Synthesis, structure, and reactivity of neutral hydrogen-substituted ruthenium silylene and germylene complexes

Organometallics

Volumn 28, Issue 17, 2009, Pages 5082-5089

  Hayes, Paul G ^a,b   Waterman, Rory ^a,c   Glaser, Paul B ^a,d   Tilley, T Don ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF LETHBRIDGE   (Canada)

^c UNIVERSITY OF VERMONT   (United States)

^d GE GLOBAL RESEARCH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COUPLING CONSTANTS; GERMYLENES; NEUTRAL HYDROGEN; SILICON CENTERS; SILYLENES; SOLID-STATE STRUCTURES;

CHLORINE; GERMANIUM; HYDROGEN; RUTHENIUM; SILANES; TOLUENE;

RUTHENIUM COMPOUNDS;

EID: 69949130811     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900348m     Document Type: Article

References (59)

1. Waterman, R.; Hayes, P. G.; Tilley, T. D. Acc. Chem. Res. 2007, 40, 712-719.
2. (a) Lewis, K. M., Rethwisch, D. G., Eds. Catalyzed Direct Reactions of Silicon; Elsevier: Amsterdam, 1993.
3. (b) Pachaly, B.; Weis, J. In Organosilicon Chemistry III: From Molecules to Materials, Munich Silicon Days; 1996; Wiley & Sons: New York, 1998; p 478.
4. (c) Brook, M. A. Silicon in Organic, Organometallic and Polymer Chemistry; Wiley: New York, 2000; p 381.
5. (d) Lewis, L. N. In Chemistry of Organosilicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, UK, 1998; Pt 2, p 1581.
6. (a) Curtis, M. D.; Epstein, P. S. Adv. Organomet. Chem. 1981, 19, 213-255.
7. (b) Kumada, M. J. J. Organomet. Chem. 1975, 100, 127-138.
8. Some recent examples include: (a)Franz, A.K.; Woerpel, K. A. J. Am. Chem. Soc. 1999, 121, 949-957.
9. (b) Palmer, W S.; Woerpel, K. A. Organometallics 2001, 20, 3691-3697.
10. (c) Cirakovic, J.; Driver, T. G.; Woerpel, K. A. J. Am. Chem. Soc. 2002, 124, 9370-9371.
11. Glaser, P. B.; Tilley, T. D. J. Am. Chem. Soc. 2003, 125, 13640-13641.
12. (a) Chalk, A. J.; Harrod, J. F. J. Am. Chem. Soc. 1965, 87, 16-21.
13. (b) Seitz, F.; Wrighton, M. S. Angew. Chem., Int. Ed. 1988, 27, 289-291.
14. (c) Duckett, S. B.; Perutz, R. N. Organometallics 1992, 11, 90-98.
15. (d) Sakaki, S.; Sumimato, M.; Fukuhara, M.; Sugimoto, M.; Fujimoto, H.; Matsuzaki, S. Organometallics 2002, 21, 3788-3802.
16. (a) Rubin, M.; Schwier, T.; Gevorgyan, N. J. Org. Chem. 2002, 67, 1936-1940.
17. (b) Song, Y S.; Yoo, B. R.; Lee, G. H.; Jung, I. N. Organometallics 1999, 18, 3109-3115.
18. (c) Lambert, J. B.; Zhao, Y.; Wu, H. W J. Org. Chem. 1999, 64, 2729-2736.
19. (d) Schmeltzer, J. M.; Porter, L. A.; Stewart, M. P.; Buriak, J. M. Langmuir 2002, 18, 2971-2974.
20. Hayes, P. G.; Beddie, C.; Hall, M. B.; Waterman, R.; Tilley, T. D. J. Am. Chem. Soc. 2006, 128, 428-429.
21. (a) Beddie, C.; Hall, M. B. J. Am. Chem. Soc. 2004, 126, 13564-13565.
22. (b) Beddie, C.; Hall, M. B. J. Phys. Chem. A 2006, 110, 1416.
23. (c) Böhme, U. J. Organomet. Chem. 2006, 691,4400-4410.
24. Brunner, H. Angew. Chem., Int. Ed. 2004, 43, 2749-2750.
25. (a) Sakaba, H.; Hirata, T.; Kabuto, C.; Kabuto, K. Organometallics 2006, 25, 5145-5150.
26. (b) Watanabe, T.; Hashimoto, H.; Tobita, H. J. Am. Chem. Soc. 2007, 129, 11338-11339.
27. (c) Watanabe, T.; Hashimoto, H.; Tobita, H. J. Am. Chem. Soc. 2006, 128, 2176-2177.
28. (d) Ochiai, M.; Hashimoto, H.; Tobita, H. Angew. Chem., Int. Ed. 2007, 46, 8192-8194.
29. (e) Simmons, R. S.; Gallucci, J. C.; Tessier, C. A.; Youngs, W J. J. Organomet. Chem. 2002, 654, 224-228.
30. (f) Watanabe, T.; Hashimoto, H.; Tobita, H. Angew. Chem., Int. Ed. 2004, 43, 218-221.
31. (g) Mork, B. V.; Tilley, T. D.; Schultz, A. J.; Cowan, J. A. J. Am. Chem. Soc. 2004, 126, 10428-10440.
32. (h) Feldman, J. D.; Peters, J. D.; Tilley, T D. J. Am. Chem. Soc. 2002, 21, 4065-4075.
33. (i) Glaser, P. B.; Tilley, T D. Organometallics 2004, 23, 5799-5812.
34. (j) Rankin, M. A.; MacLean, D. F.; Schatte, G.; McDonald, R.; Stradiotto, M. J. Am. Chem. Soc. 2007, 129, 15855-15864.
35. (k) Ochiai, M.; Hashimoto, H.; Tobita, H. Dalton Trans. 2009, 1812-1814.
36. Hashimoto, H.; Ochiai, M.; Tobita, H. J. Organomet. Chem. 2007, 692, 36-43.
37. See Supporting Information for additional details.
38. Grumbine, S. K.; Tilley, T. D. J. Am. Chem. Soc. 1994, 116, 5495-5496.
39. Rivard, E.; Power, P. P. Inorg. Chem. 2007, 46, 10047-10064.
40. Smit, C. N.; Bickelhaupt, F. Organometallics 1987, 6, 1156-1163.
41. F): Unpublished results. Hayes, P. G.; Tilley, T. D.
42. Mork, B. V.; Tilley, T. D. Angew. Chem., Int. Ed. 2003, 42, 357-360.
43. See Supporting Information for additional details.
44. (a) Chan, L. Y. Y.; Graham, W. A. G. Inorg. Chem. 1975, 14, 1778-1781.
45. (b) Ball, R.; Bennett, M. J. Inorg. Chem. 1972, 11, 1806-1811.
46. (c) Adams, R. D.; Captain, B.; Zhu, L. Inorg. Chem. 2005, 44, 6623-6631.
47. (d) Adams, R. D.; Captain,B.; Fu, W Inorg. Chem. 2003, 42, 1328-1333.
48. (e) Adams, R. D.; Boswell, E. M.; Captain, B.; Patel, M. A. Inorg. Chem. 2007, 47, 533-540.
49. (f) Matsumoto, T.; Nakaya, Y.; Itakura, N.; Tatsumi, K. J. Am. Chem. Soc. 2008, 130, 2458-2459.
50. (g)Zhang, Y.; Wang, B.;Xu, S.; Zhou,X. Organometallics 2001, 20, 3829-3832.
51. (h) Adams, R. D.; Captain, B.; Fu, W J. Organomet, Chem. 2003, 671, 158-165.
52. (i) Freeman, W. P.; Tilley, T. D.; Rheingold, A. L.; Ostrander, R. L. Angew. Chem., Int. Ed. 1993, 32, 1744-1745.
53. (j) Howard, J. A. K.; Woodward, P. J. Chem. Soc., Dalton Trans. 1978, 412-416.
54. (k) Marciniec, B.; Lawicka, H.; Majchrzak, M.; Kubicki, M.; Kownacki, I. Chem.-Eur. J. 2006, 12, 244-250.
55. Fagan, P. J.; Ward, M. D.; Calabrese, J. C. J. Am. Chem. Soc. 1989, 111, 1698-1719.
56. Betley, T. A.; Peters, J. C. Inorg. Chem. 2003, 42, 5074-5084.
57. Schrock, R. R. J. Organomet. Chem. 1976, 122, 209-225.
58. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112-122.
59. Tenorio, M. J.; Puerta, M. C.; Valerga, P. J. Organomet. Chem. 2000, 609, 161-168.