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Volumn 16, Issue 6, 2010, Pages 1776-1779

Fluorous 4-N,N-dimethylaminopyridine (DMAP) salts as simple recyclable acylation catalysts

Author keywords

Esterification; Fluorine; Green chemistry; Organocatalysis; Sustainable chemistry

Indexed keywords

CATALYSIS; CATALYSTS; ESTERIFICATION; ESTERS; FLUORINE;

EID: 75749090354     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902982     Document Type: Article
Times cited : (39)

References (73)
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    • For reviews on 4-aminopyridines as organocatalysts. see: a) A. C. Spivey, S. Arseniyadis, Angew. Chem. 2004, 116, 5552:
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    • Spivey, A.C.1    Arseniyadis, S.2
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    • -1 ')
    • -1 ');
  • 23
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    • With DMAP salts (e.g., citrate), the dermal toxicity is reduced to such an extent that even high concentrations (12 g/100 mL) of this substance produce only local irritation: see ref. [7b]
    • With DMAP salts (e.g., citrate), the dermal toxicity is reduced to such an extent that even high concentrations (12 g/100 mL) of this substance produce only local irritation: see ref. [7b].
  • 48
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    • For reviews on fluorous chemistry, see: a) W. Zhang, Green Chem. 2009, 11, 911;
    • (2009) Green Chem. , vol.11 , pp. 911
    • Zhang, W.1
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    • Eds.: J. A. Gladysz, D. P. Curran, I. T. Horváth, Wiley-VCH, Weinheim
    • d) Handbook of Fluorous Chemistry, (Eds.: J. A. Gladysz, D. P. Curran, I. T. Horváth), Wiley-VCH, Weinheim, 2004.
    • (2004) Handbook of Fluorous Chemistry
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    • Teflon tape has also been used for fluorous catalyst delivery/recovery, see: L. V. Dinh, J. A. Gladysz, Angew. Chem. 2005, 117, 4164;
    • (2005) Angew. Chem. , vol.117 , pp. 4164
    • Dinh, L.V.1    Gladysz, J.A.2
  • 61
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    • in the Special Issue "Dennis P. Curran ACS Award for Creative Work in Fluorine Chemistry" (Eds.: G. K. Surya Prakash, W. R. Dolbier, Jr.)
    • for fluorous 4-dialkylaminopyridine, see: d) J. Legros, B. Crousse, D. Bonnet-Delpon, J. Fluorine Chem. 2008, 129, 974 in the Special Issue "Dennis P. Curran ACS Award for Creative Work in Fluorine Chemistry" (Eds.: G. K. Surya Prakash, W. R. Dolbier, Jr.);
    • (2008) J. Fluorine Chem. , vol.129 , pp. 974
    • Legros, J.1    Crousse, B.2    Bonnet-Delpon, D.3
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    • note
    • f15 (δ = 6.71 ppm) (see the Supporting Information for details).
  • 72
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    • 2H as a catalyst
    • 2H as a catalyst.
  • 73
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    • note
    • f23 disfavors the release of free DMAP, thus, explaining the moderate activity in the acetylation reaction (58% conversion after 8 h).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.