Hydrogenation of carbon monoxide by tetranuclear rare earth metal polyhydrido complexes. Selective formation of ethylene and isolation of well-defined polyoxo rare earth metal clusters

Journal of the American Chemical Society

Volumn 128, Issue 25, 2006, Pages 8124-8125

  Shima, Takanori ^a   Hou, Zhaomin ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; ETHYLENE; LANTHANIDE;

ARTICLE; CATALYST; CHEMICAL BOND; COMPLEX FORMATION; HYDROGENATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 33745676948     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja062348l     Document Type: Article

References (32)

1. Fischer, F.; Tropsch, H. Chem. Ber. 1926, 59, 830-836.
2. (a) Masters, C. Adv. Organomet. Chem. 1979, 17, 61-103.
3. (b) Herrmann, W. A. In Applied Homogeneous Catalysis with Organometallic Compounds; Cornils, B., Herrmann, W. A., Eds.; VCH: Weinheim, Germany, 1996; Vol. 2. pp 747-762.
4. (c) Maitlis, P. M. J. Organomet. Chem. 2004, 689, 4366-4374.
5. (d) Akita, M. Appl. Catal. A 2000, 200, 153-165.
6. (e) Overett, M. J.; Hill, R. O.; Moss, J. R. Coord. Chem. Rev. 2000, 200, 581-605.
7. For examples, see: (a) Cutler, A. R.; Hanna, P. K.; Vites, J. C. Chem. Rev. 1988, 88, 1363-1403.
8. (b) Wayland, B. B.; Woods, B. A. J. Chem. Soc., Chem. Commun. 1981, 700-701.
9. (c) Wayland, B. B.; Woods, B. A.; Pierce, R. J. Am. Chem. Soc. 1982, 104, 302-303.
10. (a) Gambarotta, S.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Am. Chem. Soc. 1983, 105, 1690-1691.
11. (b) Wolczanski, P. T.; Threlkel, R. S.; Bercaw, J. E. J. Am. Chem. Soc. 1979, 101, 218-220.
12. (c) Miller, R. L.; Toreki, R.; LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D.; Roe, D. C. J. Am. Chem. Soc. 1993, 115, 5570-5588.
13. (a) Manriquez, J. M.; McAlister, D. R.; Sanner, R. D.; Bercaw, J. E. J. Am. Chem. Soc. 1978, 100, 2716-2724.
14. (b) Manriquez, J. M.; McAlister, D. R.; Sanner, R. D.; Bercaw, J. E. J. Am. Chem. Soc. 1976, 98, 6733-6735.
15. (c) Moloy, K. G.; Marks, T. J. J. Am. Chem. Soc. 1984, 106, 7051-7064.
16. (d) Katahira, D. A.; Moloy, K. G.; Marks, T. J. Organometallics 1982, 1, 1723-1726.
17. (e) Fagan, P. J.; Moloy, K. G.; Marks, T. J. J. Am. Chem. Soc. 1981, 103, 6959-6962.
18. (f) Evans, W. J.; Grate, J. W.; Doedens, R. J. J. Am. Chem. Soc. 1985, 107, 1671-1679.
19. Matsuo, T.; Kawaguchi, H. J. Am. Chem. Soc. 2005, 127, 17198-17199.
20. (a) Tardif, O.; Nishiura, M.; Hou, Z. Organometallics 2003, 22, 1171-1173.
21. (b) Cui, D.; Tardif, O.; Hou, Z. J. Am. Chem. Soc. 2004, 126, 1312-1313.
22. (c) Tardif, O.; Hashizume, D.; Hou, Z. J. Am. Chem. Soc. 2004, 126, 8080-8081.
23. (d) Cui, D.; Nishiura, M.; Hou, Z. Angew. Chem., Int. Ed. 2005, 44, 959-962.
24. (e) Luo, Y.; Baldamus, J.; Tardif, O.; Hou, Z. Organometallics 2005, 24, 4362-4366.
25. Masters, C.; van der Woude, C.; van Doorn, J. A. J. Am. Chem. Soc. 1979, 101, 1633-1634.
26. (a) Kou, Y.; Su, G. Q.; Zhang, W. Z.; Yin, Y. Q. J. Catal. 1996, 162, 361-364.
27. (b) Su, G. Q.; Zhang, W. Z.; Gao, R. X.; Yin, Y. Q. Chin. Sci. Bull. 1992, 3, 261.
28. 2 (1 atm) at room temperature resulted in the quantitative formation of ethane and 4.
29. 1H COSY.
30. Evans, W. J.; Dominguez, R.; Hanusa, T. P. Organometallics 1986, 5, 1291-1296.
31. 2=CHOR, and is typical for a C-C double bond. See: Kamieñska-Trela, K. In Annual Reports on NMR Spectroscopy, Webb, G. A., Ed.; Academic Press: London, 1995; Vol. 30, p 148.
32. An intermolecular process might also be possible.