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Volumn 48, Issue 23, 2009, Pages 11226-11235

From monomers to geometry-constrained molecules: One step further toward cyanide bridged wires

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[No Author keywords available]

Indexed keywords


EID: 72949087792     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic901710x     Document Type: Article
Times cited : (19)

References (75)
  • 25
    • 72949118368 scopus 로고    scopus 로고
    • Bignozzi, C. A.; Roffia, S.; Chiorboli, C.; Davila, J.; Indelli, M. T.; Scandola, F. Inorg. Chem. 1.989, 28, 4350-4358.
    • (a) Bignozzi, C. A.; Roffia, S.; Chiorboli, C.; Davila, J.; Indelli, M. T.; Scandola, F. Inorg. Chem. 1.989, 28, 4350-4358.
  • 58
    • 0037008566 scopus 로고    scopus 로고
    • (a.) Schalley, C. A.; Muller, T.; Linnartz, P.; Witt, M.; Schafer, M.; Lutzen, A. Chem.-Eur. J. 2002, 5, 3538-3551.
    • (a.) Schalley, C. A.; Muller, T.; Linnartz, P.; Witt, M.; Schafer, M.; Lutzen, A. Chem.-Eur. J. 2002, 5, 3538-3551.
  • 63
    • 72949089130 scopus 로고    scopus 로고
    • The orientation of the cyanide bridge is expected from the connectivity in the precursors. In previous work we did not find isomerization of the cyanide bridge and in one case we have prepared the two possible isomers (see ref 5, The properties of the two isomers are quite distinctive, especially their redox behavior. Isomerization of the bridge results in an increase in the redox potential of the RuII/III couple, while the FeIII/II couples become more irreversible because of the lability of the Fe-N(nitrile) bond. Our exploration of the redox properties of the complexes reported here show no evidence of bridge isomerization
    • III/II couples become more irreversible because of the lability of the Fe-N(nitrile) bond. Our exploration of the redox properties of the complexes reported here show no evidence of bridge isomerization.
  • 70
    • 72949099760 scopus 로고    scopus 로고
    • We estimate the distance between the redox centers as multiples of the Fe-Ru distance of 5.05 Å observed in the trinuclear compounds
    • We estimate the distance between the redox centers as multiples of the Fe-Ru distance of 5.05 Å observed in the trinuclear compounds.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.