5 DIPHENYL 4H 1,2,4 DIAZASILOLE; ALKANE DERIVATIVE; AZOALKANE DERIVATIVE; BENZENE DERIVATIVE; CYCLOPENTANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; SYNTHESIS; THERMODYNAMICS;

EID: 77949833528     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo902714c     Document Type: Article

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