메뉴 건너뛰기




Volumn 118, Issue 44, 1996, Pages 10914-10915

A monovalent gallium complex supported by tris(3,5-di-tert-butylpyrazoylyl)hydroborato ligation: The synthesis and structures of [Tp(Bu(t)2)]Ga and its GaI3 adduct, [Tp(Bu(t)2)]Ga→GaI3

Author keywords

[No Author keywords available]

Indexed keywords

GALLIUM; METAL COMPLEX;

EID: 0029797766     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962698f     Document Type: Article
Times cited : (98)

References (56)
  • 1
    • 10544234290 scopus 로고    scopus 로고
    • In memory of Brian Bent, a beloved friend and colleague, an outstanding chemist, and a wonderful person, who died suddenly at the age of 35 on July 23, 1996
    • In memory of Brian Bent, a beloved friend and colleague, an outstanding chemist, and a wonderful person, who died suddenly at the age of 35 on July 23, 1996.
  • 9
    • 84985579947 scopus 로고
    • For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
    • (1985) Angew. Chem., Int. Ed. Engl. , vol.24 , pp. 893-904
    • Schmidbaur, H.1
  • 10
    • 0000212552 scopus 로고
    • For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
    • (1983) Organometallics , vol.2 , pp. 1550-1554
    • Schmidbaur, H.1    Thewalt, U.2    Zafiropoulos, T.3
  • 11
    • 37049071177 scopus 로고
    • For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
    • (1995) J. Chem. Soc., Dalton Trans. , pp. 245-254
    • Ulvenlund, S.1    Wheatley, A.2    Bengtsson, L.A.3
  • 12
    • 0005335598 scopus 로고
    • For example, mixed-valent arene complexes are known. See: (a) Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 893-904. (b) Schmidbaur, H.; Thewalt, U.; Zafiropoulos, T. Organometallics 1983, 2, 1550-1554. (c) Ulvenlund, S.; Wheatley, A.; Bengtsson, L. A. J. Chem. Soc., Dalton Trans. 1995, 245-254. (d) Schmidbaur, H.; Nowak, R.; Huber, B.; Müller, G. Polyhedron 1990, 9, 283-287.
    • (1990) Polyhedron , vol.9 , pp. 283-287
    • Schmidbaur, H.1    Nowak, R.2    Huber, B.3    Müller, G.4
  • 13
    • 0000767786 scopus 로고
    • Tuck, D. Polyhedron 1990, 9, 377-386.
    • (1990) Polyhedron , vol.9 , pp. 377-386
    • Tuck, D.1
  • 14
    • 0001361495 scopus 로고
    • However, it should be noted that although by definition complexes with metal-metal bonds exhibit reduced oxidation states, it is not necessarily appropriate to consider such complexes to be subvalent. See: Green, M. L. H. J. Organomet. Chem. 1995, 500, 127-148.
    • (1995) J. Organomet. Chem. , vol.500 , pp. 127-148
    • Green, M.L.H.1
  • 31
    • 0010636960 scopus 로고
    • For the abbreviations of tris(pyrazolyl)hydroborato ligands, see: Trofimenko, S. Chem. Rev. 1993, 93, 943-980.
    • (1993) Chem. Rev. , vol.93 , pp. 943-980
    • Trofimenko, S.1
  • 32
    • 0030526715 scopus 로고    scopus 로고
    • For a review of poly(pyrazolyl)borate complexes of gallium and indium, see: Reger, D. L. Coord. Chem. Rev. 1996, 147, 571-595.
    • (1996) Coord. Chem. Rev. , vol.147 , pp. 571-595
    • Reger, D.L.1
  • 38
    • 10544239212 scopus 로고    scopus 로고
    • 3 by extraction of the former into pentane
    • 3 by extraction of the former into pentane.
  • 39
    • 10544232721 scopus 로고    scopus 로고
    • Personal communication
    • 3), have been observed in other reactions of "Gal". Green, M. L. H. Personal communication.
    • Green, M.L.H.1
  • 42
    • 10544228632 scopus 로고    scopus 로고
    • note
    • 3, z = 4.
  • 46
    • 0024800998 scopus 로고
    • The significance of metal-metal bonding in cyclopentadienyl derivatives of the heavier group 3 elements is currently a matter of some debate. See: (a) Janiak, C.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1688-1690. (b) Schwerdtfeger, P. Inorg. Chem. 1991, 30, 1660-1663. (c) Budzelaar, P. H. M.; Boersma, J. Recl. Trav. Chim. Pays-Bas 1990, 109, 187-189.
    • (1989) Angew. Chem., Int. Ed. Engl. , vol.28 , pp. 1688-1690
    • Janiak, C.1    Hoffmann, R.2
  • 47
    • 33751500519 scopus 로고
    • The significance of metal-metal bonding in cyclopentadienyl derivatives of the heavier group 3 elements is currently a matter of some debate. See: (a) Janiak, C.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1688-1690. (b) Schwerdtfeger, P. Inorg. Chem. 1991, 30, 1660-1663. (c) Budzelaar, P. H. M.; Boersma, J. Recl. Trav. Chim. Pays-Bas 1990, 109, 187-189.
    • (1991) Inorg. Chem. , vol.30 , pp. 1660-1663
    • Schwerdtfeger, P.1
  • 48
    • 84987108437 scopus 로고
    • The significance of metal-metal bonding in cyclopentadienyl derivatives of the heavier group 3 elements is currently a matter of some debate. See: (a) Janiak, C.; Hoffmann, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1688-1690. (b) Schwerdtfeger, P. Inorg. Chem. 1991, 30, 1660-1663. (c) Budzelaar, P. H. M.; Boersma, J. Recl. Trav. Chim. Pays-Bas 1990, 109, 187-189.
    • (1990) Recl. Trav. Chim. Pays-Bas , vol.109 , pp. 187-189
    • Budzelaar, P.H.M.1    Boersma, J.2
  • 56
    • 10544237777 scopus 로고    scopus 로고
    • note
    • 3, 2.441(1) A (ref 11).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.