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2) in a 200 % cell could be realized and current yields of up to 190 % were obtained; T. Arns, E. Steckhan, Diplomarbeit, Bonn, 1998 and reference [1].
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3 salts proceeds at very negative potentials (≈ -2.2 V versus Ag/AgCl) accompanied with a "trace crossing" in the back sweep of the cyclic voltammogram.
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0037901596
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note
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The electrochemically generated allylic anion might be absorbed on the electrode surface and the concentration of an allyllithium species seems to be low in solution.
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