Electrochemical allylation of carbonyl compounds in aqueous electrolyte catalyzed by zinc

Chemical Communications

Volumn 46, Issue 13, 2010, Pages 2286-2288

  Huang, Jing Mei ^a   Ren, Hai Rui ^a  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BENZALDEHYDE; CARBONYL DERIVATIVE; ELECTROLYTE; ZINC;

ALLYLATION; AQUEOUS SOLUTION; ARTICLE; ELECTROCHEMISTRY;

EID: 77949642121     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b922897g     Document Type: Article

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39. The yield was very low when the chamber was separated by sintered glass. For the cation-exchange membrane, Nafion® 324 and Nafion® 966 did not give good yields also. In these cases, migration of the organic starting material to the anode chamber was observed.
40. See ESI for cyclic voltammograms.
41. 4Cl (0.1 M) and THF (5 mL:5 mL) in cathode chamber produced a layer of loosely packed Zn particles on the Zn electrode. And the electrodeposited Zn particles can be easily scraped from the Zn electrode.
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45. See ESI (a table) for the yields and Zn consumption for each cycle.