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Apart from the wavenumber shift owing to the transition from ordered to disordered state, one has to be aware that the peak positions in the experimental ellipsometric spectra of oriented films may slightly differ from the true resonance frequencies due to pure optical effect.34 The wavenumber shift for SAMs on metallic surfaces is about 1-2 cm-1 only and therefore hardly discernible, while for monolayers on semiconductors it could be more pronounced34.
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