Investigation on lewis acid mediated diels-alder reactions of 2-phosphono-2-alkenoates. Application to total synthesis of (±)-α- alasken-8-one via reductive alkylation of resulting adduct

Journal of Organic Chemistry

Volumn 74, Issue 20, 2009, Pages 7873-7884

  Liao, Chuan Cheng ^a   Zhu, Jia Liang ^a  

^a NATIONAL DONG HWA UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUPS; CHEMICAL EQUATIONS; COMBINED OPERATIONS; CYCLOADDITIONS; DIELS ALDER ADDUCTS; DIELS-ALDER; DIELS-ALDER REACTION; ELECTRON-RICH; ELEVATED TEMPERATURE; GOOD YIELD; LEWIS ACID; METHYL GROUP; NATURAL PRODUCTS; QUATERNARY CARBON; REDUCTIVE ALKYLATION; SESQUITERPENES; SYNTHETIC EQUIVALENTS; TIN CHLORIDES; TOTAL SYNTHESIS; ZINC CHLORIDE;

ACIDS; CHLORINE COMPOUNDS; CYCLOADDITION; ESTERS; OLEFINS; STEREOSELECTIVITY; TIN; ZINC;

ALKYLATION;

2 PHOSPHONO 2 ALKENOATE; LEWIS ACID; LITHIUM DERIVATIVE; LITHIUM NAPHTHALENIDE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG; ZINC CHLORIDE;

ALKYLATION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; DIELS ALDER REACTION; ELECTRON; HIGH TEMPERATURE; ISOMER; STEREOCHEMISTRY; STEREOISOMERISM; SYNTHESIS;

EID: 70349880366     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9017292     Document Type: Article

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