-
3
-
-
52149088873
-
-
For reviews on applications of DMAP and its derivatives as organocatalysts, see:
-
For reviews on applications of DMAP and its derivatives as organocatalysts, see:
-
-
-
-
4
-
-
38349156051
-
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Wurz R.P. Chem. Rev. 107 (2007) 5570-5595
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Chem. Rev.
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Wurz, R.P.1
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9
-
-
52149123780
-
-
For studies in the role of DMAP in rate acceleration, see:
-
For studies in the role of DMAP in rate acceleration, see:
-
-
-
-
10
-
-
34548068809
-
-
Baidya M., Kobayashi S., Brotzel F., Schmidhammer U., Riedle E., and Mayr H. Angew. Chem., Int. Ed. 46 (2007) 6176-6179
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(2007)
Angew. Chem., Int. Ed.
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Baidya, M.1
Kobayashi, S.2
Brotzel, F.3
Schmidhammer, U.4
Riedle, E.5
Mayr, H.6
-
11
-
-
52149109811
-
-
For more potent DMAP analogues for acylation reaction, see:
-
For more potent DMAP analogues for acylation reaction, see:
-
-
-
-
15
-
-
0142214745
-
-
Heinrich M.R., Klisa H.S., Mayr H., Steglich W., and Zipse H. Angew. Chem. Int. Ed. 42 (2003) 4826-4828
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(2003)
Angew. Chem. Int. Ed.
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Heinrich, M.R.1
Klisa, H.S.2
Mayr, H.3
Steglich, W.4
Zipse, H.5
-
16
-
-
52149122589
-
-
note
-
50 = 13 mg/kg).
-
-
-
-
17
-
-
36749050839
-
-
Sakakura A., Kawajiri K., Ohkubo T., Kosugi Y., and Ishihara K. J. Am. Chem. Soc. 129 (2007) 14775-14779
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Sakakura, A.1
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Ishihara, K.5
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20
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-
0037270111
-
-
Pelotier B., Priem G., Macdonald S.J.F., Anson M.S., and Campbell I.B. Synlett (2003) 679-683
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(2003)
Synlett
, pp. 679-683
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-
Pelotier, B.1
Priem, G.2
Macdonald, S.J.F.3
Anson, M.S.4
Campbell, I.B.5
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31
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-
52149087074
-
-
For reviews on supported organocatalysts, see:
-
For reviews on supported organocatalysts, see:
-
-
-
-
34
-
-
84958634880
-
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Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
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In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York
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Handbook of Fluorous Chemistry
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35
-
-
52149095256
-
-
For examples of fluorous organocatalysts, see:
-
For examples of fluorous organocatalysts, see:
-
-
-
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36
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-
49549107813
-
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Zu L., Xie H., Li H., Wang J., and Wang W. Org. Lett. 10 (2008) 1211-1214
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(2008)
Org. Lett.
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Zu, L.1
Xie, H.2
Li, H.3
Wang, J.4
Wang, W.5
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38
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13244253108
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Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
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Gladysz J.A., and Emmet C. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 11-23
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Handbook of Fluorous Chemistry
, pp. 11-23
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Gladysz, J.A.1
Emmet, C.2
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39
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3943111078
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Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
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Curran D.P. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 101-126
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Handbook of Fluorous Chemistry
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Curran, D.P.1
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40
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13244274279
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Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
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Gladysz J.A., and Corrêa da Costa R. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 24-40
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Handbook of Fluorous Chemistry
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Gladysz, J.A.1
Corrêa da Costa, R.2
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41
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10044238972
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Gladysz J.A., Curran D.P., and Horváth I.T. (Eds), Wiley-VCH, New York
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Gladysz J.A. In: Gladysz J.A., Curran D.P., and Horváth I.T. (Eds). Handbook of Fluorous Chemistry (2004), Wiley-VCH, New York 41-55
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(2004)
Handbook of Fluorous Chemistry
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Gladysz, J.A.1
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42
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0035310337
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Campos J., del Carmen Núñez M., Rodríguez V., Entrena A., Hernández-Alcoceba R., Fernández F., Lacal J.C., Gallo M.A., and Espinosa A. Eur. J. Med. Chem. 36 (2001) 215-225
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Campos, J.1
del Carmen Núñez, M.2
Rodríguez, V.3
Entrena, A.4
Hernández-Alcoceba, R.5
Fernández, F.6
Lacal, J.C.7
Gallo, M.A.8
Espinosa, A.9
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43
-
-
52149089532
-
-
For a review on perfluoroalkyl halides, see:
-
For a review on perfluoroalkyl halides, see:
-
-
-
-
45
-
-
52149091527
-
-
note
-
3B (0.2 equiv.; 1 M solution in hexanes) in dichloroethane or under neat conditions; or with AIBN (0.1-1 equiv., in toluene or in benzene at reflux). In all the cases, the starting material remained unchanged and was fully recovered after work up.
-
-
-
-
46
-
-
52149119289
-
-
note
-
The addition products 3a and 3b have not been isolated and fully characterized. Their structures have been assumed from that of dehydrohalogenation products 4a and 4b.
-
-
-
-
47
-
-
52149097213
-
-
note
-
The use of other bases (e.g. NaH, t-BuOK), or hydride reduction (Bu3SnH) afforded complex mixtures.
-
-
-
-
50
-
-
52149102129
-
-
For a review and discussion on the particular case of nitrogen-containing fluorous catalysts, see:
-
For a review and discussion on the particular case of nitrogen-containing fluorous catalysts, see:
-
-
-
-
52
-
-
14244250195
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-
Klomp D., Djanashvili K., Svennum N.C., Chantapariyavat N., Wong C.-S., Vilela F., Maschmeyer T., Peters J.A., and Hanefeld U. Org. Biomol. Chem. 3 (2005) 483-489
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(2005)
Org. Biomol. Chem.
, vol.3
, pp. 483-489
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Klomp, D.1
Djanashvili, K.2
Svennum, N.C.3
Chantapariyavat, N.4
Wong, C.-S.5
Vilela, F.6
Maschmeyer, T.7
Peters, J.A.8
Hanefeld, U.9
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