Experimental probe for hyperconjugative resonance contribution in stabilizing the singlet state of 2,2-dialkoxy-1,3-diyls: Regioselective 1,2-oxygen migration

Journal of the American Chemical Society

Volumn 128, Issue 24, 2006, Pages 8008-8014

  Abe, Manabu ^a   Hattori, Masanori ^a   Takegami, Akinobu ^a   Masuyama, Araki ^a   Hayashi, Takashi ^a   Seki, Shu ^a   Tagawa, Seiichi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; ELECTRON TRANSITIONS; ELECTRONIC STRUCTURE; OXYGEN; SUBSTITUTION REACTIONS;

1,2-OXYGEN MIGRATION; HYPERCONJUGATIVE RESONANCE STRUCTURE; SINGLET STATE; ZWITTERIONIC CHARACTERISTICS;

AROMATIC COMPOUNDS;

4 METHOXYPHENYL GROUP; ALKOXY GROUP; ALKYL GROUP; AMPHOLYTE; CYCLOPENTANE 1,3 DIYL DERIVATIVE; FUNCTIONAL GROUP; OXYGEN; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CONJUGATION; EXPERIMENTATION; HYPERCONJUGATIVE RESONANCE; MOLECULAR DYNAMICS; MOLECULAR PROBE; MOLECULAR STABILITY; OXYGEN TRANSPORT; STEREOCHEMISTRY;

EID: 33745432293     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0617688     Document Type: Article

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