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0002540658
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Time-resolved spectra at 430, 520 and 600 nm for this spectrum are contained in the ESI. Similarly, overlaid transient absorption spectra for 8, as well as the corresponding time-resolved spectra (430, 520 and 600 nm), are also contained in the ESI -40
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2+ and BQ groups in 6 and 8 in all likelihood minimizes the enhancement in the electronic coupling that occurs in dyads 5 and 7. Charge recombination is more exergonic than charge separation in all four dyads, and the relative energies of CR/CS probably become more important in 6 and 8 than the more minor changes in electronic coupling induced by the presence of the second phenyl group. As a result, charge recombination becomes more rapid than charge separation in 6 and 8, despite the excited state structural changes -4327
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