Mechanism of heterolysis of H2 by an Unsaturated d8 nickel center: Via tetravalent nickel?

Journal of the American Chemical Society

Volumn 132, Issue 3, 2010, Pages 910-911

  He, Tao ^a   Tsvetkov, Nikolay P ^a   Andino, José G ^a   Gao, Xinfeng ^a   Fullmer, Benjamin C ^a   Caulton, Kenneth G ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; DFT CALCULATION; DIHYDROGEN COMPLEXES; EXPERIMENTAL STUDIES; GEOMETRIC FEATURE; H-BONDS; LOCAL MAXIMUM; NICKEL COMPLEX; TRANSITION STATE;

AMIDES; COORDINATION REACTIONS; NICKEL ALLOYS; SULFUR COMPOUNDS;

NICKEL;

HYDROGEN; NICKEL;

ARTICLE; DENSITY FUNCTIONAL THEORY; DISSOCIATION; HYDROGEN BOND; MOLECULAR INTERACTION; OXIDATION REDUCTION REACTION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; THERMODYNAMICS;

EID: 76149129091     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja908674x     Document Type: Article

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