Decomposition of 1,1-dimethyl-1-silacyclobutane on a tungsten filament - Evidence of both ring C-C and ring Si-C bond cleavages

Journal of Mass Spectrometry

Volumn 45, Issue 2, 2010, Pages 215-222

  Tong, L ^a   Shi, Y J ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

1,1 dimethyl 1 silacyclobutane; Chemical vapor deposition; Reaction mechanisms; Tungsten; Vacuum ultraviolet laser ionization mass spectrometry

Indexed keywords

1,1-DIMETHYL-1-SILACYCLOBUTANE; BOND CLEAVAGES; C-C BONDS; CATALYTIC PROCESS; COLLISION-FREE CONDITIONS; DIMETHYLSILYLENE; DIRADICAL INTERMEDIATES; DIRADICALS; GASPHASE; METHYL RADICAL; REACTION MECHANISMS; SECONDARY REACTIONS; SI-C BOND; SILACYCLOBUTANE; SINGLE PHOTON IONIZATION; TETRAMETHYL; TIME OF FLIGHT MASS SPECTROMETRY; TUNGSTEN FILAMENTS; VACUUM ULTRAVIOLET LASER IONIZATIONS; VACUUM ULTRAVIOLETS; W FILAMENT;

CHEMICAL BONDS; CHEMICAL VAPOR DEPOSITION; DECOMPOSITION; ETHYLENE; FILAMENTS (LAMP); IONIZATION OF GASES; MASS SPECTROMETERS; MASS SPECTROMETRY; PARTICLE DETECTORS; PHOTOIONIZATION; PROPANE; PROPYLENE; SILICON; TUNGSTEN; VACUUM;

ULTRAVIOLET LASERS;

1,1 DIMETHYL 1 SILACYCLOBUTANE; 1,1 DIMETHYLSILENE; 1,3 DISILACYCLOBUTANE; CARBON; CYCLOBUTANE DERIVATIVE; CYCLOPROPANE; DIMETHYLSILYLENE; ETHYLENE; PROPYLENE; RADICAL; SILANE DERIVATIVE; SILICON; TUNGSTEN; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CONTROLLED STUDY; DECOMPOSITION; DIMERIZATION; GAS; HEATING; IONIZATION; PRIORITY JOURNAL; TIME OF FLIGHT MASS SPECTROMETRY; ULTRAVIOLET RADIATION; VACUUM; VACUUM ULTRAVIOLET LASER SINGLE PHOTON IONIZATION TIME OF FLIGHT MASS SPECTROMETRY;

EID: 76249133046     PISSN: 10765174     EISSN: 10969888     Source Type: Journal    
DOI: 10.1002/jms.1712     Document Type: Article

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