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Volumn 182, Issue 11, 2009, Pages 3211-3214

Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies

Author keywords

Fluorescence; Metal organic frameworks; Mixed connectivity; Network topology; Thermal stability

Indexed keywords

3D ARRAYS; AMBIENT CONDITIONS; BENZOIC ACID; METAL ORGANIC FRAMEWORK; METAL SALT; METAL-ORGANIC FRAMEWORKS; MIXED CONNECTIVITY; NET TOPOLOGY; NETWORK TOPOLOGY; TECTONS; THERMAL STABILITY;

EID: 70350574728     PISSN: 00224596     EISSN: 1095726X     Source Type: Journal    
DOI: 10.1016/j.jssc.2009.09.004     Document Type: Article
Times cited : (16)

References (50)
  • 39
    • 70350566494 scopus 로고    scopus 로고
    • Synthesis. Complexes 1-4 were prepared by using a similar procedure as described below. To a DMF (5 mL) solution of 3,4-Hpybz (0.05 mmol) was added a CH3OH (10 mL) solution of metal salt (0.10 mmol, MnCl2·4H2O for 1, Zn(NO3)2·6H2O for 2, Cd(NO3)2·4H2O for 3, and Pb(NO3)2 for 4, After stirring for ca. 30 min, the mixture was filtered and left to stand at room temperature. Colorless block (for 1-3) or needle-shaped (for 4) crystals were obtained by slow evaporation of the solvents for ca. two weeks. Yield: 43% for 1, 51% for 2, 39% for 3, and 66% for 4. Anal. Calcd for C48H34Mn2N4O9 (1, Mr=920.67, C, 62.62; H, 3.72; N, 6.09, Found: C, 62.50; H, 3.64; N, 6.16, IR cm-1, 3447b, 1619vs, 1556s, 1426s, 1398vs, 1328s, 1192m, 1101m, 1031m, 1006m, 817s, 780s, 754s, 705s, 643m, 473s. An
    • -1): 1594s, 1548s, 1432w, 1353vs, 1195m, 1130m, 1003w, 867w, 843m, 778s, 703m, 667w, 622w, 551w, 528w, 474 m.
  • 40
    • 70350572152 scopus 로고    scopus 로고
    • Crystallographic data for 1: C48H34Mn2N4O9, M=920.67, 0.18×0.14×0.13 mm3, monoclinic, space group C2/c, a=11.982(3, b=15.316(4, c=21.926(5) Å, β=95.607(4)°, V=4005(2) Å3, Z=4, Dc=1.527 g/cm3, F(000)=1888, GOF=1.141, μ=0.698 mm-1, R=0.0670, and wR=0.1607. Crystallographic data for 2: C48H34Zn2N4O9, M=941.57, 0.24×0.20×0.18 mm3, monoclinic, space group C2/c, a=11.863(2, b=15.487(3, c=21.635(5) Å, β=94.938(4)°, V=3960(1) Å3, Z=4, Dc=1.579 g/cm3, F(000)=1928, GOF=1.048, μ=1.279 mm-1, R=0.0274, and wR=0.0661. Crystallographic data for 3: C48H34Cd2N4O9, M=1035.61, 0.24×0.22×0.18 mm3, monoclinic, space group C2/c, a=12.0223
    • -1, R=0.0160, and wR=0.0353.
  • 48
    • 70350570345 scopus 로고    scopus 로고
    • For the three-letter net codes, see
    • For the three-letter net codes, see Ref. [5] and the associated website 〈http://rcsr.anu.edu.au/〉.
    • 5] and the associated website
    • Ref1
  • 50
    • 70350564123 scopus 로고    scopus 로고
    • 2/ncm.
    • 2/ncm.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.