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J. L. Dye, Angew. Chem., Int. Ed. 1433-7851 18, 587 (1979). 10.1002/anie.197905871
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J. L. Dye, Prog. Inorg. Chem. 0079-6379 32, 327 (1984). 10.1002/9780470166338.ch4
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This decrease in optical density likely results from reactions of Na- with small amounts of impurities in the solvents or small amounts of air leaking into the cell. The OD decay typically occurred on a time scale of days and did not affect the dynamics in our pump/probe experiments within the 95% error bars shown in all the figures. We did not use data from a few samples whose optical density decay occurred on a time scale comparable to that over which we needed to signal-average.
-
This decrease in optical density likely results from reactions of Na- with small amounts of impurities in the solvents or small amounts of air leaking into the cell. The OD decay typically occurred on a time scale of days and did not affect the dynamics in our pump/probe experiments within the 95% error bars shown in all the figures. We did not use data from a few samples whose optical density decay occurred on a time scale comparable to that over which we needed to signal-average.
-
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58
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T. Q. Nguyen, I. B. Martini, J. Liu, and B. J. Schwartz, J. Phys. Chem. B 1089-5647 104, 237 (2000). 10.1021/jp993190c
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Nguyen, T.Q.1
Martini, I.B.2
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59
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0003601534
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12th ed., edited by S. Budavari (Merck & Co., Inc., Whitehouse Station, NJ).
-
The Merck Index, 12th ed., edited by, S. Budavari, (Merck & Co., Inc., Whitehouse Station, NJ, 1996).
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(1996)
The Merck Index
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60
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33751158711
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0022-3654, 10.1021/j100074a003
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C. Laurence, P. Nicolet, M. T. Dalati, J. L. M. Abboud, and R. Notario, J. Phys. Chem. 0022-3654 98, 5807 (1994). 10.1021/j100074a003
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0002-7863, 10.1021/ja00952a005
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C. Carvajal, K. J. Tolle, J. Smid, and M. Szwarc, J. Am. Chem. Soc. 0002-7863 87, 5548 (1965). 10.1021/ja00952a005
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Carvajal, C.1
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62
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70449378209
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-
To the best of our knowledge, the dielectric constant for DG has not been measured.
-
To the best of our knowledge, the dielectric constant for DG has not been measured.
-
-
-
-
63
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-
70449366672
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88th ed., edited by D. R. Lide (CRC, Boca Raton)
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CRC Handbook of Chemistry and Physics, 88th ed., edited by, D. R. Lide, (CRC, Boca Raton, 2007), pp. 6-175-6-179.
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CRC Handbook of Chemistry and Physics
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64
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0021-9568, 10.1021/je950299e
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A. Pal and Y. P. Singh, J. Chem. Eng. Data 0021-9568 41, 1008 (1996). 10.1021/je950299e
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Pal, A.1
Singh, Y.P.2
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66
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-
70449450653
-
-
TN value of 1.
-
TN value of 1.
-
-
-
-
67
-
-
70449396058
-
-
The absorption spectra of the solvated alkali anions, the solvated alkali atoms, and the solvated electron in THF have been shown to fit very well on the high energy side to a Gaussian and on the low energy side to a Lorentzian (Ref.).
-
The absorption spectra of the solvated alkali anions, the solvated alkali atoms, and the solvated electron in THF have been shown to fit very well on the high energy side to a Gaussian and on the low energy side to a Lorentzian (Ref.).
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-
-
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68
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36849099847
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0021-9606, 10.1063/1.1679050
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F. Y. Jou and L. M. Dorfman, J. Chem. Phys. 0021-9606 58, 4715 (1973). 10.1063/1.1679050
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70
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34547311395
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0008-4042, 10.1139/v77-276
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R. Catterall, J. Slater, and M. C. R. Symons, Can. J. Chem. 0008-4042 55, 1979 (1977). 10.1139/v77-276
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71
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0008-4042, 10.1139/v77-282
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W. A. Seddon, J. W. Fletcher, and R. Catterall, Can. J. Chem. 0008-4042 55, 2017 (1977). 10.1139/v77-282
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Seddon, W.A.1
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B. Bockrath and L. M. Dorfman, J. Phys. Chem. 0022-3654 77, 1002 (1973). 10.1021/j100627a007
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W. A. Seddon, J. W. Fletcher, F. C. Sopchyshyn, and R. Catterall, Can. J. Chem. 0008-4042 55, 3356 (1977). 10.1139/v77-470
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Seddon, W.A.1
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75
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W. A. Seddon, J. W. Fletcher, R. Catterall, and F. C. Sopchyshyn, Chem. Phys. Lett. 0009-2614 48, 584 (1977). 10.1016/0009-2614(77)85098-7
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76
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70449378208
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-
Even though the LCP is not observed in equilibrium in liquid THF at room temperature, we have found that if the temperature is decreased to ∼-60 °C, the LCP is produced in pulse radiolysis experiments, apparently in equilibrium with the TCP; (nee Cavanagh), (unpublished).
-
Even though the LCP is not observed in equilibrium in liquid THF at room temperature, we have found that if the temperature is decreased to ∼-60 °C, the LCP is produced in pulse radiolysis experiments, apparently in equilibrium with the TCP; M. C. Larsen (nee Cavanagh), J. R. Miller, and B. J. Schwartz (unpublished).
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-
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Larsen, M.C.1
Miller, J.R.2
Schwartz, B.J.3
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77
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70449450652
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As described in Ref., we are unable to explore the disjoint state coupling in DEE for excitation wavelengths other than 395 or 785 nm due to possible interference from K- contamination.
-
As described in Ref., we are unable to explore the disjoint state coupling in DEE for excitation wavelengths other than 395 or 785 nm due to possible interference from K- contamination.
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-
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78
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70449392623
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-
The data in Fig. also were averaged over several different experiments and/or several different samples. Our choice of longtime scaling for calculating the fraction of long-lived electrons is justified since the appearance kinetics of the detached electrons is the same for all the solvents at all the excitation wavelengths investigated.
-
The data in Fig. also were averaged over several different experiments and/or several different samples. Our choice of longtime scaling for calculating the fraction of long-lived electrons is justified since the appearance kinetics of the detached electrons is the same for all the solvents at all the excitation wavelengths investigated.
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-
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79
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70449366671
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In order to explain the difference in the fraction of long-lived electrons in different solvents from differences in absorption, the CTTS band of sodide in DG and DME would have to be shifted by ∼2700 and ∼1500 cm-1, respectively, relative to that in THF; instead, the experimental absorption spectrum of sodide in DG and DME are shifted by ∼700 and ∼400 cm-1, respectively, relative to that in THF (Fig.).
-
In order to explain the difference in the fraction of long-lived electrons in different solvents from differences in absorption, the CTTS band of sodide in DG and DME would have to be shifted by ∼2700 and ∼1500 cm-1, respectively, relative to that in THF; instead, the experimental absorption spectrum of sodide in DG and DME are shifted by ∼700 and ∼400 cm-1, respectively, relative to that in THF (Fig.).
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-
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80
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70449408294
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-
Although it is possible that there are differences in the electron absorption rise time in the different solvents that are too subtle for us to observe at the time resolution of our apparatus, we note that the difference in the number of long-lived electrons in DG relative to that in THF is as much as ∼50%, so that the corresponding ∼50% difference in electron appearance time would have been easily observed with our instrument.
-
Although it is possible that there are differences in the electron absorption rise time in the different solvents that are too subtle for us to observe at the time resolution of our apparatus, we note that the difference in the number of long-lived electrons in DG relative to that in THF is as much as ∼50%, so that the corresponding ∼50% difference in electron appearance time would have been easily observed with our instrument.
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-
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81
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33746882432
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Electron photodetachment from aqueous anions. 3. Dynamics of geminate pairs derived from photoexcitation of Mono- Vs polyatomic anions
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DOI 10.1021/jp0610113
-
R. Lian, D. A. Oulianov, R. A. Crowell, I. A. Shkrob, X. Y. Chen, and S. E. Bradforth, J. Phys. Chem. A 1089-5639 110, 9071 (2006). 10.1021/jp0610113 (Pubitemid 44187329)
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(2006)
Journal of Physical Chemistry A
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, Issue.29
, pp. 9071-9078
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Oulianov, D.A.2
Crowell, R.A.3
Shkrob, I.A.4
Chen, X.5
Bradforth, S.E.6
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82
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The ultrafast dynamics of photodetachment
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DOI 10.1146/annurev.physchem.58.032806.104702
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X. Chen and S. E. Bradforth, Annu. Rev. Phys. Chem. 0066-426X 59, 203 (2008). 10.1146/annurev.physchem.58.032806.104702 (Pubitemid 351703385)
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(2008)
Annual Review of Physical Chemistry
, vol.59
, pp. 203-231
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Chen, X.1
Bradforth, S.E.2
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83
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70449396057
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There is also a probability that electrons excited to this highest energy could also be excited directly to a disjoint state. This could explain why all the dynamics at this high energy excitation are so similar in all the solvents.
-
There is also a probability that electrons excited to this highest energy could also be excited directly to a disjoint state. This could explain why all the dynamics at this high energy excitation are so similar in all the solvents.
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-
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84
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70449338981
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We note that this relatively slow solvation process occurs on a much different time scale than both the fast and the slow recombination dynamics. Thus, when probed near 1100 nm, this process is not masked by the changing population of TCPs (which amounts to ∼10% over the first ∼30 ps for the 395 nm excitation wavelength) and can be easily observed in the raw data.
-
We note that this relatively slow solvation process occurs on a much different time scale than both the fast and the slow recombination dynamics. Thus, when probed near 1100 nm, this process is not masked by the changing population of TCPs (which amounts to ∼10% over the first ∼30 ps for the 395 nm excitation wavelength) and can be easily observed in the raw data.
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-
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85
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70449358720
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The small difference in the early time dynamics of DG may be due to a small difference in the relative extinction coefficients of the (Na+, e-) and solvated electron at this probe wavelength in this solvent.
-
The small difference in the early time dynamics of DG may be due to a small difference in the relative extinction coefficients of the (Na+, e-) and solvated electron at this probe wavelength in this solvent.
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-
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86
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0000546040
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1089-5647, 10.1021/jp990993r
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V. Tran and B. J. Schwartz, J. Phys. Chem. B 1089-5647 103, 5570 (1999). 10.1021/jp990993r
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(1999)
J. Phys. Chem. B
, vol.103
, pp. 5570
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Tran, V.1
Schwartz, B.J.2
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87
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Nonlinear, nonpolar solvation dynamics in water: The roles of electrostriction and solvent translation in the breakdown of linear response
-
DOI 10.1021/jp000326u
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D. Aherne, V. Tran, and B. J. Schwartz, J. Phys. Chem. B 1089-5647 104, 5382 (2000). 10.1021/jp000326u (Pubitemid 30865957)
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(2000)
Journal of Physical Chemistry B
, vol.104
, Issue.22
, pp. 5382-5394
-
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Aherne, D.1
Tran, V.2
Schwartz, B.J.3
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