Synthesis and structural characterization of thermally stable group 13 hydride complexes derived from a gallium(I) carbene analogue

Angewandte Chemie - International Edition

Volumn 42, Issue 23, 2003, Pages 2660-2663

  Baker, Robert J ^a   Jones, Cameron ^a   Kloth, Marc ^a   Platts, Jamie A ^a  

^a CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

Density functional calculations; Group 13 elements; Hydrides; Metal metal interactions; Structure elucidation

Indexed keywords

CHARACTERIZATION; CHEMICAL BONDS; COMPLEXATION; NEGATIVE IONS; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY;

HETEROCYCLES;

GALLIUM COMPOUNDS;

ALUMINUM; CARBENOID; GALLIUM; HETEROCYCLIC COMPOUND; METAL; TRANSITION ELEMENT;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; COVALENT BOND; CRYSTALLOGRAPHY; MOLECULAR INTERACTION; REACTION ANALYSIS; SOLID STATE; SPECTROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; THERMOSTABILITY;

EID: 0038451454     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351281     Document Type: Article

References (22)

1. A. Schnepf, H. Schnöckel, Angew. Chem. 2002, 114, 3682-3704; Angew. Chem. Int. Ed. 2002, 41, 3532-3552, and references therein.
2. A. Schnepf, H. Schnöckel, Angew. Chem. 2002, 114, 3682-3704; Angew. Chem. Int. Ed. 2002, 41, 3532-3552, and references therein.
3. G. Linti, H. Schnöckel, Coord. Chem. Rev. 2000, 206-207, 285-319, and references therein.
4. C. Cui, H. W. Roesky, H.-G. Schmidt, M. Noltemeyer, H. Hao, F. Cimpoesu, Angew. Chem. 2000, 112, 4444-4446; Angew. Chem. Int. Ed. 2000, 39, 4274-4276.
5. C. Cui, H. W. Roesky, H.-G. Schmidt, M. Noltemeyer, H. Hao, F. Cimpoesu, Angew. Chem. 2000, 112, 4444-4446; Angew. Chem. Int. Ed. 2000, 39, 4274-4276.
6. N. J. Hardman, B. E. Eichler, P. P. Power, Chem. Commun. 2000, 1991-1992.
7. N. J. Hardman, R. J. Wright, A. D. Phillips, P. P. Power, J. Am. Chem. Soc. 2003, 125, 2667-2679.
8. N. J. Hardman, P. P. Power, J. D. Gorden, C. L. B. Macdonald, A. H. Cowley, Chem. Commun. 2001, 1866-1867.
9. a) E. S. Schmidt, A. Jockisch, H. Schmidbaur, J. Am. Chem. Soc. 1999, 121, 9758-9759;
10. b) E. S. Schmidt, A. Schier, H. Schmidbaur, J. Chem. Soc. Dalton Trans. 2001, 505-507.
11. R. J. Baker, R. D. Farley, C. Jones, M. Kloth, D. M. Murphy, J. Chem. Soc. Dalton Trans. 2002, 3844-3850.
12. W. A. Herrmann, Angew. Chem. 2002, 114, 1342-1363; Angew. Chem. Int. Ed. 2002, 41, 1290-1309, and references therein.
13. W. A. Herrmann, Angew. Chem. 2002, 114, 1342-1363; Angew. Chem. Int. Ed. 2002, 41, 1290-1309, and references therein.
14. C. Jones, Chem. Commun. 2001, 2293-2298, and references therein.
15. full synthetic and spectroscopic data for compound 2 have been submitted as supplementary material.
16. 2) 0.0860 (I> 2σ(I)). CCDC-204734 2, CCDC-204735 3, CCDC-204736 4 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam. ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
17. C. Jones, G. A. Koutsantonis, C. L. Raston, Polyhedron 1993, 12, 1829-1848.
18. G. Linti, A. Rodig, W. Kostler, Z. Anorg. Allg. Chem. 2001, 627, 1465-1476.
19. W. Uhl, F, Schmock, G. Geisler, Z. Anorg. Allg. Chem. 2002, 628, 1963-1966.
20. M. C. Kutchta, J. B. Bonanno, G. Parkin, J. Am. Chem. Soc. 1996, 118, 10914-10915.
21. J. Emsley, The Elements, 2nd ed., Clarendon, Oxford, 1991, p. 77, 91.
22. Geometries of 5 and 6 were optimized in Gaussian 98 by using the mPW91 functional with the 6-311 + G basis set on Ga, C, N, and H atoms and LANL2DZ basis set and core potential for In. Atomic charge, orbital population, and bonding analyses were carried out by using the NBO scheme. See supplementary material for full details.