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Volumn 15, Issue 10, 1996, Pages 2548-2553

Deoxygenative reduction of diruthenium carbonyl complexes (η5-C5H4R)2Ru 2(μ-CO)2(CO)2 with hydrosilanes leading to bridging methylene complexes (η5-C5H4R)2Ru 2(μ-CH2)n(μ-CO)2-n(CO) 2 (n = 1, 2; R = H, CH3)

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EID: 0001461112     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950893h     Document Type: Article
Times cited : (23)

References (64)
  • 7
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    • D. Reidel: Dordrecht, The Netherlands
    • (b) Keim, W. Catalysis in C, Chemistry; D. Reidel: Dordrecht, The Netherlands, 1983.
    • (1983) Catalysis in C, Chemistry
    • Keim, W.1
  • 15
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    • and references cited therein. For carbide complexes
    • (e) Cutler, A. R.; Hanna, P. K.; Vites, J. C. Chem. Rev. 1988, 88, 1363 and references cited therein. For carbide complexes:
    • (1988) Chem. Rev. , vol.88 , pp. 1363
    • Cutler, A.R.1    Hanna, P.K.2    Vites, J.C.3
  • 48
    • 0003426786 scopus 로고
    • Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: Chichester, U.K.
    • (a) The chemistry of organosilicon compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: Chichester, U.K., 1989; Vols. 1 and 2.
    • (1989) The Chemistry of Organosilicon Compounds , vol.1-2
  • 49
    • 0003625966 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K.
    • (b) Comprehensive Organometallic Chemistry I and II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1982 and 1995.
    • (1982) Comprehensive Organometallic Chemistry I and II
  • 50
    • 3843091267 scopus 로고    scopus 로고
    • Part of this work was reported in a communication, ref 8e
    • Part of this work was reported in a communication, ref 8e.
  • 51
    • 85087251200 scopus 로고    scopus 로고
    • note
    • -1.
  • 52
    • 3843131479 scopus 로고    scopus 로고
    • note
    • 14 The interconversion was not observed at 150°C. Attempted determination of the activation parameters of 3a was unsuccessful, because the isomerization at 150°C was too slow to be measured and 3a decomposed gradually at 200°C before reaching the equilibrium. Thus we could not make a quantitative comparison of the activation parameters. However, it is evident that, as the number of the bridging alkylidene ligands increases, the cis-trans isomerization becomes a higher energy process.
  • 56
    • 85087249742 scopus 로고    scopus 로고
    • note
    • -1.
  • 58
    • 3843097870 scopus 로고    scopus 로고
    • (a) Reaction of 9: unpublished results. (b) Reaction of 10: see ref 8f,j
    • (a) Reaction of 9: unpublished results. (b) Reaction of 10: see ref 8f,j.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.