Additional steps toward molecular scale wires: Further study of Ni510/11+ chains embraced by polypyridylamide ligands

Inorganic Chemistry

Volumn 42, Issue 11, 2003, Pages 3534-3539

  Berry, John F ^a   Cotton, F Albert ^a   Lei, Peng ^a   Lu, Tongbu ^a,b   Murillo, Carlos A ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b SUN YAT SEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDE; LIGAND; METAL; NICKEL; POLYPYRIMIDYLAMIDE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONDUCTOR; ELECTRONICS; MAGNETISM; MOLECULAR STABILITY; OXIDATION; SOLUBILITY; SYNTHESIS;

EID: 0038100167     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034071l     Document Type: Article

References (76)

1. (a) Odon, T. W.; Huang, J.; Lieber, C. M. Ann. N.Y. Acad. Sci. 2002, 960, 203.
2. (b) Rueckes, T.; Kim, K.; Joselevich, E.; Tseng, G. Y.; Cheung, C.-L.; Lieber, C. M. Science 2000, 289, 94.
3. (c) Kong, J.; Franklin, N. R.; Zhou, C.; Chapline, M. G.; Peng, S.; Cho, K.; Dai, H. Science 2000, 287, 622.
4. (a) Duan, X.; Lieber, C. M. J. Am. Chem. Soc. 2000, 122, 188.
5. (b) Ivanovskii, A. L. Russ. Chem. Rev. 2002, 71, 175.
6. (a) Heeger, A. J. Rev. Mod. Phys. 2001, 73, 681.
7. (b) Shirakawa, H. Rev. Mod. Phys. 2001, 73, 713.
8. (c) Dembinski, R.; Bartik, T.; Bartik, B.; Jaeger, M.; Gladysz, J. A. J. Am. Chem. Soc. 2000, 122, 810.
9. (d) Wong, K.-T.; Lehn, J.-M.; Peng, S.-M.; Lee, G.-H. Chem. Commun. 2000, 2259.
10. (e) Coat, F.; Lapinte, C. Organometallics 1996, 15, 477.
11. (f) Kheradmandan, S.; Heinze, K.; Schmalle, H. W.; Berke, H. Angew. Chem., Int. Ed. 1999, 38, 2270.
12. MacDiarmid, A. G. Rev. Mod. Phys. 2001, 73, 701.
13. (a) Venkataraman, L.; Lieber, C. M. Phys. Rev. Lett. 1999, 83, 5334.
14. (b) Iengo, E.; Zangrando, E.; Minatel, R.; Alessio, E. J. Am. Chem. Soc. 2002, 124, 1003.
15. (c) Karzazi, Y.; Cornil, J.; Brédas, J. L. J. Am. Chem. Soc. 2001, 123, 10076.
16. (d) Davis, W. B.; Svec, W. A.; Ratner, M. A.; Wasielewski, M. R. Nature 1998, 396, 60.
17. (e) Alvaro, M.; Ferrer, B.; García, H.; Lay, A.; Trinidad, F.; Valenciano, J. Chem. Phys. Lett. 2002, 356, 577.
18. (f) Le Stang, S.; Paul, F.; Lapinte, C. Organometallics 2000, 19, 1035.
19. (g) Taylor, P. N.; O'Connell, M. J.; McNiell, L. A.; Hall, M. J.; Aplin, R. T.; Anderson, H. L. Angew. Chem., Int. Ed. 2000, 39, 3456.
20. (h) Jestin, I.; Frère, P.; Blanchard, P.; Roncali, J. Angew. Chem., Int. Ed. 1998, 37, 942.
21. (i) Shiotsuka, M.; Yamamoto, Y.; Okuno, S.; Kitou, M.; Nozaki, K.; Onaka, S. Chem. Commun. 2002, 590.
22. (j) Jaquinod, L.; Siri, O.; Khoury, R. G.; Smith, K. M. Chem. Commun. 1998, 1261.
23. (k) Schenning, A. P. H. J.; Martin, R. E.; Ito, M.; Diederich, F.; Boudon, C.; Gisselbrecht, J.-P.; Gross, M. Chem. Commun. 1998, 1013.
24. (l) Barigelletti, F.; Flamigni, L. Chem. Soc. Rev. 2000, 29, 1.
25. (m) Paul, F.; Lapinte, C. Coord. Chem. Rev. 1998, 178-180, 431.
26. (n) Jiang, B.; Yang, S. W.; Bailey, S. L.; Hermans, L. G.; Niver, R. A.; Bolcar, M. A.; Jones, W. E., Jr. Coord. Chem. Rev. 1998, 171, 365.
27. (o) Sirota, M.; Minkin, E.; Lifshitz, E.; Hensel, V.; Lahav, M. J. Phys. Chem. B 2001, 105, 6792.
28. (p) Bumm, L. A.; Arnold, J. J.; Cygan, M. T.; Dunbar, T. D.; Burgin, T. P.; Jones, L., II; Allara, D. L.; Tour, J. M.; Weiss, P. S. Science 1996, 271, 1705.
29. (q) Finniss, G. M.; Canadell, E.; Campana, C., Dunbar, K. R. Angew. Chem., Int. Ed. Engl. 1996, 35, 2772.
30. (r) Pruchnik, F. P.; Jakimowicz, P.; Ciunik, Z.; Stanislawek, K.; Oro, L. A.; Tejel, C.; Ciriano, M. A. Inorg. Chem. Commun. 2001, 4, 19.
31. The field of extended linear chain compounds and extended structures has been reviewed by a myriad of experts. See for example: (a) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 1. (b) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 2. (c) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1983; Vol. 3. (d) Hoffmann, R. Solids and Surfaces: A Chemist's View of Bonding in Extended Sructures; VCH Publishers: New York, 1988. (e) Bera, J. K.; Dunbar, K. R. Angew. Chem., Int. Ed. 2002, 41, 4453.
32. The field of extended linear chain compounds and extended structures has been reviewed by a myriad of experts. See for example: (a) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 1. (b) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 2. (c) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1983; Vol. 3. (d) Hoffmann, R. Solids and Surfaces: A Chemist's View of Bonding in Extended Sructures; VCH Publishers: New York, 1988. (e) Bera, J. K.; Dunbar, K. R. Angew. Chem., Int. Ed. 2002, 41, 4453.
33. The field of extended linear chain compounds and extended structures has been reviewed by a myriad of experts. See for example: (a) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 1. (b) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 2. (c) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1983; Vol. 3. (d) Hoffmann, R. Solids and Surfaces: A Chemist's View of Bonding in Extended Sructures; VCH Publishers: New York, 1988. (e) Bera, J. K.; Dunbar, K. R. Angew. Chem., Int. Ed. 2002, 41, 4453.
34. The field of extended linear chain compounds and extended structures has been reviewed by a myriad of experts. See for example: (a) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 1. (b) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 2. (c) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1983; Vol. 3. (d) Hoffmann, R. Solids and Surfaces: A Chemist's View of Bonding in Extended Sructures; VCH Publishers: New York, 1988. (e) Bera, J. K.; Dunbar, K. R. Angew. Chem., Int. Ed. 2002, 41, 4453.
35. The field of extended linear chain compounds and extended structures has been reviewed by a myriad of experts. See for example: (a) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 1. (b) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1982; Vol. 2. (c) Extended Linear Chain Compounds; Miller, J. S., Ed.; Plenum Press: New York, 1983; Vol. 3. (d) Hoffmann, R. Solids and Surfaces: A Chemist's View of Bonding in Extended Sructures; VCH Publishers: New York, 1988. (e) Bera, J. K.; Dunbar, K. R. Angew. Chem., Int. Ed. 2002, 41, 4453.
36. (a) Hu, J.; Odom, T. W.; Lieber, C. M. Acc. Chem. Res. 1999, 32, 435.
37. (b) Treboux, G. J. Phys. Chem. B 2000, 104, 9823.
38. (c) Tour, J. M.; Rawlett, A. M.; Kozaki, M.; Yao, Y.; Jagessar, R. C.; Dirk, S. M.; Price, D. W.; Reed, M. A.; Zhou, C.-W.; Chen, J.; Wang, W.; Campbell, I. Chem. Eur. J. 2001, 7, 5118.
39. In considering this version of a molecular wire, one might also recall Feynman's often quoted adage that "There is plenty of room at the bottom," by which he meant making devices as small as possible. This version might be called "the bottom of the bottom." See: Feynman, R. P. Engineering and Science (CalTech), February 1990.
40. Peierls, R. E. Quantum Theory of Solids; Oxford University Press: Oxford, 1955; p 108.
41. (a) Schere-Miller, I.; Böttcher, P. Z. Kristallogr. 1991, 196, 137.
42. (b) Furuseth, S.; Fjellvåg, H. Acta Chem. Scand. 1991, 45, 694.
43. (c) Haneveld, A. J. K.; Jellinek, F. J. Less-Common Met. 1970, 21, 45.
44. (d) Stöwe, K. Z. Anorg. Allg. Chem. 1996, 622, 1419.
45. (e) Wu, E. J.; Pell, M. A.; Ibers, J. A. J. Alloys Compd. 1997, 255, 106.
46. (f) Krönert, W.; Plieth, K. Z. Anorg. Allg. Chem. 1965, 336, 207.
47. (g) Ben Salem, A.; Meerschaut, A.; Rouxel, J. C. R. Acad. Sci., Ser. 2 1984, 299, 617.
48. (h) Choi, K.-S.; Patschke, R.; Billinge, S. J. L.; Waner, M. J.; Dantus, M.; Kanatzidis, M, G. J. Am. Chem. Soc. 1998, 120, 10706.
49. (i) Huang, F. Q.; Brazis, P.; Kannewurf, C. R.; Ibers, J. A. J. Am. Chem. Soc. 2000, 122, 80.
50. Bersuker, I. B. The Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry; Plenum Press: New York. 1984.
51. Renner, E. Z. Phys. 1934, 92, 172.
52. (a) Longuet-Higgins, H. C.; Salem, L. Proc. R. Soc. London 1959. A251, 172.
53. (b) Salem, L.; Longuet-Higgins, H. C. Proc. R. Soc. London 1960, A255, 435.
54. (c) Longuet-Higgins, H. C.; Salem, L. Proc. R. Soc. London 1960, A257, 445.
55. (d) Yannoni, C. S.; Clarke, T. C. Phys. Rev. Lett. 1983, 51, 1191.
56. (e) Guo, H.; Paldus, J. Int. J. Quantum Chem. 1997, 63, 345.
57. (a) Cody, J. A.; Ibers, J. A. Inorg. Chem. 1995, 34, 3165.
58. (b) Dung, N.-H.; Pardo, M.-P.; Boy, P. Acta Crystallogr. 1983, C39, 668.
59. Others have referred to the aligned metal atoms as "strings" (Lai, S.Y.; Lin, T.-W.; Chen, Y.-H.; Wang, C.-C.; Lee, G.-H.; Yang, M.-H.; Leung, M.-K.; Peng, S.-M. J. Am. Chem. Soc. 1999, 121, 250).
60. Berry, J. F.; Cotton, F. A.; Daniels, L. M.; Murillo, C. A. J. Am. Chem. Soc. 2002, 124, 3212.
61. Berry, J. F.; Cotton, F. A.; Lu, T.; Murillo, C. A.; Wang, X. Inorg. Chem., in press.
62. Yeh, C. Y.; Chiang, Y.-L.; Lee, G.-H.; Peng, S.-M. Inorg. Chem. 2002, 41, 4096.
63. Hansch, C.; Carpenter, W.; Todd, J. J. Org. Chem. 1958, 23, 1924.
64. Wagaw, S.; Buchwald, S. L. J. Org. Chem. 1996, 61, 7240.
65. SMART V5.05 Software for the CCD Detector system; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 1998.
66. SAINTPLUS V5.05 Software for the CCD Detector system; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 1998.
67. SADABS. Program for absorption correction using SMART CCD based on the method of Blessing: Blessing, R. H. Acta Crystallogr. 1995, A51, 33.
68. SHELXTL, version 6.10; Bruker AXS Inc.: Madison, WI, 2000.
69. Shieh, S.-J.; Chou, C.-C.; Lee, G.-H.; Wang, C.-C.; Peng, S.-M. Angew. Chem., Int. Ed. Engl. 1997 36, 56.
70. Wang, C.-C.; Lo, W.-C.; Chou, C.-C.; Lee, G.-H.; Chen, J.-M.; Peng, S.-M. Inorg. Chem. 1998, 37, 4059.
71. 11+ unit fill all but the highest antibonding orbital., which is half-filled.
72. Berry, J. F.; Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Wang, X. Inorg. Chem. 2003, 42, 2418.
73. 5. Use of the eigenvalues from this Hamiltonian and the Van Vleck equation produces the equation given in the text, Though the exchange coupling mechanism is unknown, it is likely to be via spin polarization through the bridging ligands.
74. Escuer, A.; Ribas, J. J. Chem. Soc., Dalton Trans. 2002, 3778.
75. 15. The numbers given here, for comparison, are therefore twice the values listed in ref 26. We also note that in ref 26 there are errors in eqs 5 and 6, but it is impossible to tell whether these are only typographical errors, or whether the incorrect equations were actually used.
76. It should be noted that even though oxidation of 1 to 2 changes the electronic structure as to favor application to devices such as reversible molecular switches, such oxidation is accompanied by significant chemical changes (i.e., removal of axial chloride ions). Currently we are studying ways to eliminate exchange of axial ligands.