Fast separation and determination of sterols in vegetable oils by ultraperformance liquid chromatography with atmospheric pressure chemical ionization mass spectrometry detection

Journal of Agricultural and Food Chemistry

Volumn 58, Issue 5, 2010, Pages 2771-2776

  Lerma García, María Jesús ^a   Simó Alfonso, Ernesto Francisco ^a   Méndez, Alberto ^b   Lliberia, Josep Lluís ^b   Herrero Martínez, José Manuel ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

^b Ronda de Can Fatjó ^*  (Spain)

Author keywords

Botanical origin; Mass spectrometry; Sterols; Ultraperformance liquid chromatography; Vegetable oils

Indexed keywords

STEROL; VEGETABLE OIL;

ARTICLE; ATMOSPHERIC PRESSURE; CHEMISTRY; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; METHODOLOGY;

ATMOSPHERIC PRESSURE; CHROMATOGRAPHY, LIQUID; MASS SPECTROMETRY; PLANT OILS; STEROLS;

EID: 77949345171     PISSN: 00218561     EISSN: 15205118     Source Type: Journal    
DOI: 10.1021/jf9043887     Document Type: Article

References (33)

1. Lercker, G.; Rodriguez-Estrada, M. T. Chromatographic analysis of unsaponifiable compounds of olive oils and fat-containing foods. J. Chromatogr. A 2000, 881, 105-129.
2. Piironen, V.; Lindsay, D. G.; Miettinen, T. A.; Toivo, J.; Lampi, A. M. Plant sterols: biosynthesis, biological function and their importance to human nutrition. J. Sci. Food Agrie. 2000, 80, 939.
3. Perona, J. S.; Cabello-Moruno, R.; Ruiz-Gutierrez, V. The role of virgin olive oil components in the modulation of endothelial function. J. Nutr. Biochem. 2006, 17, 429.
4. Morchio, G.; Amelotti, G.; Bocca, A.; Bovio, V.; Conte, L.; Cozzoli, O.; Cremonesi, L.; Fascioli, R.; Giro, L.; Grieco, D.; Lercker, G.; Mariani, C.; Pierattini, G.; Sarti, E; Zunin, P. Analisi gas cromatografica degli steroli con l'impiego di colonne capillari. Risultati di una sperimentazione interlaboratorio. Riv. Ital. Sostanze Grasse 1989, 66, 531-538.
5. Mariáni, C.; Bellan, G.; Grob, K. On the complexity of sterol fraction in edible fats and oils. Separation of "campesterol" into two epimers. Riv. Ital. Sostanze Grasse 1995, 72, 97-104.
6. Cert, A.; Moreda, W.; Pérez-Camino, M. G Chromatographic analysis of minor constituents in vegetable oils. J. Chromatogr. A 2000, 881, 131-148.
7. Aparicio, R.; Aparicio-Ruiz, R. Authentication of vegetable oils by chromatographic techniques. J. Chromatogr. A 2000, 881, 93-104.
8. Aparicio, R. In Handbook of Olive Oil: Analysis and Properties; Harwood, J. L., Aparicio, R., Eds.; Aspen, Gaithersburg, MD, 1999; p285.
9. Kiritsakis, A. K. In Olive Oil Handbook; American Oil Chemists' Society: Champaign, IL, 1998; p 20.
10. Cercaci, L.; Passalacqua, G.; Poerio, A.; Rodriguez-Estrada, M. T.; Lercker, G. Composition of total sterols (4-desmethyl-sterols) in extravirgin olive oils obtained with different extraction technologies and their influence on the oil oxidative stability. Food Chem. 2007, 102, 66-76.
11. Rivera del Alamo, R. M.; Fregapane, G.; Aranda, F.; GómezAlonso, S.; Salvador, M. D. Sterol and alcohol composition of Cornicabra virgin olive oil: the campesterol content exceeds the upper limit of 4% established by EU regulations. Food Chem. 2004, 84, 533-537.
12. Sánchez-Casas, J.; Osorio Bueno, E.; Montaño García, A. F.; Martinez Cano, M. Sterol and erythrodiol + uvaol content of virgin olive oils from cultivars of Extremadura (Spain). Food Chem. 2004, 87, 225-230.
13. Galeano Diaz, T.; Durán Merás, I.; Sánchez Casas, J.; Alexandre Franco, M. F. Characterization of virgin olive oils according to its triglycerides and sterols composition by chemometric methods. Food Control 2005, 16, 339-347.
14. Parcerisa, J.; Casals, I.; Boatella, J.; Codony, R.; Rafecas, M. Analysis of olive and hazelnut oil mixtures by high-performance liquid chromatography-atmospheric pressure chemical ionisation mass spectrometry of triacylglycerols and gas-liquid chromatography of non-saponifiable compounds (tocopherols and sterols). J. Chromatogr. A 2000, 881, 149-158.
15. Matos, L. C.; Cunha, S. C.; Amaral, J. S.; Pereira, J. A.; Andrade, P. B.; Seabra, R. M.; Oliveira, B. P. P. Chemometric characterization of three varietal olive oils (Cvs. Cobrançosa, Madural and Verdeal Transmontana) extracted from olives with different maturation indices. Food Chem. 2007, 102, 406-414.
16. Thanh, T. T.; Vergnes, M. F.; Kaloustian, J.; El-Moselhy, T. F.; Amiot-Carlin, M. J.; Portugal, H. Effect of storage and heating on phytosterol concentrations in vegetable oils determined by GC/MS. J. Sci. Food Agric. 2006, 86, 220-225.
17. Cunha, S. S.; Fernandes, J. O.; Oliveira, B. P. P. Quantification of free and esterified sterols in Portuguese olive oils by solid-phase extraction and gas chromatography-mass spectrometry. J. Chromatogr. A 2006, 1128, 220-227.
18. Abidi, S. L. Capillary electrochromatography of sterols and related steryl esters derived from vegetable oils. J. Chromatogr. A 2004, 1059, 199-208.
19. Lerma-García, M. J.; Simó-Alfonso, E. F.; Ramis-Ramos, G.; Herrero-Martínez, J. M. Rapid determination of sterols in vegetable oils by CEC using methacrylate ester-based monolithic columns. Electrophoresis 2008, 29, 4603-4611.
20. Lerma-García, M. J.; Ramis-Ramos, G.; Herrero-Martínez, J. M.; Simó-Alfonso, E. F. Classification of vegetable oils according to their botanical origin using sterol profiles established by direct infusion mass spectrometry. Rapid Commun. Mass Spectrom. 2008, 22, 973-978.
21. Cañabate-Díaz, B.; Segura-Carretero, A.; Fernández-Gutiérrez, A.; Belmonte Vega, A.; Garrido Frenich, A.; Martínez Vidal, J. L.; Duran Martos, J. Separation and determination of sterols in olive oil by HPLC-MS. Food Chem. 2007, 102, 593-598.
22. Martínez-Vidal, J. L.; Garrido-Frenich, A.; Escobar-García, M. A.; Romero-González, R. LC-MS determination of sterols in olive oil. Chromatographia 2007, 65, 695-699.
23. Segura-Carretero, A.; Carrasco-Pancorbo, A.; Cortacero, S.; Gori, A.; Cerretani, L.; Fernández-Gutiérrez, A. A simplified method for HPLC-MS analysis of sterols in vegetable oil. Eur. J. Lipid Sci. Technol. 2008, 110, 1142-1149.
24. Kawanishi, H.; Toyo'oka, T.; Ito, K.; Maeda, M.; Hamada, T.; Fukushima, T.; Kato, M.; Inagaki, S. Rapid determination of histamine and its metabolites in mice hair by ultra-performance liquid chromatography with time-of-flight mass spectrometry. J. Chromatogr. A 2006, 1132, 148-156.
25. Barceló-Barrachina, E.; Moyano, E.; Galcerán, M. T.; Lliberia, J. L.; Bago, B.; Cortes, M. A. Ultra-performance liquid chromatographytandem mass spectrometry for the analysis of heterocyclic amines in food. J. Chromatogr. A 2006, 1125, 195-203.
26. Leandro, C. C.; Hancock, P.; Fussell, R. J.; Keely, B. J. Comparison of ultra-performance liquid chromatography and high-performance liquid chromatography for the determination of priority pesticides in baby foods by tandem quadrupole mass spectrometry. J. Chromatogr. A 2006, 1103, 94-101.
27. Li, X.; Xiong, Z.; Ying, X.; Cui, L.; Zhu, W.; Li, F. A rapid ultraperformance liquid chromatography-electrospray ionization tandem mass spectrometric method for the qualitative and quantitative analysis of the constituents of the flower of Trollius ledibouri Reichb. Anal. Chim. Acta 2006, 580, 170-180.
28. Lu, B.; Zhang, Y.; Wu, X.; Shi, J. Separation and determination of diversiform phytosterols in food materials using supercritical carbon dioxide extraction and ultraperformance liquid chromatographyatmospheric pressure chemical ionization-mass spectrometry. Anal. Chim. Acta 2007, 588, 50-63.
29. Suárez, M.; Macià, A.; Romero, M. P.; Motilva, M. J. Improved liquid chromatography tandem mass spectrometry method for the determination of phenolic compounds in virgin olive oil. J. Chromatogr. A 2008, 1214, 90-99.
30. Suárez, M.; Romero, M. P.; Ramo, T.; Macià, A.; Motilva, M. J. Methods for preparing phenolic extracts from olive cake for potential application as food antioxidants. J. Agrie. Food Chem. 2009, 57, 1463-1472.
31. European Community, Commission Regulation 796/2002 of 6 May 2002. Off. J. Eur. Union 2002, L128, annex XIX, 23.
32. Jee, M. In Oils and fat authentication; Blackwell Publishing, CRC Press: Boca Raton, FL, 2002.
33. Parsia, Z.; Górecki, T. Determination of ergosterol as an indicator of fungal biomass in various samples using non-discriminating flash pyrolysis. J. Chromatogr. A 2006, 1130, 145-150.