Metal-organic replica of fluorite built with an eight-connecting tetranuclear cadmium cluster and a tetrahedral four-connecting ligand

Angewandte Chemie - International Edition

Volumn 43, Issue 8, 2004, Pages 971-974

  Chun, Hyungphil ^a   Kim, Dongwoo ^a   Dybtsev, Danil N ^a,b   Kim, Kimoon ^a  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

^b NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY   (Russian Federation)

Author keywords

Cadmium; Carboxylate ligands; Coordination polymers; Metal organic frameworks; Topochemistry

Indexed keywords

CHEMICAL REACTIONS; ORGANIC COMPOUNDS;

LIGANDS; METAL-ORGANIC ANALOGUE; SOLVOTHERMAL REACTIONS;

CADMIUM COMPOUNDS;

CADMIUM DERIVATIVE; CADMIUM NITRATE; CALCIUM FLUORIDE; CALCIUM ION; CARBOXYLIC ACID DERIVATIVE; FLUORIDE ION; FLUORINE DERIVATIVE; LIGAND; METAL COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 4544232791     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353139     Document Type: Article

References (59)

1. a) S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558-1595; Angew. Chem. Int. Ed. 1998, 37, 1460-1494;
2. a) S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558-1595; Angew. Chem. Int. Ed. 1998, 37, 1460-1494;
3. b) M. O'Keeffe, M. Eddaoudi, H. Li, T. Reineke, O. M. Yaghi, J. Solid State Chem. 2000, 152, 3-20;
4. c) R. Robson, J. Chem. Soc. Dalton Trans. 2000, 3735-3744;
5. d) M. Eddaoudi, D. B. Moler, H. Li, B. Chen, T. M. Reineke, M. O'Keeffe, O. M. Yaghi, Acc. Chem. Res. 2001, 34, 319-330;
6. e) B. Moulton, M. Zaworotko, Chem. Rev. 2001, 101, 1629-1658;
7. f) O. R. Evans, W. Lin, Acc. Chem. Res. 2002, 35, 511-522;
8. g) O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature 2003, 423, 705-714;
9. h) S. L. James, Chem. Soc. Rev. 2003, 32, 276-288.
10. See refs. [1a-c,e-h,12] and references therein.
11. Most recent and representative examples: a) B. F. Hoskins, R. Robson, D. A. Slizys, Angew. Chem. 1997, 109, 2861-2863; Angew. Chem. Int. Ed. Engl. 1997, 36, 2752-2755;
12. Most recent and representative examples: a) B. F. Hoskins, R. Robson, D. A. Slizys, Angew. Chem. 1997, 109, 2861-2863; Angew. Chem. Int. Ed. Engl. 1997, 36, 2752-2755;
13. b) H. Li, M. Eddaoudi, M. O'Keefe, O. M. Yaghi, Nature 1999, 402, 276-279;
14. c) S. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem. 2000, 112, 2161-2164; Angew. Chem. Int. Ed. 2000, 39, 2081-2084;
15. c) S. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem. 2000, 112, 2161-2164; Angew. Chem. Int. Ed. 2000, 39, 2081-2084;
16. d) E. Lee, J. Heo, K. Kim, Angew. Chem. 2000, 112, 2811-2813; Angew. Chem. Int. Ed. 2000, 39, 2699-2701;
17. d) E. Lee, J. Heo, K. Kim, Angew. Chem. 2000, 112, 2811-2813; Angew. Chem. Int. Ed. 2000, 39, 2699-2701;
18. e) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe, O. M. Yaghi, Science 2002, 295, 469-472.
19. a) B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins, R. Robson, Angew. Chem. 1996, 108, 1794-1796; Angew. Chem. Int. Ed. Engl. 1996, 35, 1690-1692;
20. a) B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins, R. Robson, Angew. Chem. 1996, 108, 1794-1796; Angew. Chem. Int. Ed. Engl. 1996, 35, 1690-1692;
21. (later reported as α-Porelated net,[1a] but a close examination reveals that the structure is better described as a boracite topology) b) For a twisted boracite net, see S. S.-Y. Chu, S. M.-F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams, Science 1999, 283, 1148-1150.
22. a) M. Eddaoudi, J. Kim, D. Vodak, A. Sudik, J. Wachter, M. O'Keeffe, O. M. Yaghi, Proc. Natl. Acad. Sci. USA 2002, 99, 4900-4904;
23. b) B. Moulton, H. Abourahma, M. W. Bradner, J. Lu, G. J. McManus, M. J. Zaworotko, Chem. Commun. 2003, 1342-1343;
24. c) V. Niel, A. L. Thompson, M. C. Muñoz, A. Galet, A. E. Goeta, J. A. Real, Angew. Chem. 2003, 115, 3890-3893; Angew. Chem. Int. Ed. 2003, 42, 3760-3763.
25. c) V. Niel, A. L. Thompson, M. C. Muñoz, A. Galet, A. E. Goeta, J. A. Real, Angew. Chem. 2003, 115, 3890-3893; Angew. Chem. Int. Ed. 2003, 42, 3760-3763.
26. J. Kim, B. Chen, T. M. Reineke, H. Li, M. Eddaoudi, D. B. Moler, M. O'Keeffe, O. M. Yaghi, J. Am. Chem. Soc. 2001, 123, 8239-8247.
27. S. W. Keller, Angew. Chem. 1997, 109, 295-297; Angew. Chem. Int. Ed. Engl. 1997, 36, 247-248.
28. S. W. Keller, Angew. Chem. 1997, 109, 295-297; Angew. Chem. Int. Ed. Engl. 1997, 36, 247-248.
29. a) M. Eddaoudi, J. Kim, M. O'Keeffe, O. M. Yaghi, J. Am. Chem. Soc. 2002, 124, 376-377;
30. b) B. Chen, F. R. Fronczek, A. W. Maverick, Chem. Commun. 2003, 2166-2167.
31. a) ref. [3d];
32. b) for organic perovskite, see C. A. Bremner, M. Simpson, W. T. A. Harrison, J. Am. Chem. Soc. 2002, 124, 10960-10961.
33. a) R. P. Farrell, T. W. Hambley, P. A. Lay, Inorg. Chem. 1995, 34, 757-758;
34. b) B. Chen, M. Eddaoudi, S. T. Hyde, M. O'Keeffe, O. M. Yaghi, Science 2001, 291, 1021-1023
35. a) R. W. Gable, B. F. Hoskins, R. Robson, J. Chem. Soc. Chem. Commun. 1990, 762-763;
36. b) B. F. Abrahams, B. F. Hoskins, D. M. Michael, R. Robson, Nature 1994, 369, 727-729;
37. c) B. Chen, M. Eddaoudi, T. M. Reineke, J. W. Kampf, M. O'Keeffe, O. M. Yaghi, J. Am. Chem. Soc. 2000, 122, 11559-11560.
38. H. K. Chae, J. Kim, O. D. Friedrichs, M. O'Keeffe, O. M. Yaghi, Angew. Chem. 2003, 115, 4037-4039; Angew. Chem. Int. Ed. 2003, 42, 3907-3909.
39. H. K. Chae, J. Kim, O. D. Friedrichs, M. O'Keeffe, O. M. Yaghi, Angew. Chem. 2003, 115, 4037-4039; Angew. Chem. Int. Ed. 2003, 42, 3907-3909.
40. a) B. F. Hoskins, R. Robson, N. V. Y. Scarlett, Angew. Chem. 1995, 107, 1317-1318; Angew. Chem. Int. Ed. Engl. 1995, 34, 1203-1204;
41. a) B. F. Hoskins, R. Robson, N. V. Y. Scarlett, Angew. Chem. 1995, 107, 1317-1318; Angew. Chem. Int. Ed. Engl. 1995, 34, 1203-1204;
42. b) J. Sun, L. Weng, Y. Zhou, J. Chen, Z. Chen, Z. Liu, D. Zhao, Angew. Chem. 2002, 114, 4651-4653; Angew. Chem. Int. Ed. 2002, 41, 4471-4473.
43. b) J. Sun, L. Weng, Y. Zhou, J. Chen, Z. Chen, Z. Liu, D. Zhao, Angew. Chem. 2002, 114, 4651-4653; Angew. Chem. Int. Ed. 2002, 41, 4471-4473.
44. a) S. R. Batten, B. F. Hoskins, R. Robson, J. Chem. Soc. Chem. Commun. 1991, 445-447;
45. b) S. R. Batten, B. F. Hoskins, B. Moubaraki, K. S. Murray, R. Robson, J. Chem. Soc. Dalton Trans. 1999, 2977-2986.
46. B. F. Abrahams, M. G. Haywood, R. Robson, D. A. Slizys, Angew. Chem. 2003, 115, 1144-1147; Angew. Chem. Int. Ed. 2003, 42, 1111-1115.
47. B. F. Abrahams, M. G. Haywood, R. Robson, D. A. Slizys, Angew. Chem. 2003, 115, 1144-1147; Angew. Chem. Int. Ed. 2003, 42, 1111-1115.
48. Also known as (10, 3)-a net. a) O. M. Yaghi, C. E. Davis, G. Li, H. Li, J. Am. Chem. Soc. 1997, 119, 2861-2868;
49. 2, see K. Biradha, M. Fujita, Angew. Chem. 2002, 114, 3542-3545; Angew. Chem. Int. Ed. 2002, 41, 3392-3395.
50. 2, see K. Biradha, M. Fujita, Angew. Chem. 2002, 114, 3542-3545; Angew. Chem. Int. Ed. 2002, 41, 3392-3395.
51. 2, see K. Biradha, M. Fujita, Angew. Chem. 2002, 114, 3542-3545; Angew. Chem. Int. Ed. 2002, 41, 3392-3395.
52. E. B. Rusanov, V. V. Ponomarova, V. V. Komarchuk, H. Stoeckli-Evans, E. Fernandez-Ibañez, F. Stoeckli, J. Sieler, K. V. Domasevitch, Angew. Chem. 2003, 115, 2603-2605; Angew. Chem. Int. Ed. 2003, 42, 2499-2501.
53. E. B. Rusanov, V. V. Ponomarova, V. V. Komarchuk, H. Stoeckli-Evans, E. Fernandez-Ibañez, F. Stoeckli, J. Sieler, K. V. Domasevitch, Angew. Chem. 2003, 115, 2603-2605; Angew. Chem. Int. Ed. 2003, 42, 2499-2501.
54. a) A. K. Sra, G. Rombaut, F. Lahitête, S. Golhen, L. Ouahab, C. Mathonière, J. V. Yakhmi, O. Kahn, New J. Chem. 2000, 24, 871-876;
55. b) D.-L. Long, A. J. Blake, N. R. Champness, C. Wilson, M. Schröder, Angew. Chem. 2001, 113, 2509-2513; Angew. Chem. Int. Ed. 2001, 40, 2443-2447.
56. b) D.-L. Long, A. J. Blake, N. R. Champness, C. Wilson, M. Schröder, Angew. Chem. 2001, 113, 2509-2513; Angew. Chem. Int. Ed. 2001, 40, 2443-2447.
57. M. Grimm, B. Kirste, H. Kurreck, Angew. Chem. 1986, 98, 1095-1099; Angew. Chem. Int. Ed. Engl. 1986, 25, 1097-1098.
58. M. Grimm, B. Kirste, H. Kurreck, Angew. Chem. 1986, 98, 1095-1099; Angew. Chem. Int. Ed. Engl. 1986, 25, 1097-1098.
59. 2, and the evacuated sample showed severe line broadening in its powder XRD pattern. This may be attributed to the instability of the framework caused by the loss of coordinated DMF molecules.