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Volumn , Issue 33, 2009, Pages 6562-6577

Photoinduced electron-transfer within osmium(II) and ruthenium(II) bis-terpyridine donor acceptor dyads

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION EXPERIMENTS; BENZOQUINONES; CHARGE RECOMBINATIONS; CHARGE SEPARATIONS; DONOR-ACCEPTOR DYADS; ELECTRON ACCEPTOR; ELECTRON DONOR ACCEPTORS; ELECTRON TRANSFER; EXCITED STATE LIFETIMES; FEMTOSECOND PUMPS; LOW EMISSION; MODEL COMPLEXES; PHOTOINDUCED ELECTRON-TRANSFER; PHOTOPHYSICAL CHARACTERIZATION; RU COMPLEXES; STEADY-STATE EMISSIONS; TERPYRIDINES; ULTRAFAST ELECTRON TRANSFER;

EID: 68749119618     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b903130h     Document Type: Article
Times cited : (19)

References (81)
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    • Time-resolved spectra at 515 and 600 nm for this spectrum are contained in the ESI. Similarly, overlaid transient absorption spectra for 5, as well as the corresponding time-resolved spectra (515 and 600 nm), are also contained in the ESI -9358
    • D. Kuciauskas J. E. Monat R. Villahermosa H. B. Gray N. S. Lewis J. K. McCusker J. Phys. Chem. B 2002 106 9347 9358
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  • 56
    • 0002540658 scopus 로고    scopus 로고
    • Time-resolved spectra at 430, 520 and 600 nm for this spectrum are contained in the ESI. Similarly, overlaid transient absorption spectra for 8, as well as the corresponding time-resolved spectra (430, 520 and 600 nm), are also contained in the ESI -40
    • S. W. Jones L. M. Vrana K. J. Brewer J. Organomet. Chem. 1998 554 29 40
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  • 75
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    • 2+ and BQ groups in 6 and 8 in all likelihood minimizes the enhancement in the electronic coupling that occurs in dyads 5 and 7. Charge recombination is more exergonic than charge separation in all four dyads, and the relative energies of CR/CS probably become more important in 6 and 8 than the more minor changes in electronic coupling induced by the presence of the second phenyl group. As a result, charge recombination becomes more rapid than charge separation in 6 and 8, despite the excited state structural changes -4327
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.