Activation and dehydrogenative silylation of the C-H bonds of phosphine-coordinated ruthenium in Lu/Ru heteromultimetallic hydride complexes

Chemistry Letters

Volumn 37, Issue 3, 2008, Pages 298-299

  Shima, Takanori ^a   Hou, Zhaomin ^a  

^a INST OF PHYS AND CHEMICAL RESEARCH   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 42049113722     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2008.298     Document Type: Article

References (28)

1. a) W. J. Evans, J. H. Meadows, T. P. Hanusa, J. Am. Chem. Soc. 1984, 106, 4454.
2. b) N. S. Radu, P. K. Gantzel, T. D. Tilley, J. Chem. Soc., Chem. Commun. 1994, 1175.
3. c) D. Alvarez, Jr., K. G. Caulton, W. J. Evans, J. W. Ziller, Inog. Chem. 1992, 31, 5500.
4. d) D. Alvarez, Jr., K. G. Caulton, J. Am. Chem. Soc. 1990, 112, 5674.
5. e) M. Ephritikhine, Chem. Rev. 1997, 97, 2193.
6. f) I. P. Beletskaya, A. Z. Voskoboynikov, E. B. Chuklanova, N. I. Kirillova, A. K. Shestakova, I. N. Parshina, A. I. Gusev, G. K. Magomedov, J. Am. Chem. Soc. 1993, 115, 3156.
7. g) M. L. H. Green, A. K. Hughes, D. M. Michaelidou, P. Mountford, J. Chem. Soc., Chem. Commun. 1993, 591.
8. a) Y. Luo, J. Baldamus, Z. Hou, J. Am. Chem. Soc. 2004, 126, 13910.
9. b) X. Li, J. Baldamus, Z. Hou, Angew. Chem., Int. Ed. 2005, 44, 962.
10. c) D. Cui, M. Nishiura, Z. Hou, Macromolecules 2005, 38, 4089.
11. a) Z. Hou, M. Nishiura, T. Shima, Eur. J. Inorg. Chem. 2007, 2535.
12. b) T. Shima, Z. Hou, J. Am. Chem. Soc. 2006, 128, 8124.
13. c) X. Li, J. Baldamus, M. Nishiura, O. Tardif, Z. Hou, Angew. Chem., Int. Ed. 2006, 45, 8184.
14. d) D. Cui, O. Tardif, Z. Hou, J. Am. Chem. Soc. 2004, 126, 1312.
15. e) O. Tardif, D. Hashizume, Z. Hou, J. Am. Chem. Soc. 2004, 126, 8080.
16. T. M. Cameron, J. C. Gordon, B. L. Scott, Organometallics 2004, 23, 2995.
17. H. Suzuki, D. H. Lee, N. Oshima, Y. Moro-oka, Organometallics 1987, 6, 1569.
18. An isomer of 4 is also present due to the two stereoisomers of the coordination of THF.
19. a) E. C. Morrison, D. A. Tocher, J. Organomet. Chem. 1991, 408, 105.
20. b) E. C. Morrison, D. A. Tocher, Inorg. Chim. Acta 1989, 157, 139.
21. R. D. Adams, B. Captain, W. Fu, M. D. Smith, J. Organomet. Chem. 2002, 651, 124.
22. See Supporting Information for details, which is available electronically on the CSJ-Journal web site, http://www.csj.jp/journals/chem-lett/. Crystallographic data reported in this manuscript have been deposited with Cambridge Crystallographic Data Centre as supplementary publication Nos. CCDC-675087-675091. Copies of the data can be obtained free of charge via http://www.ccdc. cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge, CB2 IEZ, UK; fax: +44 1223 336033; or deposit@ccdc. cam.ac.uk).
23. 3)-H bond, see: a) F. Kakiuchi, K. Tsuchiya, M. Matsumoto, E. Mizushima, N. Chatani, J. Am. Chem. Soc. 2004, 126, 12792.
24. b) A. D. Sadow, T. D. Tilley, J. Am. Chem. Soc. 2005, 127, 643.
25. 2Ph has been well documented. For examples: See: a) A. Z. Voskoboynikov, I. N. Parshina, A. K. Shestakova, K. P. Butin, I. P. Beletskaya, L. G. Kuz'mina, J. A. K. Howard, Organometallics 1997, 16, 4041.
26. b) S. Arndt, P. Voth, T. P. Spaniol, J. Okuda, Organometallics 2000, 19, 4690.
27. c) I. Castillo, T. D. Tilley, Organometallics 2001, 20, 5598.
28. d) O. Tardif, M. Nishiura, Z. Hou, Organometallics 2003, 22, 1171.