Splendid isolation for a nonmetallic dication

Angewandte Chemie - International Edition

Volumn 48, Issue 21, 2009, Pages 3740-3743

  Müller, Thomas ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

Author keywords

Carbene homologues; Cations; Cryptands; Germanium; Reactive intermediates

Indexed keywords

ATOMIC CATIONS; CARBENE HOMOLOGUES; CATIONS; CRYPTANDS; DICATIONS; REACTIVE INTERMEDIATES; SPACE-FILLING; TRIFLATES;

CRYSTAL ATOMIC STRUCTURE; GERMANIUM; SUGAR (SUCROSE);

POSITIVE IONS;

EID: 70349769739     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200900181     Document Type: Article

References (44)

1. Reviews: a) T. MÜller, Adv. Organomet. Chem. 2005, 53, 155
2. b) I. Zharov, J. Michl in The chemistry of organic germanium, tin and lead compounds, Vol. II (Ed.: Z. Rappoport), Wiley, Chichester, 2002, p. 633
3. C. A. Reed, Acc. Chem. Res. 1998, 31, 325.
4. a)C. Douvris, O. V. Ozerov, Science 2008, 321, 1188
5. b) R. Panisch, M. Bolte, T. MÜller, J. Am. Chem. Soc. 2006,128, 9676.
6. P. P. Gaspar in Organosilicon Chemistry VI, Vol. 2 (Eds.: N. Auner, J. Weis), Wiley-VCH, Weinheim, 2005, p. 10.
7. a) P. Jutzi, F. Kohl, P. Hofmann, C. Krüger, Y. Tsay, Chem. Ber. 1980,113, 757
8. b) P. Jutzi, A. Mix, B. Rummel, W. W. Schoeller, B. Neumann, H. G. Stammler, Science 2004, 305, 849
9. c) P. Jutzi, R. Dickbreder, H. Nöth, Chem. Ber. 1989, 122, 865
10. 10
11. e)M. Stender, A. D. Phillips P. P. Power, Inorg. Chem. 2001, 40, 5314
12. f) H. V. R. Dias, Z. Wang, J. Am. Chem. Soc. 1997, 119, 4650
13. g) M. Driess, S. Yao, M. Brym, C. van WÜllen, Angew. Chem. 2006, 118, 6882
14. Angew. Chem. Int. Ed. 2006, 45, 6730
15. h) A. Schäfer, W. Saak, D. Haase, T. Müller, Chem. Eur. J. 2009, 15, 3945
16. i) T. Probst, O. Steigelmann, J. Riede, H. Schmidbaur, Angew. Chem. 1990, 102, 1471
17. Angew. Chem. Int. Ed. Engl. 1990, 29, 1397
18. j) S. Hino, M. Brynda, A. D. Phillips, P. P. Power, Angew. Chem. 2004,116, 2709
19. Angew. Chem. Int. Ed. 2004, 43, 2655.
20. P. A. Rupar, V. N. Staroverov, K. M. Baines, Science 2008, 322, 1360.
21. a) A. J. Arduengo III, H. V. R. Dias, J. C. Calabrese, F. Davidson, Inorg. Chem. 1993, 32,1541
22. b) B. Gehrhus, P. B. Hitchcock, M. F. Lappert, J. Chem. Soc. Dalton Trans. 2000, 3094.
23. P. A. Rupar, M. C. Jennings, P. J. Ragogna, K. M. Baines, Organometallics 2007, 26, 4109.
24. P. A. Rupar, M. C. Jennings, K. M. Baines, Organometallics 2008, 27, 5043.
25. A. F. Holleman, E. Wiberg, N. Wiberg, Lehrbuch der Anorganischen Chemie 102 ed., de Gruyter, Berlin, 2007, p. 1015.
26. P. A. Rupar, V. N. Staroverov, P. J. Ragogna, K. M. Baines, J. Am. Chem. Soc. 2007, 129, 15138.
27. a) B. D. Ellis, C. A. Dyker, A. Decken, C. L. B. Macdonald, Chem. Commun. 2005, 1965
28. b) Y. Wang, B. Quillian, P. Wei, C. S. Wannere, Y. Xie, R. B. King, H. F. Schaefer III, P. v. R. Schleyer, G. H. Robinson, J. Am. Chem. Soc. 2007, 129, 12412
29. c) Y. Wang, Y. Xie, P. Wei, R. B. King, H. F. Schaefe III, P. v. R. Schleyer, G. H. Robinson, Science 2008, 321, 1069
30. d) Y. Wang, Y. Xie, P. Wei, R. B. King, H. F. Schaefer III, P. v. R. Schleyer, G. H. Robinson, J. Am. Chem. Soc. 2008, 130, 14970
31. e) C. A. Dyker, V. Lavallo, B. Donnadieu, G. Bertrand, Angew. Chem. 2008, 120, 3250
32. Angew. Chem. Int. Ed. 2008, 47, 3206
33. f) A. Fürstner, M. Alcarazo, R. Goddard, C. W. Lehmann, Angew. Chem. 2008, 120, 3254
34. Angew. Chem. Int. Ed. 2008, 47, 3210.
35. K. W. Klinkhammer in The chemistry oforganic germanium, tin and lead compounds, Vol. II (Ed.: Z. Rappoport), Wiley, Chichester, 2002, p. 283.
36. B. Dietrich in Comprehensive Supramolecular Chemistry, Vol. 1 (Eds.: J. L. Atwood, J.-M. Lehn), Pergamon, New York, 1996, p. 153.
37. V. A. Benin, J. C. Martin, M. R. Wilcott, Tetrahedron 1997, 53, 10133.
38. M. K. Denk, M. Khan, A. J. Lough, K. Shuchi, Acta Crystallogr. Sect. C 1998, 54, 1830.
39. a) A. Sekiguchi, T. Fukaea, V. Y. Lee, M. Nakamoto, M. Ichinohe, Angew. Chem. 2003, 115, 1175
40. Angew. Chem. Int. Ed. 2003, 42, 1143
41. b) J. B. Lambert, Y. Zhao, H. Wu, W. C. Tse, B. Kuhlmann, J. Am. Chem. Soc. 1999, 121, 5001
42. C. Schenk, C. Drost, A. Schnepf, J. Chem. Soc. Dalton Trans. 2009, 773.
43. For a recent example, see: J. W. Su, R. R. Burnette, ChemPhys-Chem 2008, 9, 1989.
44. 2+ dication or the GeX+ monocation complex, and they impressively demonstrate the general applicability of this synthetic approach to isolated subvalent germanium cations. See P. A. Rupar, R. Bandyopadhyay, B. F. T. Cooper, M. R. Stinchcombe, P. J. Ragogna, C. L. B. Macdonald, K.M. Baines, Angew. Chem. Int. Ed. 2009, DOI: 10.1002/anie.200901351.