Reduction of transition-metal-coordinated carbon monoxide by a rare-earth hydride cluster: Isolation of well-defined heteromultimetallic oxycarbene, oxymethyl, carbene, and methyl complexes

Angewandte Chemie - International Edition

Volumn 48, Issue 42, 2009, Pages 7888-7891

  Takenaka, Yasumasa ^a   Shima, Takanori ^a   Baldamus, Jens ^a   Hou, Zhaomin ^a  

^a RIKEN   (Japan)

Author keywords

Carbonyl ligands; Heterometallic complexes; Hydrides; Late transition metals; Rare earths

Indexed keywords

CARBENES; CARBONYL LIGANDS; COMPLEX 1; COORDINATED CARBON MONOXIDE; HETEROMETALLIC COMPLEXES; HETEROMETALLICS; HETEROMULTIMETALLIC; LATE TRANSITION METALS; METAL CARBONYL; METHYL COMPLEXES; OXO COMPLEXES; RARE-EARTH HYDRIDES; REACTION PATTERNS; TRANSITION-METAL COMPLEX;

CARBON CLUSTERS; CARBON MONOXIDE; CARBONYLATION; HYDRIDES; LIGANDS; METAL COMPLEXES; METALS; RARE EARTH ELEMENTS; YTTRIUM;

RARE EARTHS;

EID: 70349656350     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200903660     Document Type: Article

References (62)

1. a) E. L. Muetterti.es, J. Stein, Chem. Rev. 1.979, 79, 479-490;
2. b) A. R. Cutler, P. K. Hanna, J. C. Vites, Chem. Rev. 1988, 88, 1363-1403.
3. For the reduction of carbonyl ligands by main-group-metal hydride reagents, see: a) P. M. Treichel, R. L. Shubkin, Inorg. Chem. 1967, 6, 1328-1334;
4. b) C. Masters, C. vanderWoude, J. A. van Doom, J. Am. Chem. Soc. 1979, 101, 1633-1634;
5. c) W. Tarn, W-K. Wong, J. A. Gladysz, J. Am. Chem. Soc. 1979, 101, 1589-1591;
6. d) C. P. Casey, M. A. Andrews, D. R. McAlister, J. E. Rinz, J. Am. Chem. Soc. 1980, 102, 1927-1933;
7. e) J. A. Gladysz, Adv. Organomet. Chem. 1982, 20, 1 -38;
8. f) J. R. Sweet, W A. G. Graham, J. Am. Chem. Soc. 1982, 104, 2811-2815;
9. g) M. M. Harris, J. D. Atwood, M. E. Wright, G. O. Nelson, Inorg. Chem. 1982, 21, 2117-2118;
10. h) B. P. Gracey, S. A. R. Knox, K. A. Macpherson, A. G. Orpen, S. R. Stobart, J. Chem. Soc. Dalton Trans. 1985,1935-1944;
11. i) S. L. Brown, S. G. Davies, J. Chem. Soc. Chem. Commun. 1986, 84-85;
12. j) T. Beringhelli, G. D'Alfonso, G. Ciani, H. Molinari, Organometallics 1987, 6, 194-196;
13. k) G. Ortaggi, R. Paolesse, J. Organomet. Chem. 1988, 346, 219-224;
14. l) M. Akita, R. Hua, T. Oku, Y. Moro-oka, Organometallics 1996, 15, 2548-2553;
15. m) R. Shiozawa, H. Tobita, H. Ogino, Organometallics 1998, 17, 3497-3504;
16. n) M. Okazaki, T. Ohtani, M. Tkkano, H. Ogino, Organometallics 2004, 23, 4055-4061;
17. o) A. J. M. Miller, J. A. Labinger, J. E. Bercaw, J. Am. Chem. Soc. 2008, 130, 11874-11875.
18. For the reduction of carbonyl ligands by transition-metal hydride complexes, see: a) J. M. Manriquez, DR. McAlister, R. D. Sanner, J. E. Bercaw, J. Am Chem. Soc. 1978, 100, 2716-2724;
19. b) P. T. Wolczanski, R. S. Threlkel, J. E. Bercaw, J. Am. Chem. Soc. 1979, 101, 218-220;
20. c) R. S. Threlkel, J. E. Bercaw, J. Am. Chem. Soc. 1981, 103, 2650-2659;
21. d) D. H. Berry, J. E. Bercaw, Polyhedron 1988, 7, 759-766;
22. e) P. T. Barger, J. E. Bercaw, Organometallics 1984, 3, 278-284;
23. f) M. A. St. Clair, B. D. Santarsiero, J. E. Bercaw, Organometallics 1989, 8, 17-22;
24. g) A. Miedaner, D. L. DuBois, C. J. Curtis, R. C. Haltiwanger, Organometallics 1993, 12, 299-303;
25. h) W. W. Ellis, A. Miedaner, C. X Curtis, D. H. Gibson, D. L. DuBois, J. Am. Chem. Soc. 2002, 124, 1926-1932.
26. a) P. M. Maitlis, J. Organomet. Chem. 1995, 500, 239-249;
27. b) H. Schulz, Appl. Catal. A 1999, 186, 3-12;
28. c) M. X Overett, R. O. Hill, X R. Moss, Coord. Chem. Rev. 2000, 206, 581-605;
29. d) M. Akita, Appl. Catal. A 2000, 200, 153-165;
30. e)P. M. Maitlis, J. Organomet, Chem. 2004, 689, 4366-4374.
31. A review: Z. Hou, M. Nishiura, T. Shima, Eur. J. Inorg. Chem. 2007, 2535-2545.
32. a) O. Tardif, M. Nishiura, Z. Hou, Organometallics 2003, 22, 1171-1173;
33. b) D. Cui, O. Tardif, Z. Hou, J. Am. Chem. Soc 2004, 126, 1312-1313;
34. c) O. Tardif, D. Hashizume, Z. Hou, J. Am. Chem. Soc. 2004, 126, 8080-8081;
35. d) D. Cui, M. Nishiura, Z. Hou, Macromolecules 2005, 38, 4089-4095;
36. e) D. Cui, M. Nishiura, Z. Hou, Angew. Chem. 2005, 117, 981-984;
37. Angew. Chem. Int. Ed. 2005, 44, 959-962;
38. f) T. Shima, Z. Hou, J. Am. Chem. Soc. 2006, 128, 8124-8125;
39. g) X. Li, J. Baldamus, M. Nishiura, O. Tardif, Z. Hou, Angew. Chem. 2006, 118, 8364-8368;
40. Angew. Chem. Int. Ed. 2006, 45, 8184-8188;
41. h) M. Yousufuddin, X Baldamus, O. Tardif, Z. Hou, S. A. Mason, G. J. Mclntyre, R. Bau, Phys. B 2006, 385-386;
42. i) Y. Luo, Z, Hou, Organometallics 2007, 26, 2941-2944;
43. j) M. Yousufuddin, M. X Gutmann, X Baldamus, O. Tkrdif, Z. Hou, S. A. Mason, G. X Mclntyre, R. Bau, J. Am. Chem. Soc. 2008, 130, 3888-3891;
44. k) Y Luo, Z. Hou, J. Phys Chem. C. 2008, 112, 635-638.
45. For rare-earth-metal polyhydride complexes with no cyclopentadienyl ligands, see: a) D. M. Lyubov, C. Döring, G. K. Fukin, A. V. Cherkasov, A. S. Shavyrin, R. Kempe, A. A. Trifonov, Organometallics 2008, 27, 2905-2907;
46. b)M. Ohashi, M. Konkol, I. D. Rosal, R. Poteau, L. Maron, J. Okuda, J. Am. Chem. Soc 2008, 130, 6920-6921;
47. c) J. Cheng, K. Saliu, G. Y. Kiel, M., J. Ferguson, R. McDonald, J. Takats, Angew. Chem. 2008, 120, 4988-4991;
48. Angew. Chem. Int. Ed. 2008, 47, 4910-4913.
49. C. P. Casey, T. X Burkhardt, C. A. Bunnell, J. C. Calabrese, J. Am. Chem. Soc. 1977, 99, 2127-2134.
50. CCDC 738452 (2 a), 738453 (2 b), 738454 (3), 738455 (4), and 738456 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac. uk/data-request/cif.
51. X. T. Malito, R. Shakir, J. L. Atwood, / Chem. Soc. Dalton Trans. 1980,1253-1258.
52. A. T. Patton, C. E. Strouse, C. B. Knobler, X A. Gladysz, J. Am. Chem. Soc 1983, 105, 5804-5811.
53. a) J. W Kang, P. M. Maitlis, J. Organomet. Chem. 1971,26, 393-399;
54. b) J. W. Kang, K. Moseley, P. M. Maitlis, J. Am. Chem. Soc. 1969, 91, 5970-5977.
55. K. Isobe, A. de V. Miguel, P. M. Bailey, S. Okeya, P. M. Maitlis, J. Chem. Soc. Dalton Trans. 1983,1441-1447.
56. The reason for the formation of by-products and ethene has not been yet been clarified. Further studies are in progress and will be reported in. due course. For the formation of ethene in the reaction, of CO gas with the hydride cluster 1, see Ref. [6f].
57. See the Supporting Information for details.
58. a) R. A. Periana, R. G. Bergman, J. Am. Chem. Soc. 1986, 108, 7332-7346;
59. b) W D. Jones, F. X Feher, Organometallics 1983, 2, 562-563.
60. For recent examples of rare-earth/d-bl.ock transition-metal heteromultimetallic polyhydride complexes, see: a) T. Shima, Z. Hou, Chem. Lett. 2008, 37, 298-299;
61. b) T. Shima, Z. Hou, Organometallics 2009, 28, 2244-2252.
62. 2 was monitored by gas chromatography, although the newly formed complexes could not be successfully characterized.