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1042293895
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note
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int = 0.0356), 125 parameters, R1 [I > 2σ(I)] = 0.0393, wR2 [all data] = 0.1226. Data were collected using an oil-coated shock-cooled crystal on a Bruker-AXS CCD 1000 diffractometer (λ = 0.71073 Å, Mo Kα). Semiempirical absorption corrections were employed.15 The structures were solved by direct methods (SHELXS-97),16 and refined using the least-squares method on F2.17 Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-228652 (cis-2), 228653 (trans-2), 228654 (3), 228655 (4), 228656 (5), and 228657 (6), Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1 EZ, UK [fax: (+44)1223-336-033: e-mail: deposit@ccdc.cam.ac.uk].
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24
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1042270776
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note
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3 anion.
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25
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0035498332
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For the use of organoboranes as a source of radicals, see: Ollivier, C.; Renaud, P. Chem. Rev. 2001, 101. 3415-3434.
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26
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1042293893
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Program for data correction, Bruker-AXS
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SADABS, Program for data correction, Bruker-AXS.
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SADABS
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