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Volumn 49, Issue 5, 2010, Pages 2247-2258

Spectroscopic characterization of alumina-supported bis(allyl)iridium complexes: Site-isolation, reactivity, and decomposition studies

Author keywords

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Indexed keywords


EID: 77649097226     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9021036     Document Type: Article
Times cited : (11)

References (69)
  • 8
    • 77649121479 scopus 로고    scopus 로고
    • Regalbuto, J. R., Ed.; Taylor & Francis Publishing Group, CRC Press: New York, Chapter 10
    • (a) Gates, B. C. In Catalyst Preparation; Regalbuto, J. R., Ed.; Taylor & Francis Publishing Group, CRC Press: New York, 2007; Chapter 10, pp 237-249.
    • (2007) Catalyst Preparation , pp. 237-249
    • Gates, B.C.1
  • 36
    • 62249202817 scopus 로고    scopus 로고
    • and references cited therein
    • Böhmer, I. K.; Alt, H. G. J. Organomet. Chem. 2009, 694, 1001-1010 and references cited therein.
    • (2009) J. Organomet. Chem. , vol.694 , pp. 1001-1010
    • Böhmer, I.K.1    Alt, H.G.2
  • 66
    • 77649166780 scopus 로고    scopus 로고
    • 1H NMR spectroscopy. In one trial, a turnover number of 121 for the dehydrogenation of cyclohexane to benzene was achieved at 200 °C (41% yield) when 0,050 g of 1 was employed as the catalyst. Using the same quantity of 1, a turnover number of 156 was observed for the conversion of heptane to toluene at 270 °C (72% yield).
    • 1H NMR spectroscopy. In one trial, a turnover number of 121 for the dehydrogenation of cyclohexane to benzene was achieved at 200 °C (41% yield) when 0,050 g of 1 was employed as the catalyst. Using the same quantity of 1, a turnover number of 156 was observed for the conversion of heptane to toluene at 270 °C (72% yield).
  • 67
    • 77649150562 scopus 로고    scopus 로고
    • 2 pressure in the reaction vessel would result in more reducing conditions than those in the in situ XAFS experiments, which were conducted under a constant flow of cyclohexane gas in helium
    • 2 pressure in the reaction vessel would result in more reducing conditions than those in the in situ XAFS experiments, which were conducted under a constant flow of cyclohexane gas in helium.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.