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Volumn 48, Issue 36, 2009, Pages 6731-6734

Manganese-catalyzed oxidative cross-coupling of grignard reagents with oxygen as an oxidant

Author keywords

Cross coupling; Grignard reagents; Manganese; Oxidation; Synthetic methods

Indexed keywords

CROSS-COUPLING; CROSS-COUPLINGS; GRIGNARD REAGENT; GRIGNARD REAGENTS; HOMOCOUPLING; HOMOCOUPLING REACTIONS; MECHANISTIC ANALYSIS; SYNTHETIC METHODS;

EID: 70349906976     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200902188     Document Type: Article
Times cited : (64)

References (59)
  • 2
    • 70349944765 scopus 로고    scopus 로고
    • A Cu-catalyzed procedure for homocoupling of aryl zinc halides by using N-methyl-N'-(3,4dinitrobenzoyl)piperazine has been successfully used to perform a few intramolecular heterocoupling reactions:
    • A Cu-catalyzed procedure for homocoupling of aryl zinc halides by using N-methyl-N'-(3,4dinitrobenzoyl)piperazine has been successfully used to perform a few intramolecular heterocoupling reactions:
  • 9
    • 33845251381 scopus 로고    scopus 로고
    • 2 as oxidant: H. Mizuno, H. Sakurai, T. Amaya, T. Hirao, Chem. Commun. 2006, 5042, and references quoted herein.
    • 2 as oxidant: H. Mizuno, H. Sakurai, T. Amaya, T. Hirao, Chem. Commun. 2006, 5042, and references quoted herein.
  • 35
    • 61349136863 scopus 로고    scopus 로고
    • G. Cahiez, O. Gager, F. Lecomte, Org. Lett. 2008, 10, 5255. See also ré [9] For a review, see:
    • e) G. Cahiez, O. Gager, F. Lecomte, Org. Lett. 2008, 10, 5255. See also ré [9] For a review, see:
  • 44
    • 70349912793 scopus 로고    scopus 로고
    • Oxygen has also been employed as oxidant for metal-free homocoupling of Grignard reagents with 2,2,6,6tetramethylpiperidine-N-oxyl radical (TEMPO) as catalyst:
    • Oxygen has also been employed as oxidant for metal-free homocoupling of Grignard reagents with 2,2,6,6tetramethylpiperidine-N-oxyl radical (TEMPO) as catalyst:
  • 47
    • 0036589259 scopus 로고    scopus 로고
    • In the case of an ortho-substituted aryl group, the detrimental effect of steric hindrance on the formation of biaryl by crosscoupling reaction is well established. For reviews, see: a J. Hassan, M. Sevignon, C. Gozzi, E. Schulz, M. Lemaire, Chem. Rev. 2002, 102, 1359;
    • In the case of an ortho-substituted aryl group, the detrimental effect of steric hindrance on the formation of biaryl by crosscoupling reaction is well established. For reviews, see: a) J. Hassan, M. Sevignon, C. Gozzi, E. Schulz, M. Lemaire, Chem. Rev. 2002, 102, 1359;
  • 52
    • 37049111384 scopus 로고
    • For the influence of the π-electronic density of the aryl group on the reductive elimination rate, see: a
    • For the influence of the π-electronic density of the aryl group on the reductive elimination rate, see: a) P. S. Braterman, R. J. Cross, G. B. Young, J. Chem. Soc. Dalton Trans. 1977,1892;
    • (1977) J. Chem. Soc. Dalton Trans , pp. 1892
    • Braterman, P.S.1    Cross, R.J.2    Young, G.B.3
  • 57
    • 70349930220 scopus 로고    scopus 로고
    • 2 commences
    • 2 commences
  • 58
    • 70349896305 scopus 로고    scopus 로고
    • See Supporting Information Figure Sl
    • See Supporting Information (Figure Sl).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.