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Volumn 48, Issue 24, 2009, Pages 4409-4413

Tellurium(II)-centered dications from the pseudohalide "Te(OTf) 2"

Author keywords

Carbenes; N ligands; Polycations; Synthetic methods; Tellurium

Indexed keywords

CARBENES; DICATIONS; ELECTROPHILIC REAGENTS; HIGH YIELD; N LIGANDS; POLYCATIONS; SYNTHETIC METHODS;

EID: 70349786172     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200901495     Document Type: Article
Times cited : (47)

References (39)
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    • Crystal data for 8: Formula, C39H42Cl 2F6N2O6S2Te, T= 150(2) K, Mτ= 1011.37 g mol-1, crystal size: 0.31 × 0.26 × 0.08 mm, orthorhombic, space group Pna2(1, a, 18.491(4, b, 12.156(2, c, 19.453(4) Å, V= 4372(2) Å3, Z, 4, ρcalcd= 1.536 g cm-3, μ= 0.969 mm-1, 2θmax, 27.49°, 9395 reflections measured, 9395 unique, refined parameters, 524, R1(I) > 2σ(I, 0.0524, wR 2(F2, 0.1146, R1(all data, 0.0875, wR 2(all data, 0.1310, ρ(e)(min/max, 1.183/0.970 e Å-3. Crystal data for 9: Formula, C 31.5H42F6N8O6S 2Te, T= 150(2) K, Mr= 1040.80 g mol-1, crystal size: 0.30 × 0.30 × 0.20 mm, tricl
    • -3. CCDC 711250 (8), 711251 (9), 719664 (10), 722582 (11) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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    • For a structurally characterized phosphorus analogue of a carbodication, the only other p-block representative, see
    • For a structurally characterized phosphorus analogue of a carbodication, the only other p-block representative, see : B. D. Ellis, C. A. Dyker, A. Decken, C. L. B. Macdonald, Chem. Commun. 2005, 1965-1967.
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    • For a recent very detailed computational investigation on carbodicarbenes and related carbon(O) compounds see: a) R. Tonner, G. Frenking, Angew. Chem. 2007, 119, 8850-8853;
    • For a recent very detailed computational investigation on carbodicarbenes and related carbon(O) compounds see: a) R. Tonner, G. Frenking, Angew. Chem. 2007, 119, 8850-8853;
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.