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Volumn 129, Issue 10, 2008, Pages 974-977

Fluorous analogues of DMAP (F-DMAP): Reusable organocatalysts for acylation reaction

Author keywords

4 (Dimethylamino)pyridine; 4 Pyrrolidinopyridine; Fluorous tag; Organocatalysis; PPY

Indexed keywords


EID: 52149087217     PISSN: 00221139     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jfluchem.2008.06.008     Document Type: Article
Times cited : (10)

References (52)
  • 3
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    • For reviews on applications of DMAP and its derivatives as organocatalysts, see:
    • For reviews on applications of DMAP and its derivatives as organocatalysts, see:
  • 4
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    • 52149123780 scopus 로고    scopus 로고
    • For studies in the role of DMAP in rate acceleration, see:
    • For studies in the role of DMAP in rate acceleration, see:
  • 11
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    • For more potent DMAP analogues for acylation reaction, see:
    • For more potent DMAP analogues for acylation reaction, see:
  • 16
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    • note
    • 50 = 13 mg/kg).
  • 31
    • 52149087074 scopus 로고    scopus 로고
    • For reviews on supported organocatalysts, see:
    • For reviews on supported organocatalysts, see:
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    • Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
    • In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York
    • (2004) Handbook of Fluorous Chemistry
  • 35
    • 52149095256 scopus 로고    scopus 로고
    • For examples of fluorous organocatalysts, see:
    • For examples of fluorous organocatalysts, see:
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    • Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
    • Gladysz J.A., and Emmet C. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 11-23
    • (2004) Handbook of Fluorous Chemistry , pp. 11-23
    • Gladysz, J.A.1    Emmet, C.2
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    • Curran D.P. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 101-126
    • (2004) Handbook of Fluorous Chemistry , pp. 101-126
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    • Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
    • Gladysz J.A., and Corrêa da Costa R. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 24-40
    • (2004) Handbook of Fluorous Chemistry , pp. 24-40
    • Gladysz, J.A.1    Corrêa da Costa, R.2
  • 41
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    • Gladysz J.A. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 41-55
    • (2004) Handbook of Fluorous Chemistry , pp. 41-55
    • Gladysz, J.A.1
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    • For a review on perfluoroalkyl halides, see:
    • For a review on perfluoroalkyl halides, see:
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    • note
    • 3B (0.2 equiv.; 1 M solution in hexanes) in dichloroethane or under neat conditions; or with AIBN (0.1-1 equiv., in toluene or in benzene at reflux). In all the cases, the starting material remained unchanged and was fully recovered after work up.
  • 46
    • 52149119289 scopus 로고    scopus 로고
    • note
    • The addition products 3a and 3b have not been isolated and fully characterized. Their structures have been assumed from that of dehydrohalogenation products 4a and 4b.
  • 47
    • 52149097213 scopus 로고    scopus 로고
    • note
    • The use of other bases (e.g. NaH, t-BuOK), or hydride reduction (Bu3SnH) afforded complex mixtures.
  • 50
    • 52149102129 scopus 로고    scopus 로고
    • For a review and discussion on the particular case of nitrogen-containing fluorous catalysts, see:
    • For a review and discussion on the particular case of nitrogen-containing fluorous catalysts, see:


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.