Heterospin single-molecule magnets based on terbium ions and TCNQF 4 radicals: Interplay between single-molecule magnet and phonon bottleneck phenomena investigated by dilution studies

Chemistry - A European Journal

Volumn 15, Issue 42, 2009, Pages 11390-11400

  Lopez, Nazario ^a   Prosvirin, Andrey V ^a   Zhao, Hanhua ^a   Wernsdorfer, Wolfgang ^b   Dunbar, Kim R ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b LABORATOIRE DE CRISTALLOGRAPHIE   (France)

Author keywords

Magnetic properties quinodimethanes; Radicals, rare earths; Single molecule magnets

Indexed keywords

AC SIGNALS; CONCENTRATION OF; FREQUENCY-DEPENDENT; ISOSTRUCTURAL COMPOUNDS; LOW TEMPERATURES; MAGNETIC METALS; ORGANIC RADICAL LIGANDS; OUT OF PHASE; PARAMAGNETIC RELAXATION; PHONON BOTTLENECK; RADICALS, RARE EARTHS; SINGLE-MOLECULE; SINGLE-MOLECULE MAGNET; SINGLE-MOLECULE MAGNETS; TERBIUM IONS; TETRAFLUORO-TETRACYANOQUINODIMETHANE; YTTRIUM ION;

ELECTRONIC EQUIPMENT MANUFACTURE; MAGNETIC PROPERTIES; MAGNETISM; MAGNETS; METAL IONS; MOLECULES; PHONONS; PHOTOLITHOGRAPHY; RARE EARTHS; TERBIUM; YTTRIUM;

TERBIUM ALLOYS;

EID: 70350504900     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200900629     Document Type: Article

References (97)

1. a) J. R. Friedman, M. P. Sarachik, J. Tejada, R. Ziolo, Phys. Rev. Lett. 1996, 76, 3830-3833;
2. b) L. Thomas, F. Lionti, R. Bailou, D. Gatteschi, R. Sessoli, B. Barbara, Nature 1996, 383, 145-147;
3. c) J. M. Hernández, X. X. Zhang, F. Luis, J. Bartolomé, J. Tejada, R. Ziolo, Europhys. Lett. 1996, 35, 301-306.
4. a) L. Bogani, W. Wernsdorfer, Nat. Mater. 2008, 7, 179-186;
5. b) M. Mannini, F. Pineider, P. Sainctavit, C. Danieli, E. Ptero, C. Sciancalepore, A. M. Talarico, M.-A. Arrio, A. Comia, D. Gatteschi, R. Sessoli, Nat. Mater. 2009, 8, 194.
6. a) R. Sessoli, H.-T. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 1804-1816;
7. b) R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141-143.
8. G. Aromí, E. K. Brechin in Single-Molecule Magnets and Related Phenomena, Structure and Bonding, Vol 122 (Ed.: R. Winpenny), Springer, Berlin, 2006, pp. 1-67.
9. a) G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66-71;
10. b) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309;
11. Angew. Chem. Int. Ed. 2003, 42, 268-297.
12. a) S. L. Castro, Z. Sun, C. M. Grant, J. C. Bollinger, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 1998, 120, 2365-2375;
13. b) A. L. Barra, D. Gatteschi, R. Sessoli, Chem. Eur. J. 2000, 6, 1608-1614;
14. c) H. Andres, R. Basier, A. J. Blake, C. Cadiou, G. Chaboussant, C. M. Grant, H.-U. Güdel, M. Murrie, S. Parsons, C. Paulsen, F. Semadini, V. Villlar, W. Wernsdorfer, R. E. P. Winpenny, Chem. Eur. J. 2002, 8, 4867-4876;
15. d) M. Murrie, S.J. Teat, H. Stoeckli-Evans, H. U. Güdel, Angew. Chem. 2003, 115, 4801-4804;
16. Angew. Chem. Int. Ed. 2003, 42, 4653-4656.
17. C. P. Berlinguette, D. Vaughn, C. Cañada-Vilalta, J. R. Galán-Mascaros, K. R. Dunbar, Angew. Chem. 2003, 115, 1561-1564;
18. Angew. Chem. Int. Ed. 2003, 42, 1523-1526.
19. M. Murugesu, M. Habrych, W. Wernsdorfer, K. A. Abboud, G. Christou, J. Am. Chem. Soc. 2004, 126, 4766.
20. T. C. Stamatatos, K. A. Abboud, W. Wernsdorfer, G. Christou, Angew. Chem. 2007, 119, 902-906;
21. Angew. Chem. Int. Ed. 2007, 46, 884-888.
22. a) E. J. Schelter, A. V. Prosvirin, K. R. Dunbar, J. Am. Chem. Soc. 2004, 126, 15004-15005;
23. b) J. Martinez-Lillo, D. Armentano, G. De Munno, W. Wernsdorfer, M. Juive, F. Lloret, J. Faus, J. Am. Chem. Soc. 2006, 128, 14218-14219;
24. c) E.J. Schelter, F. Karadas, C. Avendano, A. V. Prosvirin, W. Wernsdorfer, K. R. Dunbar, J. Am. Chem. Soc. 2001, 129, 8139-8149.
25. a) J. J. Sokol, A. G. Hee, J. R. Long, J. Am. Chem. Soc. 2002, 124, 7656-7657;
26. b) S. Wang, J.-L. Zuo, H.-C. Zhou, H.J. Choi, Y. Ke, J. R. Long, X.-Z. You, Angew. Chem. 2004, 116, 6066-6069;
27. Angew. Chem. Int. Ed. 2004, 43, 5940-5943;
28. c) H.J. Choi, J.J. Sokol, J. R. Long, Inorg. Chem. 2004, 43, 1606-1608.
29. a) S. Karasawa, G. Zhou, H. Morikawa, N. Koga, J. Am. Chem. Soc. 2003, 125, 13676;
30. b) D. Yoshihara, S. Karasawa, N. Koga, J. Am. Chem. Soc. 2008, 130, 10460.
31. a) S. Osa, T. Kido, N. Matsumoto, N. Re, A. Pochaba, J. Mrozinski, J. Am. Chem. Soc. 2004, 126, 420-421;
32. b) A. Mishra, W. Wernsdorfer, K. A. Abboud, G. Christou, J. Am. Chem. Soc. 2004, 126, 15648-15649;
33. c) C. M. Zaleski, E. C. Depperman, J. W. Kampf, M. L. Kirk, V.L. Pecoraro, Angew. Chem. 2004, 116, 4002-4004;
34. Angew. Chem. Int. Ed. 2004, 43, 3912-3914;
35. d) A. Mishra, W. Wernsdorfer, S. Parsons, G. Christou, E. K. Brechin, Chem. Commun. 2005, 2086-2088;
36. e)F. Mori, T. Nyui, T. Ishida, T. Nogami, K.-Y. Choi, H. Nojiri, J. Am. Chem. Soc. 2006, 128, 1440-1441;
37. f) C. Aronica, G. Pilet, G. Chastanet, W. Wernsdorfer, J.-F. Jacquot, D. Luneau, Angew. Chem. 2006, 118, 4775-4778;
38. Angew. Chem. Int. Ed. 2006, 45, 4659-4662;
39. g) M. Ferbinteanu, T. Kajiwara, K.-Y. Choi, H. Nojiri, A. Nakamoto, N. Kojima, F. Cimpoesu, Y. Fujimura, S. Takaishi, M. Yamashita, J. Am. Chem. Soc. 2006, 128, 9008;
40. h) V. M. Mereacre, A. M. Ako, R. Clérac, W. Wernsdorfer, G. Filoti, J. Bartolomé, C. E. Anson, A. K. Powell, J. Am. Chem. Soc. 2007, 129, 9248;
41. i) V. Chandrasekhar, B. M. Pandian, R. Boomishankar, A. Steiner, J. J. Vittal, A. Houri, R. Clérac, Inorg. Chem. 2008, 47, 4918-4929;
42. j) T. Kajiwara, M. Nakano, S. Takaishi, M. Yamashita, Inorg. Chem. 2008, 47, 8604-8606;
43. k) T. C. Stamatatos, S. J. Teat, W. Wernsdorfer, G. Christou, Angew. Chem. 2009, 121, 529-532;
44. Angew. Chem. Int. Ed. 2009, 48, 521-524;
45. G. Novitchi, W. Wernsdorfer, L. F. Chibotaru, J.-P. Costes, C. E. Anson, A. K. Powell, Angew. Chem. 2009, 121, 1642-1647;
46. Angew. Chem. Int. Ed. 2009, 48, 1614-1619.
47. N. Ishikawa, M. Sugita, N. Tanaka, T. Ishikawa, S. Koshihara, Y. Kaizu, Inorg. Chem. 2004, 43, 5498-5500.
48. a) J. Tang, I. Hewitt, N.T. Madhu, G. Chastenet, W. Wernsdorfer, C. E. Anson, C. Benelli, R. Sessoli, A. K. Powell, Angew. Chem. 2006, 118, 1761-1765;
49. Angew. Chem. Int. Ed. 2006, 45, 1729-1733;
50. b) M. T. Gamer, Y. Lan, P. W. Roesky, A. K. Powell, R. Clérac, Inorg. Chem. 2008, 47, 6581.
51. a) N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Am. Chem. Soc. 2003, 125, 8694-8695;
52. b) N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Phys. Chem. B 2004, 108, 11265-11271;
53. c) N. Ishikawa, M. Sugita, W. Wernsdorfer, Angew. Chem. 2005, 117, 2991-2995;
54. Angew. Chem. Int. Ed. 2005, 44, 2931-2935;
55. d) N. Ishikawa, M. Sugita, W. Wernsdorfer, J. Am. Chem. Soc. 2005, 127, 3650-3651;
56. e) M. A. AlDamen, J. M. Clemente-Juan, E. Coronado, C. Martí-Gastaldo, A. Gaita-Arifio, J. Am. Chem. Soc. 2008, 130, 8874;
57. f) M. A. AlDamen, S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Arifio, C. Martí-Gastaldo, F. Luis, O. Montero, Inorg. Chem. 2009, 48, 3467-3479.
58. a) L. Bogani, C. Sangregorio, R. Sessoli, D. Gatteschi, Angew. Chem. 2005, 117, 5967-5971;
59. Angew. Chem. Int. Ed. 2005, 44, 5817-5821;
60. b) K. Bernot, L. Bogani, A. Caneschi, D. Gatteschi, R. Sessoli, J. Am. Chem. Soc. 2006, 128, 7947-7956;
61. c) K. Bernot, L. Bogani, R. Sessoli, D. Gatteschi, Inorg. Chim. Acta 2007, 360, 3807-3812;
62. d) Y.-G. Huang, X.-T. Wang, F.-L. Jiang, S. Gao, M.-Y. Wu, Q. Gao, W. Wei, M.-C. Hong, Chem. Eur. J. 2008, 14, 10340-10347.
63. Magnetism and Superconductivity in Low-Dimensional Systems: Utilization in Future Applications (Ed.: D. Stamopoulos), Nova Science Publishers, New York, 2008.
64. D. A. Garanin, Phys. Rev. B 2007, 75, 094409.
65. a) K. Petukhov, S. Bahr, W. Wernsdorfer, A.-L. Barra, V. Mosser, Phys. Rev. B 2007, 75, 064408/1-12;
66. b) M. Bal, J. R. Friedman, W. Chen, M. T. Tuominen, C. C. Beedle, E. M. Rumberger, D. N. Hendrickson, EPL 2008, 82, 17005/1-6;
67. c) G. de Loubens, D. A. Garanin, C. C. Beedle, D. N. Hendrickson, A. D. Kent, EPL 2008, 83, 37006/1-6.
68. S. A. O'Kane, R. Clérac, H. Zhao, X. Ouyang, J. R. Galán-Mascaros, R. Heintz, K. R. Dunbar, J. Solid State Chem. 2000, 152, 159.
69. T. Emge, M. Maxfield, D. Cowand, T. Kistenmacher, J. Mol. Cryst. Liq. Cryst. 1981, 65, 16.
70. T. Hahn in International Tables for Crystallography, D. Reidel Publishing Company, Dordrecht, 1983, p. 177.
71. K. Bernot, J. Luzon, L. Bogani, M. Etienne, C. Sangregorio, M. Shanmugam, A. Caneschi, R. Sessoli, D. Gatteschi, J. Am. Chem. Soc. 2009, 131, 5573-5579.
72. a) M. E. Fisher, Am. J. Phys. 1964, 32, 343;
73. b) T. Smith, S. A. Friedberg, Phys. Rev. 1968, 176, 660-665.
74. a) O. Kahn in Molecular Magnetism, Wiley-VCH, 1993, p. 11;
75. O. Kahn in Molecular Magnetism, Wiley-VCH, 1993, p. 47;
76. b) O. Kahn, in Molecular Magnetism, Wiley-VCH, 1993, pp. 3-4.
77. K. S. Cole, R. H. Cole, J. Chem. Phys. 1941, 9, 341-351.
78. R. J. Glauber, J. Math. Phys. 1963, 4, 294-307.
79. a) A. Caneschi, L. Cianchi, F. D. Giallo, D. Gatteschi, P. Moretti, F. Pieralli, G. Spina, J. Phys. Condens. Matter 1999, 11, 3395-3403;
80. b) D. Li, S. Parkin, G. Wang, G. T. Yee, R. Clérac, W. Wernsdorfer, S. M. Holmes, J. Am. Chem. Soc. 2006, 128, 4214-4215.
81. W. Wernsdorfer, N. E. Chakov, G. Christou, Phys. Rev. B 2004, 70, 132413.
82. a) I. Chiorescu, W. Wernsdorfer, A. Müller, H. Bögge, B. Barbara, Phys. Rev. Lett. 2000, 84, 3454-3457;
83. b) I. Chiorescu, W. Wernsdorfer, A. Müller, H. Bögge, B. Barbara, J. Magn. Magn. Mater. 2000, 227, 103-109;
84. c) E. I. Tolis, L. P. Engelhardt, P. V. Mason, G. Rajaraman, K. Kindo, M. Luban, A. Matsuo, H. Nojiri, J. Raftery, C. Schröder, G. A. Timco, F. Tuna, W. Wernsdorfer, R. E. P. Winpenny, Chem. Eur. J. 2006, 12, 8961-8968.
85. a) L. F. Jones, E. K. Brechin, D. Collison, M. Helliwell, Talal Mallah, S. Piligkos, G. Rajaraman, W. Wernsdorfer, Inorg. Chem. 2003, 42, 6601-6603;
86. b) N. Aliaga-Alcalde, R. S. Edwards, S.O. Hill, W. Wernsdorfer, K. Folting, G. Christou, J. Am. Chem. Soc. 2004, 126, 12503;
87. c) M. Moragues-Cánovas, M. Helliwell, L. Ricard, É. Rivière, W. Wernsdorfer, E. Brechin, T. Mallah, Eur. J. Inorg. Chem. 2004, 2219;
88. d) E.-C. Yang, W. Wernsdorfer, L. N. Zakharov, Y. Karaki, A. Yamaguchi, R. M. Isidro, G.-D. Lu, S. A. Wilson, A. L. Rheingold, H. Ishimoto, D.N. Hendrickson, Inorg. Chem. 2006, 45, 529-546;
89. e) K. W. Galloway, A. M. Whyte, W. Wernsdorfer, J. Sanchez-Benitez, K. V. Kamenev, A. Parkin, R. D. Peacock, M. Murrie, Inorg. Chem. 2008, 47, 7438.
90. L. J. de Jongh, W. D. van Amstel, A. R. Miedema, Physica 1972, 58, 277.
91. a) R. C. Wheland, E. L. Martin, J. Org. Chem. 1975, 40, 3101;
92. b) L. R. Melby, R. J. Harder, W. R. Hertler, W. Mahler, R. E. Benson, W. E. Mochel, J. Am. Chem. Soc. 1962, 84, 3374-3387.
93. SMART and SAINT, Siemens Analytical X-ray Instruments Inc., Madison, 1996.
94. SADABS, G. M. Sheldrick, University of Göttingen, Göttingen, 1996.
95. SHELXS-97 and SHELXL-97, G. M. Sheldrick, University of Göttingen: Göttingen, 1997.
96. L.J. Barbour, J. Supramol. Chem. 2001, 1, 189-191.
97. W. Wernsdorfer, Adv. Chem. Phys. 2001, 118, 99-190.