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4243154353
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note
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The general synthetic strategy and procedures will be detailed in a future publication.
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25
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85086289506
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note
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3): δ 0.88 (t, J = 6.6 Hz, 3H), 1.23-1.35 (overlapping resonance, 24H), 1.51 (m, 2H), 1.62 (t, J = 8.4 Hz, 1H), 2.48 (t, J = 6.8 Hz, 2H), 2.82 (m, 2H), 3.27 (m, 2H), 5.54 (br, 1H). Anal. Calcd: C, 68.51; H, 11.82; N, 4.44. Found: C, 68.72; H, 11.56; N, 4.47.
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26
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0029404870
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28
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4243195089
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note
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Additional sputtering after complete removal of carbon did not significantly affect the intensity of the Au peak (1.3% increase after 1.5 times the original sputter time). This suggests that the gold substrate morphology is not significantly altered during the sputtering process.
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29
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4243065448
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note
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Molecular mechanics (Sybyl force field) of the fully extended conformer of 1 on gold suggests a length of ≃26.5 Å.
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31
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4243156639
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note
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As a control, we measured ODT-derived monolayer thicknesses at 25 ± 2 Å, within experimental error of the 23 ±2 Å ellipsometric measurement of Bain et al. (ref 5c).
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