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Volumn 126, Issue 29, 2004, Pages 9079-9084

Is the allylpalladlum structure altered between solid and solutions?

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CONTINUUM MECHANICS; MOLECULAR STRUCTURE; NEGATIVE IONS; SOLIDS; SOLUTIONS; SOLVENTS;

EID: 3242749719     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja049091g     Document Type: Article
Times cited : (11)

References (40)
  • 11
    • 84962454685 scopus 로고    scopus 로고
    • note
    • The alternative is a pendant carbonium, unreactive toward the necessarily zero-valent Pd neighbor.
  • 14
    • 84962404706 scopus 로고    scopus 로고
    • note
    • One possible artifact is radiation damage. There is no evidence for radiation damage in the present case, and our analysis does not rest on radiation damage as the source of the structural conclusions from solution EXAFS data.
  • 20
    • 84962454666 scopus 로고    scopus 로고
    • note
    • We have shown with ONIOM calculations on 1′ that the phenyl groups do not perturb the first coordination sphere around Pd drastically. Therefore, there should not be any particular influence of Ph groups on the second coordination sphere associated with external interaction between the allyl ligand and the solvent or the counteranion. Consequently, we did not perform any ONIOM calculations on systems such as 3 and 4 with dhpe replaced by dppe.
  • 23
    • 84962390536 scopus 로고    scopus 로고
    • note
    • 31P NMR data indicate the absence of radical character in solution.
  • 24
    • 84962404687 scopus 로고    scopus 로고
    • note
    • The observed EXAFS scattering data were not presented in the paper or Supporting Information of ref 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.