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The orientation of the cyanide bridge is expected from the connectivity in the precursors. In previous work we did not find isomerization of the cyanide bridge and in one case we have prepared the two possible isomers (see ref 5, The properties of the two isomers are quite distinctive, especially their redox behavior. Isomerization of the bridge results in an increase in the redox potential of the RuII/III couple, while the FeIII/II couples become more irreversible because of the lability of the Fe-N(nitrile) bond. Our exploration of the redox properties of the complexes reported here show no evidence of bridge isomerization
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72949099760
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We estimate the distance between the redox centers as multiples of the Fe-Ru distance of 5.05 Å observed in the trinuclear compounds
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We estimate the distance between the redox centers as multiples of the Fe-Ru distance of 5.05 Å observed in the trinuclear compounds.
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71
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0037620430
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(a) Fraysse, S.; Coudret, C.; Launay, J. P. J. Am. Chem. Soc. 2003, 125, 5880-5888.
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(2003)
J. Am. Chem. Soc
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, pp. 5880-5888
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Fraysse, S.1
Coudret, C.2
Launay, J.P.3
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72
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0010291368
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(b)Hoshino, Y.; Suzuki, T.; Umeda, H. Inorg. Chim. Acta 1996, 245, 87-90.
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(1996)
Inorg. Chim. Acta
, vol.245
, pp. 87-90
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Hoshino, Y.1
Suzuki, T.2
Umeda, H.3
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