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Volumn 48, Issue 21, 2009, Pages 3872-3876

Substituent-free gallium by hydrogenolysis of coordinated gaCp*: Synthesis and structure of highly fluxional [Ru2(Ga)(GaCp*) 7(H)3]

Author keywords

Cluster compounds; Coordination chemistry; Gallium; Hydrogenolysis; Ruthenium

Indexed keywords

CLUSTER COMPOUNDS; COORDINATION CHEMISTRY; GALLIUM ATOMS; LIGAND EXCHANGES; METAL NANOPARTICLES;

EID: 70349973188     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200805605     Document Type: Article
Times cited : (41)

References (59)
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    • The Ru-Ga system is an interesting target for soft chemical synthesis of unusual intermetallics. See Supporting Information for details
    • The Ru-Ga system is an interesting target for soft chemical synthesis of unusual intermetallics. See Supporting Information for details.
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    • All energies herein are given as relative free energies ΔGo for the standard state.
    • All energies herein are given as relative free energies ΔGo for the standard state.
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    • Substituent-free Ga atoms in a linearly bridging position have been observed previously by S. Aldridge et al. and K. Ueno et al. However, these examples contain the gallium in the oxidation state Ga(III) and bonded to the transition-metal carbonyl fragments, rather than Ga(I) bonded to the carbonyl-free transition-metal fragments. See, for example: a) N. R. Bunn, S. Aldridge, D. L. Coombs, A. Rossin, D. J. Willock, C. Jones, L. L. Ooi, Chem. Commun. 2004, 1732-1733
    • Substituent-free Ga atoms in a linearly bridging position have been observed previously by S. Aldridge et al. and K. Ueno et al. However, these examples contain the gallium in the oxidation state Ga(III) and bonded to the transition-metal carbonyl fragments, rather than Ga(I) bonded to the carbonyl-free transition-metal fragments. See, for example: a) N. R. Bunn, S. Aldridge, D. L. Coombs, A. Rossin, D. J. Willock, C. Jones, L. L. Ooi, Chem. Commun. 2004, 1732-1733


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.