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10544234290
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In memory of Brian Bent, a beloved friend and colleague, an outstanding chemist, and a wonderful person, who died suddenly at the age of 35 on July 23, 1996
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In memory of Brian Bent, a beloved friend and colleague, an outstanding chemist, and a wonderful person, who died suddenly at the age of 35 on July 23, 1996.
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2
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0003806853
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Chapman and Hall: New York
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(a) Chemistry of Aluminum, Gallium, Indium, and Thallium; Downs, A. J., Ed.; Chapman and Hall: New York, 1993.
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For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
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For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
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Schmidbaur, H.1
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11
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37049071177
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For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
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Ulvenlund, S.1
Wheatley, A.2
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12
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0005335598
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For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
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14
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0001361495
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However, it should be noted that although by definition complexes with metal-metal bonds exhibit reduced oxidation states, it is not necessarily appropriate to consider such complexes to be subvalent. See: Green, M. L. H. J. Organomet. Chem. 1995, 500, 127-148.
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For the abbreviations of tris(pyrazolyl)hydroborato ligands, see: Trofimenko, S. Chem. Rev. 1993, 93, 943-980.
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38
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3 by extraction of the former into pentane
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3 by extraction of the former into pentane.
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39
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10544232721
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Personal communication
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3), have been observed in other reactions of "Gal". Green, M. L. H. Personal communication.
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Green, M.L.H.1
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40
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0000827871
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6. See: Beachley, O. T., Jr.; Blom, R.; Churchill, M. R.; Faegri, K., Jr.; Fettinger, J. C.; Pazik, J. C.; Victoriano, L. Organometallics 1989, 8, 346-356.
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41
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1842421197
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For an example of a related indium complex, see: Frazer, A.; Hodge, P.; Piggott, B. J. Chem. Soc., Chem. Commun. 1996, 1727-1728.
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Frazer, A.1
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Piggott, B.3
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42
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10544228632
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note
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3, z = 4.
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43
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0000732264
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Haaland, H.; Martinsen, K.-G.; Volden, H. V.; Loos, D.; Schnöckel, H. Acta Chem. Scand. 1994, 48, 172-174.
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Haaland, H.1
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Volden, H.V.3
Loos, D.4
Schnöckel, H.5
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44
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0000240409
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Haaland, A.; Martinsen, K.-G.; Shlykov, S. A.; Volden, H. V.; Dohmeier, C.; Schnöckel, H. Organometallics 1995, 14, 3116-3119.
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Haaland, A.1
Martinsen, K.-G.2
Shlykov, S.A.3
Volden, H.V.4
Dohmeier, C.5
Schnöckel, H.6
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45
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33747569885
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Dohmeier, C.; Robl, C.; Tacke, M.; Schnöckel, H. Angew. Chem., Int. Ed. Engl. 1991, 30, 564-565.
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Dohmeier, C.1
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Schnöckel, H.4
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46
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0024800998
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The significance of metal-metal bonding in cyclopentadienyl derivatives of the heavier group 3 elements is currently a matter of some debate. See: (a) Janiak, C.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1688-1690. (b) Schwerdtfeger, P. Inorg. Chem. 1991, 30, 1660-1663. (c) Budzelaar, P. H. M.; Boersma, J. Recl. Trav. Chim. Pays-Bas 1990, 109, 187-189.
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Janiak, C.1
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47
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33751500519
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The significance of metal-metal bonding in cyclopentadienyl derivatives of the heavier group 3 elements is currently a matter of some debate. See: (a) Janiak, C.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1688-1690. (b) Schwerdtfeger, P. Inorg. Chem. 1991, 30, 1660-1663. (c) Budzelaar, P. H. M.; Boersma, J. Recl. Trav. Chim. Pays-Bas 1990, 109, 187-189.
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Schwerdtfeger, P.1
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48
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84987108437
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The significance of metal-metal bonding in cyclopentadienyl derivatives of the heavier group 3 elements is currently a matter of some debate. See: (a) Janiak, C.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1688-1690. (b) Schwerdtfeger, P. Inorg. Chem. 1991, 30, 1660-1663. (c) Budzelaar, P. H. M.; Boersma, J. Recl. Trav. Chim. Pays-Bas 1990, 109, 187-189.
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Budzelaar, P.H.M.1
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0000453792
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3CGa] is tetranuclear in the solid state (ref 7), it exists as a monomer in dilute solutions and in the gas phase, as demonstrated by electron diffraction studies. See: Haaland. A.; Martinsen, K.-J.; Volden, H. V.; Kaim, W.; Waldhör, E.; Uhl, W.; Schütz, E. Organometallics 1996, 15, 1146-1150.
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Haaland, A.1
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Cowley, A. H.; Carrano, C. J.; Geerts, R. L.; Jones, R. A.; Nunn, C. M. Angew. Chem., Int. Ed. Engl. 1988, 27, 277-278.
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Cowley, A.H.1
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33748244535
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Saxena, A. K.; Zhang, H.; Maguire, J. A.; Hosmane, N. S.; Cowley, A. H. Angew. Chem., Int. Ed. Engl. 1995, 34, 332-334.
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Saxena, A.K.1
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Schluter, R. D.; Cowley, A. H.; Atwood, D. A.; Jones, R. A.; Bond, M. R.; Carrano, C. J. J. Am. Chem. Soc. 1993, 115, 2070-2071. Data is cited in ref 35.
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Schluter, R.D.1
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56
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10544237777
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note
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3, 2.441(1) A (ref 11).
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